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boron fluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to BF+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)11.12 ± 0.01eVN/AN/AL

Ionization energy determinations

IE (eV) Method Reference Comment
11.0 ± 1.0EIFarber and Srivastava, 1984LBLHLM
11.12 ± 0.01PEDyke, Kirby, et al., 1983LBLHLM
11.115EVALHuber and Herzberg, 1979LLK
12. ± 1.EIUy, Srivastava, et al., 1971LLK
11.06 ± 0.10EIHildenbrand, 1971LLK
~11.45SHildenbrand, 1971LLK
11.115 ± 0.003SCaton and Douglas, 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Farber and Srivastava, 1984
Farber, M.; Srivastava, R.D., Electron and thermal dissociation of BF3(g), J. Chem. Phys., 1984, 81, 241. [all data]

Dyke, Kirby, et al., 1983
Dyke, J.M.; Kirby, C.; Morris, A., Study of the ionization process BF+ (X2«SIGMA»+)<--BF(X1«SIGMA»+) by high-temperature photolectron spectroscopy, J. Chem. Soc. Faraday Trans. 2, 1983, 79, 483. [all data]

Huber and Herzberg, 1979
Huber, K.P.; Herzberg, G., Molecular Spectra and Molecular Structure. IV. Constants of Diatomic Molecules,, Van Nostrand Reinhold Co., 1979, ,1. [all data]

Uy, Srivastava, et al., 1971
Uy, O.M.; Srivastava, R.D.; Farber, M., Mass spectrometric determination of the heats of formation of gaseous BO2 BOF2, High Temp. Sci., 1971, 3, 462. [all data]

Hildenbrand, 1971
Hildenbrand, D.L., First ionization potentials of the molecules BF, SiO and GeO, Intern. J. Mass Spectrom. Ion Phys., 1971, 7, 255. [all data]

Caton and Douglas, 1970
Caton, R.B.; Douglas, A.E., Electronic spectrum of the BF molecule, Can. J. Phys., 1970, 48, 432. [all data]


Notes

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