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Carbon disulfide

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas116.94kJ/molReviewChase, 1998Data last reviewed in December, 1976
Deltafgas117.1 ± 0.79kJ/molCcrGood, Lacina, et al., 1961ALS
Quantity Value Units Method Reference Comment
Deltacgas-1112.kJ/molCcbGuerin, Marthe, et al., 1949ALS
Quantity Value Units Method Reference Comment
gas,1 bar237.98J/mol*KReviewChase, 1998Data last reviewed in December, 1976

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. - 1000.1000. - 6000.
A 35.8539161.25292
B 52.491211.378826
C -40.83743-0.140520
D 12.001550.009284
E -0.224831-3.244044
F 103.503090.07106
G 266.1597299.4091
H 116.9432116.9432
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in December, 1976 Data last reviewed in December, 1976

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid89.41 ± 0.71kJ/molCcrGood, Lacina, et al., 1961ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1687.2 ± 0.50kJ/molCcrGood, Lacina, et al., 1961Reanalyzed by Cox and Pilcher, 1970, Original value = -1682.3 ± 0.50 kJ/mol; ALS
Quantity Value Units Method Reference Comment
liquid151.0J/mol*KN/ABrown and Manov, 1937DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
78.99298.Staveley, Tupman, et al., 1955T = 286 to 317 K.; DH
74.89294.81Zhdanov, 1945T = 7 to 31°C. Value is unsmoothed experimental datum.; DH
77.8293.Mazur, 1939T = -100 to 20°C.; DH
76.1301.2Phillip, 1939DH
76.02297.43Brown and Manov, 1937T = 15 to 297 K. Value is unsmoothed experimental datum.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil319.2 ± 0.6KAVGN/AAverage of 13 out of 14 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus161. ± 3.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple161.11KN/ABrown and Manov, 1937, 2Uncertainty assigned by TRC = 0.02 K; TRC
Ttriple161.59KN/AStull, 1937Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Tc552.KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Deltavap27.5 ± 0.6kJ/molAVGN/AAverage of 6 values; Individual data points

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
26.74319.4N/AMajer and Svoboda, 1985 
28.7270.N/ADykyj, Svoboda, et al., 1999Based on data from 255. - 354. K.; AC
27.1369.N/ADykyj, Svoboda, et al., 1999Based on data from 354. - 552. K.; AC
28.5275.AStephenson and Malanowski, 1987Based on data from 260. - 353. K.; AC
27.4353.AStephenson and Malanowski, 1987Based on data from 338. - 408. K.; AC
27.0403.AStephenson and Malanowski, 1987Based on data from 388. - 497. K.; AC
28.7505.AStephenson and Malanowski, 1987Based on data from 490. - 533. K.; AC
28.7270.EBBoublík and Aim, 1972Based on data from 255. - 318. K. See also Stephenson and Malanowski, 1987.; AC
28.1292.EBWaddington, Smith, et al., 1962Based on data from 277. - 353. K.; AC
28.1 ± 0.1282.CWaddington, Smith, et al., 1962AC
26.7 ± 0.1319.CWaddington, Smith, et al., 1962AC
27.6318.N/AThomson, 1946Based on data from 303. - 358. K.; AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) beta Tc (K) Reference Comment
282. - 319.37.070.2264552.Majer and Svoboda, 1985 

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
276.74 - 353.084.066831168.62-31.616Waddington, Smith, et al., 1962Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
4.389161.11Brown and Manov, 1937DH

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
27.24161.11Brown and Manov, 1937DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Carbon disulfide = (Chlorine anion bullet Carbon disulfide)

By formula: Cl- + CS2 = (Cl- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar36.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Deltar49.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar58.2J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Deltar84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar19. ± 9.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Deltar24. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

CS2- + Carbon disulfide = (CS2- bullet Carbon disulfide)

By formula: CS2- + CS2 = (CS2- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar91.6 ± 6.3kJ/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Deltar18. ± 4.6kJ/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B
Deltar17.2 ± 2.5kJ/molLPESBowen and Eaton, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar130.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar54. ± 10.kJ/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

(CS2- bullet Carbon disulfide) + Carbon disulfide = (CS2- bullet 2Carbon disulfide)

