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Boron dihydride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to BH2+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.8 ± 0.2EIFehlner and Koski, 1964RDSH

De-protonation reactions

HB- + Hydrogen cation = H2B

By formula: HB- + H+ = H2B

Quantity Value Units Method Reference Comment
Deltar1629. ± 28.kJ/molD-EAReid, 1993gas phase; B

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fehlner and Koski, 1964
Fehlner, T.P.; Koski, W.S., Direct detection of the borane molecule and the boryl radical by mass spectrometry, J. Am. Chem. Soc., 1964, 86, 2733. [all data]

Reid, 1993
Reid, C.J., Electron Affinities of BH, B2, BC, and BN molecules determined using Charge Inversion Spectrometry, Int. J. Mass Spectrom. Ion Proc., 1993, 127, 147, https://doi.org/10.1016/0168-1176(93)87087-9 . [all data]


Notes

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