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Methanamine, N-methyl-N-nitro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil460.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Tfus345.45KN/ABruhl, 1897Uncertainty assigned by TRC = 1.5 K; TRC
Quantity Value Units Method Reference Comment
Deltasub69.87kJ/molVBradley, Cotson, et al., 1952ALS

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
69.9319.DBMStephen, Bradley, et al., 1952Based on data from 315. - 324. K. See also Pedley and Rylance, 1977.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Method Reference Comment
17.26331.5DSCZeman, 1997AC
37.66327.N/AOyumi and Brill, 1987AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Bruhl, 1897
Bruhl, J.W., Spectrochemistry of nitrogen containing compounds V, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1897, 22, 373. [all data]

Bradley, Cotson, et al., 1952
Bradley, R.S.; Cotson, S.; Cox, E.G., The determination of vapour pressures of the order of 1 mm of mercury by a mnodification of Smith and Menzie's method. The vapour pressure of dimethylnitramine, J. Chem. Soc., 1952, 740-741. [all data]

Stephen, Bradley, et al., 1952
Stephen, Alistair M.; Bradley, R.S.; Cotson, S.; Cox, E.G.; Gerrard, W.; Thrush, A.M.; Fairfull, A.E.S.; Lowe, J.L.; Peak, D.A., Notes, J. Chem. Soc., 1952, 738, https://doi.org/10.1039/jr9520000738 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]

Zeman, 1997
Zeman, Svatopluk, Some predictions in the field of the physical thermal stability of nitramines, Thermochimica Acta, 1997, 302, 1-2, 11-16, https://doi.org/10.1016/S0040-6031(96)03101-2 . [all data]

Oyumi and Brill, 1987
Oyumi, Y.; Brill, T.B., Thermal decomposition of energetic materials. 23. Thermochemical differentiation of cyclic and acyclic nitramines by their phase transitions, Thermochim. Acta, 1987, 116, 125-130. [all data]


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