By formula: (CS2- bullet CS2) + CS2 = (CS2- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar19.2 ± 2.9kJ/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B
Deltar27. ± 5.9kJ/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar0. ± 14.kJ/molTDAsHiraoka, Fujimaki, et al., 1994gas phase; B

S2+ + Carbon disulfide = (S2+ bullet Carbon disulfide)

By formula: S2+ + CS2 = (S2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar129.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar120.kJ/molPIOno, Linn, et al., 1981gas phase; M
Deltar91.6kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; equilibrium uncertain; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar71.5J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; equilibrium uncertain; M

(Fluorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Fluorine anion bullet 3Carbon disulfide)

By formula: (F- bullet 2CS2) + CS2 = (F- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar23. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KN/AHiraoka, Fujimaki, et al., 1993gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar1. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

Fluorine anion + Carbon disulfide = (Fluorine anion bullet Carbon disulfide)

By formula: F- + CS2 = (F- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar146. ± 6.3kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Deltar131. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Deltar118.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar111. ± 6.3kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Deltar101. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B

CS2+ + Carbon disulfide = (CS2+ bullet Carbon disulfide)

By formula: CS2+ + CS2 = (CS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar104.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar91.6kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M
Deltar73.2kJ/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar91.6J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M

(CS2+ bullet 2Carbon disulfide) + Carbon disulfide = (CS2+ bullet 3Carbon disulfide)

By formula: (CS2+ bullet 2CS2) + CS2 = (CS2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar21.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Deltar16.kJ/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

(Chlorine anion bullet 3Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 4Carbon disulfide)

By formula: (Cl- bullet 3CS2) + CS2 = (Cl- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar28. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B
Quantity Value Units Method Reference Comment
Deltar-0.4 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

CHS2+ + Carbon disulfide = (CHS2+ bullet Carbon disulfide)

By formula: CHS2+ + CS2 = (CHS2+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Deltar46.4kJ/molPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar60.7J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1977gas phase; M

(Chlorine anion bullet 2Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 3Carbon disulfide)

By formula: (Cl- bullet 2CS2) + CS2 = (Cl- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar30.1 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar3. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion bullet Carbon disulfide) + Carbon disulfide = (Chlorine anion bullet 2Carbon disulfide)

By formula: (Cl- bullet CS2) + CS2 = (Cl- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar32.2 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar66.1J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar13. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Fluorine anion bullet Carbon disulfide) + Carbon disulfide = (Fluorine anion bullet 2Carbon disulfide)

By formula: (F- bullet CS2) + CS2 = (F- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar28.0 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar64.0J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar8.8 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Iodide bullet Carbon disulfide) + Carbon disulfide = (Iodide bullet 2Carbon disulfide)

By formula: (I- bullet CS2) + CS2 = (I- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar28.5 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar0.8 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Bromine anion bullet Carbon disulfide) + Carbon disulfide = (Bromine anion bullet 2Carbon disulfide)

By formula: (Br- bullet CS2) + CS2 = (Br- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar30.5 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar5.0 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

Iodide + Carbon disulfide = (Iodide bullet Carbon disulfide)

By formula: I- + CS2 = (I- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar31.0 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar69.9J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar10. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

Bromine anion + Carbon disulfide = (Bromine anion bullet Carbon disulfide)

By formula: Br- + CS2 = (Br- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar34.7 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar54.4J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Deltar18. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(S2+ bullet 2Carbon disulfide) + Carbon disulfide = (S2+ bullet 3Carbon disulfide)

By formula: (S2+ bullet 2CS2) + CS2 = (S2+ bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar23.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar71.J/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

(S2- bullet Carbon disulfide) + Carbon disulfide = (S2- bullet 2Carbon disulfide)

By formula: (S2- bullet CS2) + CS2 = (S2- bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar26.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AHiraoka, Fujimaki, et al., 1994, 2gas phase; Entropy change calculated or estimated; M

(CS2+ bullet Carbon disulfide) + Carbon disulfide = (CS2+ bullet 2Carbon disulfide)

By formula: (CS2+ bullet CS2) + CS2 = (CS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar27.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Deltar18.kJ/molPIOno, Linn, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Deltar88.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

Methyl cation + Carbon disulfide = (Methyl cation bullet Carbon disulfide)

