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3-Azabicyclo[3.2.2]nonane

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-43.68 ± 0.79kJ/molCcrWong and Westrum, 1971see Westrum and Wong, 1967

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafsolid-101.6 ± 0.67kJ/molCcrWong and Westrum, 1971see Westrum and Wong, 1967; ALS
Quantity Value Units Method Reference Comment
Deltacsolid-5190.29 ± 0.67kJ/molCcrWong and Westrum, 1971see Westrum and Wong, 1967; ALS
Quantity Value Units Method Reference Comment
solid,1 bar245.73J/mol*KN/ABarber and Westrum, 1963DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
237.8350.Wulff and Westrum, 1964T = 330 to 490 K.; DH
239.03310.Barber and Westrum, 1963T = 5 to 350 K. Transition too close to 298.15 K to allow meaningful value of Cp.; DH

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DRB - Donald R. Burgess, Jr.
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Ttriple467.12KN/AWulff and Westrum, 1964, 2Crystal phase 1 phase; Uncertainty assigned by TRC = 0.01 K; TRC
Quantity Value Units Method Reference Comment
Deltasub57.9kJ/molN/AWong and Westrum, 1971DRB
Deltasub57.8 ± 1.3kJ/molCWestrum, Wong, et al., 1970AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
52.2318.AStephenson and Malanowski, 1987Based on data from 303. - 443. K.; AC

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
6.92466.6Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
48.87297.8Domalski and Hearing, 1996CAL
14.82466.6

Enthalpy of phase transition

DeltaHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
6.916467.12crystaline, IliquidWulff and Westrum, 1964DH
14.481297.78crystaline, IIcrystaline, IBarber and Westrum, 1963DH

Entropy of phase transition

DeltaStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
14.81467.12crystaline, IliquidWulff and Westrum, 1964DH
48.63297.78crystaline, IIcrystaline, IBarber and Westrum, 1963DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-IW- 82
NIST MS number 239289

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wong and Westrum, 1971
Wong, S.S.; Westrum, E.F., Jr., Enthalpies of formation of globular molecules. II. Three bicyclooctanes and two bicyclononanes, J. Am. Chem. Soc., 1971, 93, 5317-5321. [all data]

Westrum and Wong, 1967
Westrum, E.F., Jr.; Wong, S., Strain energies and thermal properties of globular and polynuclear aromatic molecules, AEC Rept. Coo-1149-92, Contract AT(11-1)-1149, 1967, 1-7. [all data]

Barber and Westrum, 1963
Barber, C.M.; Westrum, E.F., Jr., Heat capacities and thermodynamic properties of globular molecules. V. 3-Azabicyclo-[3,3,2]nonane from 5 to 350 K, J. Phys. Chem., 1963, 67, 2373-2376. [all data]

Wulff and Westrum, 1964
Wulff, C.A.; Westrum, E.F., Jr., Heat capacities and thermodynamic properties of globular molecules. XI. Melting of 3-azabicyclo[3,2,2]nonane, J. Phys. Chem., 1964, 68, 430-431. [all data]

Wulff and Westrum, 1964, 2
Wulff, C.A.; Westrum, E.F., Heat capacities and thermodynamic properties of globular molecules. XI. Melting of 3-azabicyclo[3.2.2]nonane, J. Phys. Chem., 1964, 68, 430. [all data]

Westrum, Wong, et al., 1970
Westrum, E.F., Jr.; Wong, W-K.; Morawetz, E., Thermodynamics of globular molecules. XVIII. Heat capacities and transitional behavior of 1-azabicyclo[2.2.2]octane and 3-oxabicyclo[3.2.2]nonane. Sublimation behavior of five globular molecules, J. Phys. Chem., 1970, 74, 2542-2547. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References