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Phenyl trichlorosilane

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil474.KN/APCR Inc., 1990BS
Quantity Value Units Method Reference Comment
Ttriple233.4KN/AGumbatov and Kostryukov, 1965Uncertainty assigned by TRC = 0.2 K; TRC

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
12.2348.N/ASokolov, Karapet'yants, et al., 1970Based on data from 333. - 453. K.; AC
11.4390.IJenkins and Chambers, 1954Based on data from 375. - 470. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference
374.8 - 470.64.10261641.-74.Jenkins and Chambers, 1954

Enthalpy of fusion

DeltafusH (kcal/mol) Temperature (K) Reference Comment
2.7868233.4Gumbatov and Kostrykov, 1965Smoothed table gives H = 11650 J/mol.; DH
2.787233.4Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (cal/mol*K) Temperature (K) Reference Comment
11.94233.4Gumbatov and Kostrykov, 1965Smoothed; DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

PCR Inc., 1990
PCR Inc., Research Chemicals Catalog 1990-1991, PCR Inc., Gainesville, FL, 1990, 1. [all data]

Gumbatov and Kostryukov, 1965
Gumbatov, D.O.; Kostryukov, V.N., Thermodynamic studies at low temperatures. The specific heat, entropy, enthalpy, and internal rotation potential of C6H5SiCl3, Zh. Fiz. Khim., 1965, 39, 116-22. [all data]

Sokolov, Karapet'yants, et al., 1970
Sokolov, V.B.; Karapet'yants, M.Kh.; Goncharov, A.K., Tr. Mosk. Khim. Tekhnol. Inst., 1970, 67, 37. [all data]

Jenkins and Chambers, 1954
Jenkins, Arthur C.; Chambers, George F., Vapor Pressures of Silicon Compounds, Ind. Eng. Chem., 1954, 46, 11, 2367-2369, https://doi.org/10.1021/ie50539a043 . [all data]

Gumbatov and Kostrykov, 1965
Gumbatov, D.O.; Kostrykov, V.N., Thermodynamic studies at low temperatures. The specific heat, entropy, enthalpy, and internal rotation potential of C6H5SiCl3, Zhur. Fiz. Khim., 1965, 39, 116-122. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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