Undecafluoropiperidine

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Δfliquid-495.1 ± 1.1kcal/molCcbGood, Todd, et al., 1963Reanalyzed by Cox and Pilcher, 1970, Original value = -482.94 kcal/mol; Heat of combustion corrected for CF4 formation; ALS
Δfliquid-482.9kcal/molCcrGood and Scott, 1959Private communication; ALS
Quantity Value Units Method Reference Comment
Δcliquid-349.8 ± 0.8kcal/molCcbGood, Todd, et al., 1963Heat of combustion corrected for CF4 formation; ALS
Quantity Value Units Method Reference Comment
liquid94.020cal/mol*KN/AGood, Todd, et al., 1963DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
70.930298.15Good, Todd, et al., 1963T = 12 to 320 K.; DH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Good, Todd, et al., 1963
Good, W.D.; Todd, S.S.; Messerly, J.F.; Lacina, J.L.; Dawson, J.P.; Scott, D.W.; McCullough, J.P., Perfluoropiperidine: Entropy, heat of formation, and vapor pressure; N-F bond energy; and solid-state transitions, J. Phys. Chem., 1963, 67, 1306-1311. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Good and Scott, 1959
Good, W.D.; Scott, D.W., Thermochemistry of organic fluorine compounds and carbon compounds of metals by rotating-bomb calorimetry, Symposium uber Thermodynamik, Freitag, 1959, 1-7. [all data]


Notes

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