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2-Butanone

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-273.3 ± 1.2kJ/molCcbSinke and Oetting, 1964ALS
Deltafliquid-279.0kJ/molCcbParks, Mosley, et al., 1950see Moore, Renquist, et al., 1940; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-2444.2kJ/molCcbSinke and Oetting, 1964Corresponding «DELTA»fliquid = -273.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2438.4kJ/molCcbParks, Mosley, et al., 1950see Moore, Renquist, et al., 1940; Corresponding «DELTA»fliquid = -278.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-2436.3 ± 1.5kJ/molCcbCrog and Hunt, 1942Corresponding «DELTA»fliquid = -281.1 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid239.0J/mol*KN/AAndon, Counsell, et al., 1968DH
liquid238.82J/mol*KN/ASinke and Oetting, 1964DH
liquid241.4J/mol*KN/AParks, Kennedy, et al., 1956Extrapolation below 80 K, 53.47 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
159.298.15Malhotra and Woolf, 1992T = 278 to 338 K. p = 0.1 MPa.; DH
162.2303.15Reddy, 1986T = 303.15, 313.15 K.; DH
158.4298.15Costas and Patterson, 1985T = 283.15, 298.15, 313.15 K.; DH
158.4298.15Costas and Patterson, 1985, 2DH
157.91298.15Grolier and Benson, 1984DH
158.4298.1Roux, Perron, et al., 1978T = 277 to 313 K.; DH
159.2298.15Grolier, Benson, et al., 1975DH
158.7298.15Andon, Counsell, et al., 1968T = 10 to 320 K.; DH
158.0293.Rastorguev and Ganiev, 1967T = 293 to 353 K.; DH
158.91298.15Sinke and Oetting, 1964T = 13 to 308 K.; DH
158.41298.15Parks, Kennedy, et al., 1956T = 80 to 300 K.; DH
160.7297.0Kolosovskii and Udovenko, 1934DH
160.7297.0de Kolossowsky and Udowenko, 1933DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sinke and Oetting, 1964
Sinke, G.C.; Oetting, F.L., The chemical thermodynamic properties of methyl ethyl ketone, J. Phys. Chem., 1964, 68, 1354-1358. [all data]

Parks, Mosley, et al., 1950
Parks, G.S.; Mosley, J.R.; Peterson, P.V., Jr., Heats of combustion and formation of some organic compounds containing oxygen, J. Chem. Phys., 1950, 18, 152. [all data]

Moore, Renquist, et al., 1940
Moore, G.E.; Renquist, M.L.; Parks, G.S., Thermal data on organic compounds. XX. Modern combustion data for two methylnonanes, methyl ethyl ketone, thiophene and six cycloparaffins, J. Am. Chem. Soc., 1940, 62, 1505-1507. [all data]

Crog and Hunt, 1942
Crog, R.S.; Hunt, H., Heats of combustion. II. The heats of combustion of ethyl methyl ketone and ethylene oxide, J. Phys. Chem., 1942, 46, 1162-1163. [all data]

Andon, Counsell, et al., 1968
Andon, R.J.L.; Counsell, J.F.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. Part XX. The low-temperature heat capacity and entropy of C4 and C5 ketones, J. Chem. Soc. A, 1968, 1894-1897. [all data]

Parks, Kennedy, et al., 1956
Parks, G.S.; Kennedy, W.D.; Gates, R.R.; Mosley, J.R.; Moore, G.E.; Renquist, M.L., Thermal data on organic compounds. XXVI. Some heat capacity, entropy and free energy data for seven compounds containing oxygen., Not In System, 1956, 78, 56-59. [all data]

Malhotra and Woolf, 1992
Malhotra, R.; Woolf, L.A., Thermodynamic properties of butan-2-one at temperatures from 278 to 338 K and pressures from 0.1 MPa to 280 MPa; predictions for higher ketones, J. Chem. Thermodynam., 1992, 24, 1207-1217. [all data]

Reddy, 1986
Reddy, K.S., Isentropic compressibilities of binary liquid mixtures at 303.15 and 313.15 K, J. Chem. Eng. Data, 1986, 31, 238-240. [all data]

Costas and Patterson, 1985
Costas, M.; Patterson, D., Heat capacities of water + organic-solvent mixtures, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 2381-2398. [all data]

Costas and Patterson, 1985, 2
Costas, M.; Patterson, D., Self-association of alcohols in inert solvents, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 635-654. [all data]

Grolier and Benson, 1984
Grolier, J.-P.E.; Benson, G.C., Thermodynamic properties of binary mixtures containing ketones. VIII. Heat capacities and volumes of some n-alkanone + n-alkane mixtures at 298.15 K, Can. J. Chem., 1984, 62, 949-953. [all data]

Roux, Perron, et al., 1978
Roux, G.; Perron, G.; Desnoyers, J.E., The heat capacities and volumes of some low molecular weight amides, ketones, esters, and ethers in water over the whole solubility range, Can. J. Chem., 1978, 56, 2808-2814. [all data]

Grolier, Benson, et al., 1975
Grolier, J-P.E.; Benson, G.C.; Picker, P., Simultaneous measurements of heat capacities and densities of organic liquid mixtures-systems containing ketones, J. Chem. Eng. Data, 1975, 20, 243-246. [all data]

Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A., Study of the heat capacity of selected solvents, Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]

Kolosovskii and Udovenko, 1934
Kolosovskii, N.A.; Udovenko, W.W., Specific heat of liquids. II., Zhur. Obshchei Khim., 1934, 4, 1027-1033. [all data]

de Kolossowsky and Udowenko, 1933
de Kolossowsky, N.A.; Udowenko, W.W., Mesure des chaleurs specifique moleculaires de quelques liquides, Compt. rend., 1933, 197, 519-520. [all data]


Notes

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