By formula: CH3+ + CS2 = (CH3+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar252.kJ/molPHPMSMcMahon, Heinis, et al., 1988gas phase; switching reaction(CH3+)N2, Entropy change calculated or estimated, uses MCA(N2) = 202. kJ/mol; Foster, Williamson, et al., 1974; M

(CS2- bullet 3Carbon disulfide) + Carbon disulfide = (CS2- bullet 4Carbon disulfide)

By formula: (CS2- bullet 3CS2) + CS2 = (CS2- bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar10. ± 28.kJ/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(CS2- bullet 4Carbon disulfide) + Carbon disulfide = (CS2- bullet 5Carbon disulfide)

By formula: (CS2- bullet 4CS2) + CS2 = (CS2- bullet 5CS2)

Quantity Value Units Method Reference Comment
Deltar8. ± 28.kJ/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(CS2- bullet 2Carbon disulfide) + Carbon disulfide = (CS2- bullet 3Carbon disulfide)

By formula: (CS2- bullet 2CS2) + CS2 = (CS2- bullet 3CS2)

Quantity Value Units Method Reference Comment
Deltar-97.91kJ/molN/ATsukuda, Hirose, et al., 1997gas phase; EA given is Vertical Detachment Energy. Affinity is difference from next lower Vertical De; B

(S2+ bullet Carbon disulfide) + Carbon disulfide = (S2+ bullet 2Carbon disulfide)

By formula: (S2+ bullet CS2) + CS2 = (S2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar35.kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

(CHS2+ bullet Carbon disulfide) + Carbon disulfide = (CHS2+ bullet 2Carbon disulfide)

By formula: (CHS2+ bullet CS2) + CS2 = (CHS2+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar20.kJ/molPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar59.8J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993, 2gas phase; M

S2- + Carbon disulfide = (S2- bullet Carbon disulfide)

By formula: S2- + CS2 = (S2- bullet CS2)

Quantity Value Units Method Reference Comment
Deltar79.9kJ/molPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSHiraoka, Fujimaki, et al., 1994, 2gas phase; M

C6H6+ + Carbon disulfide = (C6H6+ bullet Carbon disulfide)

By formula: C6H6+ + CS2 = (C6H6+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar51.0kJ/molPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSMeot-Ner (Mautner), Hamlet, et al., 1978gas phase; M

(CS2+ bullet 3Carbon disulfide) + Carbon disulfide = (CS2+ bullet 4Carbon disulfide)

By formula: (CS2+ bullet 3CS2) + CS2 = (CS2+ bullet 4CS2)

Quantity Value Units Method Reference Comment
Deltar11.kJ/molPIOno, Linn, et al., 1980gas phase; M

(Iron ion (1+) bullet Carbon disulfide) + Carbon disulfide = (Iron ion (1+) bullet 2Carbon disulfide)

By formula: (Fe+ bullet CS2) + CS2 = (Fe+ bullet 2CS2)

Quantity Value Units Method Reference Comment
Deltar188. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

CS+ + Carbon disulfide = (CS+ bullet Carbon disulfide)

By formula: CS+ + CS2 = (CS+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar151.kJ/molPIOno, Linn, et al., 1981gas phase; M

Sulfur cation + Carbon disulfide = (Sulfur cation bullet Carbon disulfide)

By formula: S+ + CS2 = (S+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar166.kJ/molPIGress, Linn, et al., 1980gas phase; M

trithiocarbonic acid = Carbon disulfide + Hydrogen sulfide

By formula: CH2S3 = CS2 + H2S

Quantity Value Units Method Reference Comment
Deltar44. ± 1.kJ/molCmGattow and Krebes, 1963liquid phase; ALS

Iron ion (1+) + Carbon disulfide = (Iron ion (1+) bullet Carbon disulfide)

By formula: Fe+ + CS2 = (Fe+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar166. ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD

Vanadium ion (1+) + Carbon disulfide = (Vanadium ion (1+) bullet Carbon disulfide)

By formula: V+ + CS2 = (V+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar114. ± 13.kJ/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

Molybdenum ion (1+) + Carbon disulfide = (Molybdenum ion (1+) bullet Carbon disulfide)

By formula: Mo+ + CS2 = (Mo+ bullet CS2)

Quantity Value Units Method Reference Comment
Deltar67. ± 13.kJ/molCIDTSchroeder, Kretzschmar, et al., 2003RCD

