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Propiolactone

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-68.40kcal/molN/ADmitriev, Kotovich, et al., 1988Value computed using «DELTA»fHliquid° value of -333.2±1.2 kj/mol from Dmitriev, Kotovich, et al., 1988 and «DELTA»vapH° value of 47.0 kj/mol from Borjesson, Nakase, et al., 1966.; DRB
Deltafgas-67.61kcal/molN/AYevstroprov, Lebedev, et al., 1979Value computed using «DELTA»fHliquid° value of -329.9±0.8 kj/mol from Yevstroprov, Lebedev, et al., 1979 and «DELTA»vapH° value of 47.0 kj/mol from Borjesson, Nakase, et al., 1966.; DRB
Deltafgas-67.61 ± 0.20kcal/molCcrBorjesson, Nakase, et al., 1966ALS

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
9.281100.Kudchadker S.A., 1975Selected values are in close agreement with results of statistical calculation by [ Joshi R.M., 1970].; GT
10.72150.
12.53200.
15.81273.15
17.03298.15
17.12300.
21.89400.
26.018500.
29.402600.
32.165700.
34.448800.
36.355900.
37.9611000.
39.3261100.
40.4881200.
41.4821300.
42.3371400.
43.0761500.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dmitriev, Kotovich, et al., 1988
Dmitriev, Yu.G.; Kotovich, K.Z.; Kochubei, V.V.; Mineravina, L.O., Heats of combustion of alkyl derivatives of «beta»-propiolactones, Vestn. L'vov. Politekhn. Inst., 1988, 221, 34-35. [all data]

Borjesson, Nakase, et al., 1966
Borjesson, B.; Nakase, Y.; Sunner, S., The heat of combustion and polymerization of «beta»-propiolactone, Acta Chem. Scand., 1966, 20, 803-810. [all data]

Yevstroprov, Lebedev, et al., 1979
Yevstroprov, A.A.; Lebedev, B.V.; Kulagina, T.G.; Lyudvig, Ye.B.; Belenkaya, B.G., The thermodynamic proerties of «beta»-propiolactone, its polymer, and its polymerization in the 0-400°K range, Polym. Sci. USSR, 1979, 21, 2249-2256. [all data]

Kudchadker S.A., 1975
Kudchadker S.A., Thermodynamic properties of oxygen compounds. II. beta-Propiolactone, gamma-butyrolactone, and gamma-butyrolactam (2-pyrrolidone), Thermochim. Acta, 1975, 12, 11-17. [all data]

Joshi R.M., 1970
Joshi R.M., Thermodynamic properties of some monomeric compounds in the standard ideal gas state, J. Polym. Sci., Part A-2, 1970, 8, 679-687. [all data]


Notes

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