Propanenitrile, 3,3'-thiobis-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid96.3 ± 5.0kJ/molCmGladstone and Chang, 1966Heat of formation derived by Cox and Pilcher, 1970

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tfus301.75KN/AGladstone and Chang, 1966, 2Uncertainty assigned by TRC = 0.3 K
Tfus301.7KN/AWitschonke, 1954Uncertainty assigned by TRC = 0.2 K
Tfus301.8KN/AWitschonke, 1954Uncertainty assigned by TRC = 0.15 K
Tfus295.25KN/AWitschonke, 1954Metastable crystal phase; Uncertainty assigned by TRC = 0.3 K

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Propanenitrile, 3,3'-thiobis- + 2Ammonia = 22-Propenenitrile + ammonium sulphide

By formula: C6H8N2S + 2H3N = 2C3H3N + ammonium sulphide

Quantity Value Units Method Reference Comment
Δr126.4 ± 2.5kJ/molCmGladstone and Chang, 1966liquid phase; Heat of formation derived by Cox and Pilcher, 1970

22-Propenenitrile + ammonium sulphide = Propanenitrile, 3,3'-thiobis- + 2Ammonia

By formula: 2C3H3N + ammonium sulphide = C6H8N2S + 2H3N

Quantity Value Units Method Reference Comment
Δr-126.4 ± 2.5kJ/molCmGladstone and Chang, 1966liquid phase

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Coblentz Society, Inc.

Condensed Phase Spectrum

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IR spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.

Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

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Owner COBLENTZ SOCIETY
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin STANDARD OIL OF OHIO
Source reference COBLENTZ NO. 3572
Date Not specified, most likely prior to 1970
Name(s) PROPANENITRILE, 3,3'-THIOBIS-
State LIQUID (NEAT)
Instrument PERKIN-ELMER 521 (GRATING)
Path length 0.0024 CM
Resolution 4
Sampling procedure TRANSMISSION
Data processing DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS)

This IR spectrum is from the Coblentz Society's evaluated infrared reference spectra collection.


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Due to licensing restrictions, this spectrum cannot be downloaded.

Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-1454
NIST MS number 229706

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gladstone and Chang, 1966
Gladstone, S.; Chang, H.Y., Determination of the standard heat of formation of 3,3'-thiodipropionitrile, J. Chem. Eng. Data, 1966, 11, 238-239. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Gladstone and Chang, 1966, 2
Gladstone, S.; Chang, H.-Y., Det. of the Standard Heat of Formation of 3,3'-Thiodipropionitrile, J. Chem. Eng. Data, 1966, 11, 238. [all data]

Witschonke, 1954
Witschonke, C.R., Freezing point and purity data for some organic compounds, Anal. Chem., 1954, 26, 562-4. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References