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Nitrogen atom

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)14.53414eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)342.2kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity318.7kJ/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
14.53414EVALLide, 1992LL
14.534SKelly, 1987LBLHLM
14.549PIDehmer, Berkowitz, et al., 1974LLK
14.55PEJonathan, Morris, et al., 1970RDSH
14.534SMcConkey and Kernahan, 1968RDSH
14.53409SMcConkey and Kernahan, 1968RDSH
14.56EIFoner and Hudson, 1962RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Lide, 1992
Lide, D.R. (Editor), Ionization potentials of atoms and atomic ions in Handbook of Chem. and Phys., 1992, 10-211. [all data]

Kelly, 1987
Kelly, R.L., Atomic and ionic spectrum lines of hydrogen through kryton, J. Phys. Chem. Ref. Data, 1987, 16. [all data]

Dehmer, Berkowitz, et al., 1974
Dehmer, P.M.; Berkowitz, J.; Chupka, W.A., Photoization of atomic nitrogen, J. Chem. Phys., 1974, 60, 2676. [all data]

Jonathan, Morris, et al., 1970
Jonathan, N.; Morris, A.; Smith, D.J.; Ross, K.J., Photoelectron spectra of ground state atomic hydrogen, nitrogen and oxygen, Chem. Phys. Lett., 1970, 7, 497. [all data]

McConkey and Kernahan, 1968
McConkey, J.W.; Kernahan, J.A., The ionization limits of N 1, Phys. Letters, 1968, 27A, 82. [all data]

Foner and Hudson, 1962
Foner, S.N.; Hudson, R.L., Mass spectrometric studies of metastable nitrogen atoms and molecules in active nitrogen, J. Chem. Phys., 1962, 37, 1662. [all data]


Notes

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