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Nitrogen cation


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
gas,1 bar197.65J/mol*KReviewChase, 1998Data last reviewed in September, 1977

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Nitrogen cation + Nitrogen = (Nitrogen cation bullet Nitrogen)

By formula: N2+ + N2 = (N2+ bullet N2)

Quantity Value Units Method Reference Comment
Deltar102. - 102.kJ/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase
Deltar67.8J/mol*KPHPMSTeng and Conway, 1973gas phase
Deltar81.6J/mol*KPHPMSPayzant and Kebarle, 1970gas phase
Deltar46.J/mol*KDTVarney, 1968gas phase; Entropy change is questionable
Deltar-4.J/mol*KDTVarney, 1959gas phase; Entropy change is questionable

Nitrogen cation + Argon = (Nitrogen cation bullet Argon)

By formula: N2+ + Ar = (N2+ bullet Ar)

Quantity Value Units Method Reference Comment
Deltar112.kJ/molPD/KERDKim and Bowers, 1990gas phase; switching reaction(N2+)N2; Hiraoka and Nakajima, 1988
Deltar106.kJ/molPHPMSTeng and Conway, 1973gas phase; switching reaction(N2+)N2
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPD/KERDKim and Bowers, 1990gas phase; switching reaction(N2+)N2; Hiraoka and Nakajima, 1988
Deltar57.3J/mol*KPHPMSTeng and Conway, 1973gas phase; switching reaction(N2+)N2

(Nitrogen cation bullet 7Argon) + Argon = (Nitrogen cation bullet 8Argon)

By formula: (N2+ bullet 7Ar) + Ar = (N2+ bullet 8Ar)

Quantity Value Units Method Reference Comment
Deltar6.40kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KN/AHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated

(Nitrogen cation bullet 8Argon) + Argon = (Nitrogen cation bullet 9Argon)

By formula: (N2+ bullet 8Ar) + Ar = (N2+ bullet 9Ar)

Quantity Value Units Method Reference Comment
Deltar6.36kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KN/AHiraoka, Mori, et al., 1992gas phase; Entropy change calculated or estimated

(Nitrogen cation bullet Nitrogen) + Nitrogen = (Nitrogen cation bullet 2Nitrogen)

By formula: (N2+ bullet N2) + N2 = (N2+ bullet 2N2)

Quantity Value Units Method Reference Comment
Deltar11.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Deltar5.9kJ/molPILinn, Ono, et al., 1981gas phase
Quantity Value Units Method Reference Comment
Deltar62.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet Argon) + Argon = (Nitrogen cation bullet 2Argon)

By formula: (N2+ bullet Ar) + Ar = (N2+ bullet 2Ar)

Quantity Value Units Method Reference Comment
Deltar16.kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase; «DELTA»rH>
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase; «DELTA»rH>

(Nitrogen cation bullet 10Nitrogen) + Nitrogen = (Nitrogen cation bullet 11Nitrogen)

By formula: (N2+ bullet 10N2) + N2 = (N2+ bullet 11N2)

Quantity Value Units Method Reference Comment
Deltar6.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 9Nitrogen) + Nitrogen = (Nitrogen cation bullet 10Nitrogen)

By formula: (N2+ bullet 9N2) + N2 = (N2+ bullet 10N2)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar86.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 2Nitrogen) + Nitrogen = (Nitrogen cation bullet 3Nitrogen)

By formula: (N2+ bullet 2N2) + N2 = (N2+ bullet 3N2)

Quantity Value Units Method Reference Comment
Deltar11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar66.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 3Nitrogen) + Nitrogen = (Nitrogen cation bullet 4Nitrogen)

By formula: (N2+ bullet 3N2) + N2 = (N2+ bullet 4N2)

Quantity Value Units Method Reference Comment
Deltar10.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar69.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 4Nitrogen) + Nitrogen = (Nitrogen cation bullet 5Nitrogen)

By formula: (N2+ bullet 4N2) + N2 = (N2+ bullet 5N2)

Quantity Value Units Method Reference Comment
Deltar10.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 5Nitrogen) + Nitrogen = (Nitrogen cation bullet 6Nitrogen)

By formula: (N2+ bullet 5N2) + N2 = (N2+ bullet 6N2)

Quantity Value Units Method Reference Comment
Deltar9.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 6Nitrogen) + Nitrogen = (Nitrogen cation bullet 7Nitrogen)

By formula: (N2+ bullet 6N2) + N2 = (N2+ bullet 7N2)

Quantity Value Units Method Reference Comment
Deltar8.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 7Nitrogen) + Nitrogen = (Nitrogen cation bullet 8Nitrogen)

By formula: (N2+ bullet 7N2) + N2 = (N2+ bullet 8N2)

Quantity Value Units Method Reference Comment
Deltar7.8 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar80.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 8Nitrogen) + Nitrogen = (Nitrogen cation bullet 9Nitrogen)

By formula: (N2+ bullet 8N2) + N2 = (N2+ bullet 9N2)

