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Aluminum tris(acetylacetonate)

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-399.4 ± 1.1kcal/molReviewMartinho SimõesSelected data. The enthalpy of formation is the average of the results obtained by CC-SB Cavell and Pilcher, 1977 and RSC Hill and Irving, 1966.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-428.51 ± 0.45kcal/molReviewMartinho SimõesSelected data. The enthalpy of formation is the average of the results obtained by CC-SB Cavell and Pilcher, 1977 and RSC Hill and Irving, 1966.; MS
Quantity Value Units Method Reference Comment
solid,1 bar114.5cal/mol*KN/ATeghil, Ferro, et al., 1981DH

Constant pressure heat capacity of solid

Cp,solid (cal/mol*K) Temperature (K) Reference Comment
76.82298.Teghil, Ferro, et al., 1981T = 4.2 to 450 K.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tfus466.7KN/AGrinberg, Lazarev, et al., 1986Uncertainty assigned by TRC = 0.2 K; TRC
Tfus467.7KN/AMurray and Hill, 1983Uncertainty assigned by TRC = 0.5 K; TRC
Quantity Value Units Method Reference Comment
Deltavap18.8 ± 0.2kcal/molTGrinberg, Lazarev, et al., 1986, 2Based on data from 430. - 530. K.; AC
Quantity Value Units Method Reference Comment
Deltasub29.11 ± 0.36kcal/molN/ASemyannikov, Igumenov, et al., 2006Based on data from 376. - 467. K.; AC
Deltasub28.7 ± 0.72kcal/molMENaghibi-Bidokhti, 1977See also da Silva and Ferrao, 1988.; AC
Deltasub29.1 ± 1.0kcal/molN/AIrving and Ribeiro da Silva, 1975MS
Deltasub29.1 ± 1.0kcal/molN/AIrving and da Silva, 1975AC

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Method Reference Comment
24.33378.MESiddiqi, Siddiqui, et al., 2007Based on data from 345. - 410. K.; AC
22.413. - 443.TGAFahlman and Barron, 2000AC
24.38 ± 0.76448.BGLazarev, Greenberg, et al., 1988Based on data from 432. - 464. K.; AC
5.81458.N/AVolkov, Mazurenko, et al., 1978AC
15.8 ± 0.79398.N/AFontaine, Pommier, et al., 1972Based on data from 383. - 413. K.; AC
4.90417. - 476.N/ABerg and Truemper, 1960See also Berg and Truemper, 1965.; AC

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Method Reference Comment
8.0545466.7N/AGrinberg, Lazarev, et al., 1986DH
8.41463.DSCSabolovic, Mrak, et al., 2004AC
8.05466.7N/ALazarev, Greenberg, et al., 1988AC
7.82458.N/ABeech and Lintonbon, 1971AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
17.2466.7Grinberg, Lazarev, et al., 1986DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.5PEAkopyan, Vovna, et al., 1990LL
7.78 ± 0.05EIWestmore, Reimer, et al., 1981LLK
8.27 ± 0.13EISchildcrout, Pearson, et al., 1968RDSH
7.95 ± 0.05EIBancroft, Reichert, et al., 1968RDSH
8.18PEAkopyan, Vovna, et al., 1990Vertical value; LL

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C10H14O4Al+9.1 ± 0.2?EIBancroft, Reichert, et al., 1968RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-5556
NIST MS number 230299

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Cavell and Pilcher, 1977
Cavell, K.J.; Pilcher, G., J. Chem. Soc. Faraday Trans. I, 1977, 73, 1590. [all data]

Hill and Irving, 1966
Hill, J.O.; Irving, R.J., J. Chem. Soc. (A), 1966, 971.. [all data]

Teghil, Ferro, et al., 1981
Teghil, R.; Ferro, D.; Bencivenni, L.; Pelino, M., A thermodynamic study of the sublimation processes of aluminum and copper acetylacetonates, Thermochim. Acta, 1981, 44, 213-222. [all data]

Grinberg, Lazarev, et al., 1986
Grinberg, Ya.Kh.; Lazarev, V.B.; Zavernyaev, A.Yu.; Shreider, V.A.; Chepik, S.D., Enthalpies of fusion of aluminium(III), chromium(III), zirconium(IV), and zinc(II) acetylacetonates, Zhur. Fiz. Khim., 1986, 60, 1044. [all data]

Murray and Hill, 1983
Murray, J.P.; Hill, J.O., DSC determination of the fusion and sublimation enthalpy of bis(2,4-pentanedionato)beryllium(II) and tris(2,4-pentanedionato)aluminium(III), Thermochim. Acta, 1983, 63, 211. [all data]

Grinberg, Lazarev, et al., 1986, 2
Grinberg, Ya.Kh.; Lazarev, V.B.; Zavernyaev, A.Yu.; Shreider, V.A.; Chepik, S.D., Zh. Fiz. Khim., 1986, 60, 1386. [all data]

Semyannikov, Igumenov, et al., 2006
Semyannikov, P.P.; Igumenov, I.K.; Trubin, S.V.; Chusova, T.P.; Semenova, Z.I., Thermodynamics of sublimation of aluminium triacetylacetonate, Thermochimica Acta, 2006, 451, 1-2, 80-83, https://doi.org/10.1016/j.tca.2006.08.008 . [all data]

