Pentanedinitrile

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil559.2KN/AWeast and Grasselli, 1989BS
Tboil559.35KN/APerkin, 1889Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Tfus243.6KN/AVan de Vloed, 1939Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Ttriple244.21KN/AClever, Wulff, et al., 1965Uncertainty assigned by TRC = 0.02 K; TRC

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
60.1379.AStephenson and Malanowski, 1987Based on data from 364. - 560. K.; AC
66.8290.AStephenson and Malanowski, 1987Based on data from 277. - 303. K. See also Dykyj, 1972 and Woodman, Murbach, et al., 1960.; AC

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
12.585244.21N/AClever, Wulff, et al., 1965, 2DH
12.03242.DSCBadea, Blanco, et al., 2007AC
12.59244.2N/ADomalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
51.53244.21Clever, Wulff, et al., 1965, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Perkin, 1889
Perkin, W.H., The Magneto Rotatory Power of Nitrogne Compounds. also of Hydrochloric Hydrobromic and Hydroioidic Acids and of some of the Salts of Ammonia and the Compound Ammonias, J. Chem. Soc., 1889, 55, 680. [all data]

Van de Vloed, 1939
Van de Vloed, A., Bull. Soc. Chim. Belg., 1939, 48, 229. [all data]

Clever, Wulff, et al., 1965
Clever, H.L.; Wulff, C.A.; Westrum, E.F., Glutaronitrile. Calorimetrically Determined Thermal Properties from 5 to 350 K and Statistical Gaseous Entropy, J. Phys. Chem., 1965, 69, 1983. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Woodman, Murbach, et al., 1960
Woodman, A.L.; Murbach, W.J.; Kaufman, M.H., Vapor pressure and viscosity relationships for a homologous series of α,omega-dinitriles, Russ. J. Phys. Chem. (Engl. Transl.), 1960, 64, 658-660. [all data]

Clever, Wulff, et al., 1965, 2
Clever, H.L.; Wulff, C.A.; Westrum, E.F., Jr., Glutaronitrile. Calorimetrically determined thermal properties from 5 to 350°K. and statisticall gaseous entropy, J. Phys. Chem., 1965, 69, 1983-1988. [all data]

Badea, Blanco, et al., 2007
Badea, Elena; Blanco, Ignazio; Della Gatta, Giuseppe, Fusion and solid-to-solid transitions of a homologous series of alkane-α,ω-dinitriles, The Journal of Chemical Thermodynamics, 2007, 39, 10, 1392-1398, https://doi.org/10.1016/j.jct.2007.03.005 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

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