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Furan, 2-methyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Glushko Thermocenter, Russian Academy of Sciences, Moscow

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
36.6450.Thermodynamics Research Center, 1997p=1 bar. Selected entropy and heat capacity at 298.15 K are in close agreement with statistical values calculated by [ Green J.H.S., 1977].
45.61100.
54.15150.
64.27200.
82.78273.15
89.66298.15
90.17300.
117.24400.
140.76500.
160.06600.
175.83700.
188.90800.
199.87900.
209.151000.
217.061100.
223.831200.
229.651300.
234.681400.
239.031500.

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
liquid213.89J/mol*KN/ACarlson and Westrum, 1965 

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
143.72298.15Carlson and Westrum, 1965T = 5 to 310 K.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil337. ± 1.KAVGN/AAverage of 10 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple181.9KN/ACarlson and Westrum, 1965, 2Uncertainty assigned by TRC = 0.1 K; TRC
Ttriple181.90KN/ACarlson, 1962Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc528.KN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Pc47.20barN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 1.034 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.247l/molN/AKobe, Ravicz, et al., 1956Uncertainty assigned by TRC = 0.005 l/mol; TRC
Quantity Value Units Method Reference Comment
Deltavap32.2kJ/molN/AMoiseev and Antonova, 1970Based on data from 215. - 360. K.; AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
32.4304.N/ALoras, Aucejo, et al., 2002Based on data from 289. - 337. K.; AC
34.4266.AStephenson and Malanowski, 1987Based on data from 251. - 338. K.; AC
31.5324.N/AKrevor and Prausnitz, 1986Based on data from 309. - 339. K.; AC
32.5295.N/ADykyj, 1972Based on data from 288. - 303. K.; AC
30.9348.N/AEon, Pommier, et al., 1971Based on data from 333. - 373. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
333.4 - 373.54.815281643.0823.234Eon, Pommier, et al., 1971Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
8.552181.90Carlson and Westrum, 1965DH
8.55181.9Carlson and Westrum, 1965AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
47.01181.90Carlson and Westrum, 1965DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C5H5O- + Hydrogen cation = Furan, 2-methyl-

By formula: C5H5O- + H+ = C5H6O

Quantity Value Units Method Reference Comment
Deltar1606. ± 13.kJ/molG+TSDePuy, Kass, et al., 1988gas phase; Anion of 2-methylfuran. Order: H2O<furan<2-Me-furan<MeOH.; B
Quantity Value Units Method Reference Comment
Deltar1577. ± 13.kJ/molIMRBDePuy, Kass, et al., 1988gas phase; Anion of 2-methylfuran. Order: H2O<furan<2-Me-furan<MeOH.; B

Maleic anhydride + Furan, 2-methyl- = 7-Oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic anhydride, 1-methyl-, exo

By formula: C4H2O3 + C5H6O = C9H8O4

Quantity Value Units Method Reference Comment
Deltar-58.5kJ/molCmBalbi, 1991liquid phase; solvent: Dioxane; ALS
Deltar-60.kJ/molCmSparks and Poling, 1983solid phase; solvent: Dioxane; ALS

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Sadtler Research Labs Under US-EPA Contract
State gas

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

View image of digitized spectrum (can be printed in landscape orientation).

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW- 692
NIST MS number 229471

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Thermodynamics Research Center, 1997
Thermodynamics Research Center, Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]

Green J.H.S., 1977
Green J.H.S., Spectroscopic and thermodynamic properties of furan derivatives. I. 2- and 2,5-substituted compounds, Spectrochim. Acta, 1977, A33, 843-848. [all data]

Carlson and Westrum, 1965
Carlson, H.G.; Westrum, E.F., Jr., 2-Methylfuran. Heat capacity and thermodynamic properties from 5 to 310 K, J. Chem. Eng. Data, 1965, 10, 134-135. [all data]

Carlson and Westrum, 1965, 2
Carlson, H.G.; Westrum, E.F., Jr., 2-Methylfuran-Heat Capacity and Thermodynamic Properties from 5°to 310° K., J. Chem. Eng. Data, 1965, 10, 2, 134, https://doi.org/10.1021/je60025a018 . [all data]

Carlson, 1962
Carlson, , Ph.D. Thesis, Univ. Mich., Ann Arbor, MI, 1962. [all data]

Kobe, Ravicz, et al., 1956
Kobe, K.A.; Ravicz, A.E.; Vohra, S.P., Critical Properties and Vapor Pressures of Some Ethers and Heterocyclic Compounds, J. Chem. Eng. Data, 1956, 1, 50. [all data]

Moiseev and Antonova, 1970
Moiseev, V.D.; Antonova, N.D., Zh. Fiz. Khim., 1970, 44, 11, 2912. [all data]

Loras, Aucejo, et al., 2002
Loras, Sonia; Aucejo, Antonio; Montón, Juan B.; Wisniak, Jaime; Segura, Hugo, Phase Equilibria for 1,1,1,2,3,4,4,5,5,5-Decafluoropentane + 2-Methylfuran, 2-Methylfuran + Oxolane, and 1,1,1,2,3,4,4,5,5,5- Decafluoropentane + 2-Methylfuran + Oxolane at 35 kPa, J. Chem. Eng. Data, 2002, 47, 5, 1256-1262, https://doi.org/10.1021/je0255325 . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Krevor and Prausnitz, 1986
Krevor, David H.; Prausnitz, John M., Vapor-liquid equilibria for model mixtures of coal-derived liquids. 1. Binary systems with 2-methylfuran, J. Chem. Eng. Data, 1986, 31, 3, 349-353, https://doi.org/10.1021/je00045a027 . [all data]

Dykyj, 1972
Dykyj, J., Petrochemia, 1972, 12, 1, 13. [all data]

Eon, Pommier, et al., 1971
Eon, C.; Pommier, C.; Guiochon, G., Vapor pressures and second virial coefficients of some five-membered heterocyclic derivatives, J. Chem. Eng. Data, 1971, 16, 4, 408-410, https://doi.org/10.1021/je60051a008 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

DePuy, Kass, et al., 1988
DePuy, C.H.; Kass, S.R.; Bean, G.P., Formation and Reactions of Heteroaromatic Anions in the Gas Phase, J. Org. Chem., 1988, 53, 19, 4427, https://doi.org/10.1021/jo00254a001 . [all data]

Balbi, 1991
Balbi, N., Dynamic calorimetry in the study of Diels-Alder reaction, Calorim. Anal. Therm., 1991, 22, 299-304. [all data]

Sparks and Poling, 1983
Sparks, B.G.; Poling, B.E., Energy storage capacity of reversible liquid-phase Diels Alder reaction between maleic anhydride and 2-methyl furan, Am. Inst. Chem. Eng. Symp. Ser. (AIChE Symp. Ser.), 1983, 29, 534-537. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References