Naghibi-Bidokhti, 1977
Naghibi-Bidokhti, H., , Ph.D. Thesis, University of Surrey, 1977. [all data]

da Silva and Ferrao, 1988
da Silva, M.A.V. Ribeiro; Ferrao, Maria Luisa C.C.H., Energetics of metal-oxygen bonds in metal complexes of «beta»-diketones, Polym. J., 1988, 60, 8, https://doi.org/10.1351/pac198860081225 . [all data]

Irving and Ribeiro da Silva, 1975
Irving, R.J.; Ribeiro da Silva, M.A.V., J. Chem. Soc., Dalton Trans., 1975, 1257.. [all data]

Irving and da Silva, 1975
Irving, Roger J.; da Silva, Manuel A.V. Ribeiro, Thermochemistry of tri(tropolonato)- and tri(4-methyltropolonato)-aluminium(III), J. Chem. Soc., Dalton Trans., 1975, 13, 1257, https://doi.org/10.1039/dt9750001257 . [all data]

Siddiqi, Siddiqui, et al., 2007
Siddiqi, M. Aslam; Siddiqui, Rehan A.; Atakan, Burak, Thermal stability, sublimation pressures and diffusion coefficients of some metal acetylacetonates, Surface and Coatings Technology, 2007, 201, 22-23, 9055-9059, https://doi.org/10.1016/j.surfcoat.2007.04.036 . [all data]

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

Lazarev, Greenberg, et al., 1988
Lazarev, V.B.; Greenberg, J.H.; Ozerova, Z.P.; Sharpataya, G.A., DSC and vapour pressure investigation of some «beta»-diketonates, Journal of Thermal Analysis, 1988, 33, 3, 797-799, https://doi.org/10.1007/BF02138589 . [all data]

Volkov, Mazurenko, et al., 1978
Volkov, S.V.; Mazurenko, E.A.; Bublik, Z.N., Effect of the nature of substituents in «beta»-diketonates on their thermodynamic characteristics, Str., Svoistva Primen. «beta» [Beta]-Diketonatov Met., [Mater. Vses. Semin.], 3rd, V.I. Spitsyn, ed(s)., 1978, 119-122. [all data]

Fontaine, Pommier, et al., 1972
Fontaine, R.; Pommier, C.; Guiochon, G., Bull. Soc. Chim. Fr., 1972, 8, 3011. [all data]

Berg and Truemper, 1960
Berg, Eugene W.; Truemper, Joseph T., A STUDY OF THE VOLATILE CHARACTERISTICS OF VARIOUS METAL «beta»-DIKETONE CHELATES, J. Phys. Chem., 1960, 64, 4, 487-490, https://doi.org/10.1021/j100833a029 . [all data]

Berg and Truemper, 1965
Berg, Eugene W.; Truemper, Joseph T., Vapor pressure-temperature data for various metal «beta»-diketone chelates, Analytica Chimica Acta, 1965, 32, 245-252, https://doi.org/10.1016/S0003-2670(00)88930-8 . [all data]

Sabolovic, Mrak, et al., 2004
Sabolovic, Jasmina; Mrak, Zeljko; Kostrun, Sanja; Janekovic, August, Is the Enthalpy of Fusion of Tris(acetylacetonato)metal(III) Complexes Affected by Their Potential Energy in the Crystal State?, Inorg. Chem., 2004, 43, 26, 8479-8489, https://doi.org/10.1021/ic048900u . [all data]

Beech and Lintonbon, 1971
Beech, Graham; Lintonbon, Roger M., Thermal and kinetic studies of some complexes of 2,4-pentanedione, Thermochimica Acta, 1971, 3, 2, 97-105, https://doi.org/10.1016/0040-6031(71)80003-5 . [all data]

Akopyan, Vovna, et al., 1990
Akopyan, M.E.; Vovna, V.I.; Kleimenov, S.N.; Lopatin, S.N.; Ustinov, A.Yu., Photoelectron spectroscopy of aluminum, chromium, and iron tris-B-diketonates, Opt. Spectrosc., 1990, 69, 53. [all data]

Westmore, Reimer, et al., 1981
Westmore, J.B.; Reimer, M.L.J.; Reichert, C., Ionization energies of metal chelates. Acetylacetonates, trifluoroacetylacetonates, and hexafluoroacetylacetonates of trivalent metals of the first transition series, Can. J. Chem., 1981, 59, 1797. [all data]

Schildcrout, Pearson, et al., 1968
Schildcrout, S.M.; Pearson, R.G.; Stafford, F.E., Ionization potentials of tris(-diketonate)metal(III) complexes and Koopmans' theorem, J. Am. Chem. Soc., 1968, 90, 4006. [all data]

Bancroft, Reichert, et al., 1968
Bancroft, G.M.; Reichert, C.; Westmore, J.B., Mass spectral studies of metal chelates. II. Mass spectra and appearance potentials of acetylacetonates of trivalent metals of the first transition series, Inorg. Chem., 1968, 7, 870. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), NIST Free Links, References