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center, 1990.
NIST MS number 118705

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Good, Lacina, et al., 1961
Good, W.D.; Lacina, J.L.; McCullough, J.P., Methanethiol and carbon disulfide: Heats of combustion and formation by rotating-bomb calorimetry, J. Phys. Chem., 1961, 65, 2229-2231. [all data]

Guerin, Marthe, et al., 1949
Guerin, M.H.; Marthe, M.; Bastick, J.; Adam-Gironne, J., Sur la chaleur de combustion du sulfure de carbon, Compt. Rend., 1949, 228, 87-89. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Brown and Manov, 1937
Brown, O.L.I.; Manov, G.G., The heat capacity of carbon disulfide from 15 to 300°K. The entropy and heat of fusion of carbon disulfide, J. Am. Chem. Soc., 1937, 59, 500-502. [all data]

Staveley, Tupman, et al., 1955
Staveley, L.A.K.; Tupman, W.I.; Hart, K.R., Some thermodynamice properties of the systems benzene + ethylene dichloride, benzene + carbon tetrachloride, acetone + chloroform, and acetone + carbon disulphide, Trans. Faraday Soc., 1955, 51, 323-342. [all data]

Zhdanov, 1945
Zhdanov, A.K., On the thermal capacity of some pure liquids and azeotropic mixtures, Zhur. Obshch. Khim., 1945, 15, 895-902. [all data]

Mazur, 1939
Mazur, J., Über die spezifische Wärme des Äthyläthers, des Nitrobenzols und des Schwefelkohlenstoffs, Z. Physik., 1939, 113, 710-720. [all data]

Phillip, 1939
Phillip, N.M., Adiabatic and isothermal compressibilities of liquids, Proc. Indian Acad. Sci., 1939, A9, 109-120. [all data]

Brown and Manov, 1937, 2
Brown, O.L.I.; Manov, G.G., The heat capacity of carbon disulfide from 15 to 300 k: the entropy and heat of fusion of carbon disulfide, J. Am. Chem. Soc., 1937, 59, 500. [all data]

Stull, 1937
Stull, D.R., A Semi-micro Calorimeter for Measuring Heat Capacities at Low Temp., J. Am. Chem. Soc., 1937, 59, 2726. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R., Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Boublík and Aim, 1972
Boublík, T.; Aim, K., Heats of vaporization of simple non-spherical molecule compounds, Collect. Czech. Chem. Commun., 1972, 37, 11, 3513-3521, https://doi.org/10.1135/cccc19723513 . [all data]

Waddington, Smith, et al., 1962
Waddington, Guy; Smith, J.C.; Williamson, K.D.; Scott, D.W., CARBON DISULFIDE AS A REFERENCE SUBSTANCE FOR VAPOR-FLOW CALORIMETRY; THE CHEMICAL THERMODYNAMIC PROPERTIES, J. Phys. Chem., 1962, 66, 6, 1074-1077, https://doi.org/10.1021/j100812a025 . [all data]

Thomson, 1946
Thomson, George Wm., The Antoine Equation for Vapor-pressure Data., Chem. Rev., 1946, 38, 1, 1-39, https://doi.org/10.1021/cr60119a001 . [all data]

Hiraoka, Fujimaki, et al., 1993
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Bond Strengths of the Gas-Phase Cluster Ions X-(CS2)n (X = F, Cl, Br and I), Chem. Phys. Lett., 1993, 208, 5-6, 491, https://doi.org/10.1016/0009-2614(93)87178-6 . [all data]

Larson and McMahon, 1985
Larson, J.W.; McMahon, T.B., Fluoride and chloride affinities of the main group oxides, fluorides, oxofluorides, and alkyls. Quantitative scales of lewis acidities from ICR halide exchange equilibria, J. Am. Chem. Soc., 1985, 107, 766. [all data]

Hiraoka, Fujimaki, et al., 1994
Hiraoka, K.; Fujimaki, S.; Aruga, K., Frontier-controlled Structures of the Gas Phas Clusters A+/-(CS2)n, A+/- = S2+, CS2+, S2-, and CS2-, J. Phys. Chem. (1994), 1994, 98, 7, 1802-1809, https://doi.org/10.1021/j100058a014 . [all data]

