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Diphenyl disulfone


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-481.3 ± 4.5kJ/molCcrMackle and O'Hare, 1964Reanalyzed by Cox and Pilcher, 1970, Original value = -481. ± 4. kJ/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafsolid-643.2 ± 1.6kJ/molCcrMackle and O'Hare, 1964Reanalyzed by Cox and Pilcher, 1970, Original value = -642.8 ± 1.5 kJ/mol
Quantity Value Units Method Reference Comment
Deltacsolid-6712.6 ± 1.4kJ/molCcrMackle and O'Hare, 1964 

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Diphenyl disulfone + Water = Benzenesulfinic-acid- + Benzenesulfonic acid

By formula: C12H10O4S2 + H2O = C6H6O2S + C6H6O3S

Quantity Value Units Method Reference Comment
Deltar-68. ± 10.kJ/molCmKice, Margolis, et al., 1977solid phase; solvent: Water; Hydrolysis

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Mackle and O'Hare, 1964
Mackle, H.; O'Hare, P.A.G., Studies in the thermochemistry of sulphones. Part 8.-Heats of combustion and formation of diphenyl disulphone, Trans. Faraday Soc., 1964, 60, 506-509. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Kice, Margolis, et al., 1977
Kice, J.L.; Margolis, H.C.; Johnson, W.S.; Wulff, C.A., Heats of hydrolysis of phenyl «alpha»-disulfone and phenyl benzenesulfinyl sulfone, J. Org. Chem., 1977, 42, 2933-2935. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References