Quantity Value Units Method Reference Comment
Deltar7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase

(Nitrogen cation bullet 2Argon) + Argon = (Nitrogen cation bullet 3Argon)

By formula: (N2+ bullet 2Ar) + Ar = (N2+ bullet 3Ar)

Quantity Value Units Method Reference Comment
Deltar7.3 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar57.3J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 3Argon) + Argon = (Nitrogen cation bullet 4Argon)

By formula: (N2+ bullet 3Ar) + Ar = (N2+ bullet 4Ar)

Quantity Value Units Method Reference Comment
Deltar7.0 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar74.9J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 4Argon) + Argon = (Nitrogen cation bullet 5Argon)

By formula: (N2+ bullet 4Ar) + Ar = (N2+ bullet 5Ar)

Quantity Value Units Method Reference Comment
Deltar6.6 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar71.1J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 5Argon) + Argon = (Nitrogen cation bullet 6Argon)

By formula: (N2+ bullet 5Ar) + Ar = (N2+ bullet 6Ar)

Quantity Value Units Method Reference Comment
Deltar6.5 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar72.8J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

(Nitrogen cation bullet 6Argon) + Argon = (Nitrogen cation bullet 7Argon)

By formula: (N2+ bullet 6Ar) + Ar = (N2+ bullet 7Ar)

Quantity Value Units Method Reference Comment
Deltar6.4 ± 0.8kJ/molPHPMSHiraoka, Mori, et al., 1992gas phase
Quantity Value Units Method Reference Comment
Deltar72.4J/mol*KPHPMSHiraoka, Mori, et al., 1992gas phase

Nitrogen cation + helium = (Nitrogen cation bullet helium)

By formula: N2+ + He = (N2+ bullet He)

Quantity Value Units Method Reference Comment
Deltar2.kJ/molPDissBieske, Soliva, et al., 1990gas phase; same «DELTA»rH for N2+(B) and (N2+)X; ab initio, Miller, Tennyson, et al., 1988

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Hiraoka and Nakajima, 1988
Hiraoka, K.; Nakajima, G., A Determination of the Stabilities of N2+(N2)n and O2+(N2)n with n = 1 - 11 from Measurements of the Gas - Phase Ion Equilibria, J. Chem. Phys., 1988, 88, 12, 7709, https://doi.org/10.1063/1.454285 . [all data]

Teng and Conway, 1973
Teng, H.H.; Conway, D.C., Ion - Molecule Equilibria in Mixtures of N2 and Ar, J. Chem. Phys., 1973, 59, 5, 2316, https://doi.org/10.1063/1.1680338 . [all data]

Payzant and Kebarle, 1970
Payzant, J.D.; Kebarle, P., Clustering Equilibrium N2+ + 2N2 = N4+ + N2 and the Bond Dissociation Energy of N4+, J. Chem. Phys., 1970, 53, 12, 4723, https://doi.org/10.1063/1.1674010 . [all data]

Varney, 1968
Varney, R.N., Equilibrium Constant and Rates for the Reversible Reaction N4+ -> N2+ + N2, Phys. Rev., 1968, 174, 1, 165, https://doi.org/10.1103/PhysRev.174.165 . [all data]

Varney, 1959
Varney, R.N., Molecular Ions, J. Chem. Phys., 1959, 31, 5, 1314, https://doi.org/10.1063/1.1730590 . [all data]

Kim and Bowers, 1990
Kim, H.S.; Bowers, M.T., Energetics, Structure and Photodissociation Dynamics of the Cluster Ar.N2+, J. Chem. Phys., 1990, 93, 2, 1158, https://doi.org/10.1063/1.459179 . [all data]

Hiraoka, Mori, et al., 1992
Hiraoka, K.; Mori, T.; Yamabe, S., Gas-Phase Solvation of N2+ with Ar Atoms - A Charge Switch in the Reaction N2+(Ar)...Ar+(N2), Chem. Phys. Lett., 1992, 189, 1, 7, https://doi.org/10.1016/0009-2614(92)85144-Y . [all data]

Linn, Ono, et al., 1981
Linn, S.H.; Ono, Y.; Ng, C.Y., Molecular Beam Photoionization Study of CO, N2, and NO Dimers and Clusters, J. Chem. Phys., 1981, 74, 6, 3342, https://doi.org/10.1063/1.441486 . [all data]

Bieske, Soliva, et al., 1990
Bieske, E.J.; Soliva, A.; Welker, M.A.; Maier, J.P., The B<---X Electronic Spectrum of N2+ He, J. Chem. Phys., 1990, 93, 6, 4477, https://doi.org/10.1063/1.458732 . [all data]

Miller, Tennyson, et al., 1988
Miller, S.; Tennyson, J.; Follmeg, B.; Rosmus, P.; Werner, H., Ab initio Investigation of the Bond Rovibrational States in the Electronic Ground State of HeN2+, J. Chem. Phys., 1988, 89, 4, 2178, https://doi.org/10.1063/1.455062 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, References