Tsukuda, Hirose, et al., 1997
Tsukuda, T.; Hirose, T.; Nagata, T., Negative-ion photoelectron spectroscopy of (CS2)(n)(-): coexistence of electronic isomers, Chem. Phys. Lett., 1997, 279, 3-4, 179-184, https://doi.org/10.1016/S0009-2614(97)01021-X . [all data]

Bowen and Eaton, 1988
Bowen, K.H.; Eaton, J.G., Photodetachment Spectroscopy of Negative Cluster Ions, in The Structure of Small Molecules and Ions, Ed. R. Naaman, Z. Vager, Plenum NY, 1988, 1988, p.147-169. [all data]

Hiraoka, Fujimaki, et al., 1994, 2
Hiraoka, K.; Fujimaki, S.; Aruga, K.; Yamabe, S., Frontier-Controlled Structures of the Gas-Phase A+-(CS2)n Clusters ,A+- = S2+, CS2+, S2-, and CS2-, J. Phys. Chem., 1994, 98, 7, 1802, https://doi.org/10.1021/j100058a014 . [all data]

Ono, Linn, et al., 1981
Ono, Y.; Linn, S.H.; Prest, H.F.; Gress, M.E.; Ng, C.Y., A Study of the High Rydberg State and Ion - Molecule Reactions of Carbon Disulfide Using the Molecular Beam Photoionization Method, J. Chem. Phys., 1981, 74, 2, 1125, https://doi.org/10.1063/1.441219 . [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Proton Affinity and Ion - Molecule Clustering in CO2 and CS2. Applications in Martian Ionospheric Chemistry, J. Chem. Phys., 1977, 66, 10, 4527, https://doi.org/10.1063/1.433706 . [all data]

Ono, Linn, et al., 1980
Ono, Y.; Linn, S.H.; Prest, H.F.; Gress, M.E.; Ng, C.Y., Molecular beam photoionization study of carbon disulfide, carbon disulfide dimer and clusters, J. Chem. Phys., 1980, 73, 2523. [all data]

Hiraoka, Fujimaki, et al., 1993, 2
Hiraoka, K.; Fujimaki, S.; Aruga, K., Proton-Held Dimer and Trimer of Carbon Disulfide, Chem. Phys. Lett., 1993, 202, 1-2, 167, https://doi.org/10.1016/0009-2614(93)85367-W . [all data]

McMahon, Heinis, et al., 1988
McMahon, T.; Heinis, T.; Nicol, G.; Hovey, J.K.; Kebarle, P., Methyl Cation Affinities, J. Am. Chem. Soc., 1988, 110, 23, 7591, https://doi.org/10.1021/ja00231a002 . [all data]

Foster, Williamson, et al., 1974
Foster, M.S.; Williamson, A.D.; Beauchamp, J.L., Photoionization mass spectrometry of trans-azomethane, Int. J. Mass Spectrom. Ion Phys., 1974, 15, 429. [all data]

Meot-Ner (Mautner), Hamlet, et al., 1978
Meot-Ner (Mautner), M.; Hamlet, P.; Hunter, E.P.; Field, F.H., Bonding Energies in Association Ions of Aromatic Molecules. Correlations with Ionization Energies, J. Am. Chem. Soc., 1978, 100, 17, 5466, https://doi.org/10.1021/ja00485a034 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Gress, Linn, et al., 1980
Gress, M.E.; Linn, S.H.; Ono, Y.; Prest, H.F.; Ng, C.Y., A Study of the Chemiionization Process CS2*(n) + CS2 ---> CS3+ + CS + e- Using the Molecular Beam Photoionization Method, J. Chem. Phys., 1980, 72, 7, 4242, https://doi.org/10.1063/1.439656 . [all data]

Gattow and Krebes, 1963
Gattow, V.G.; Krebes, B., Das kohlenstoffsulfid-di-(hydrogensulfid) SC(SH)2 und das system H2S-CS2. 2. Thermochemie des SC(SH)2, Z. Anorg. Allg. Chem., 1963, 322, 113. [all data]

Schroeder, Kretzschmar, et al., 2003
Schroeder, D.; Kretzschmar, I.; Schwarz; Armentrout, P.B., Structure, Thermochemistry, and Reactivityof MSn+ Cations (M=V,Mo; n=1-3) in the Gas Phase, Int. J. Mass Spectrom., 2003, 228, 2-3, 439, https://doi.org/10.1016/S1387-3806(03)00137-4 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References