vanadium trichloride oxide

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
>3.60 ± 0.50IMRBFlesch and Svec, 1975EA: > Cl-; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.9 ± 0.3EIMason and Behrens, 1982LBLHLM
11.90 ± 0.05EIFlesch and Svec, 1975LLK
11.6PEBurroughs, Evans, et al., 1974LLK
12.2 ± 0.2EIDillard, 1967RDSH
11.84PEBurroughs, Evans, et al., 1974Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
ClOV+18.1 ± 0.32ClEIMason and Behrens, 1982LBLHLM
ClOV+16.31 ± 0.052ClEIFlesch and Svec, 1975LLK
ClOV+14.05 ± 0.06Cl2EIFlesch and Svec, 1975LLK
ClOV+15.3 ± 0.3Cl2EIDillard, 1967RDSH
ClV+25.0 ± 0.22Cl+OEIMason and Behrens, 1982LBLHLM
ClV+22.16 ± 0.072Cl+OEIFlesch and Svec, 1975LLK
ClV+22.6 ± 0.52Cl+OEIDillard, 1967RDSH
Cl2OV+14.9 ± 0.2ClEIMason and Behrens, 1982LBLHLM
Cl2OV+13.25 ± 0.05ClEIFlesch and Svec, 1975LLK
Cl2OV+13.7 ± 0.3ClEIDillard, 1967RDSH
Cl2V+20.8 ± 0.3Cl+OEIMason and Behrens, 1982LBLHLM
Cl2V+18.98 ± 0.20Cl+OEIFlesch and Svec, 1975LLK
Cl2V+18.5 ± 0.4Cl+OEIDillard, 1967RDSH
Cl3V+16.48 ± 0.28OEIFlesch and Svec, 1975LLK
Cl3V+15.8 ± 0.4OEIDillard, 1967RDSH
OV+22.0 ± 0.33ClEIMason and Behrens, 1982LBLHLM
OV+19.77 ± 0.093ClEIFlesch and Svec, 1975LLK
OV+20.0 ± 0.43ClEIDillard, 1967RDSH
V+26.83 ± 0.393Cl+OEIFlesch and Svec, 1975LLK
V+27.4 ± 0.53Cl+OEIDillard, 1967RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Flesch and Svec, 1975
Flesch, G.D.; Svec, H.J., Thermochemistry of vanadium oxytrichloride and vanadium oxytrifluoride by mass spectrometry, Inorg. Chem., 1975, 14, 1817. [all data]

Mason and Behrens, 1982
Mason, C.F.V.; Behrens, R.G., An electron impact mass spectrometry investigation of VOCl3(g) and their dissociative fragments, J. Less-Common Met., 1982, 85, 21. [all data]

Burroughs, Evans, et al., 1974
Burroughs, P.; Evans, S.; Hamnett, A.; Orchard, A.F.; Richardson, N.V., He-I photoelectron spectra of some d (0) transition metal compounds, J. Chem. Soc. Faraday Trans. 2, 1974, 70, 1895. [all data]

Dillard, 1967
Dillard, J.G., Gaseous inorganic ion decompositions: a mass spectrometric study of some transition metal compounds, Ph.D. Dissertation, Kansas State University, 1967 (University Microfilms Internal Order 67-9138), 1967. [all data]


Notes

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