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nickel monoxide


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to NiO+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
1.4550 ± 0.0050LPESRamond, Davico, et al., 2002B
1.4700 ± 0.0030LPESMoravec and Jarrold, 1998B
1.460 ± 0.020LPESWu and Wang, 1997B

Ionization energy determinations

IE (eV) Method Reference Comment
9.5 ± 0.2ENDArmentrout, Halle, et al., 1982LBLHLM
9.5 ± 0.3EIGrimley, Burns, et al., 1961RDSH

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through April, 1975

Symbols used in the table of constants
SymbolMeaning
State electronic state and / or symmetry symbol
Te minimum electronic energy (cm-1)
ωe vibrational constant – first term (cm-1)
ωexe vibrational constant – second term (cm-1)
ωeye vibrational constant – third term (cm-1)
Be rotational constant in equilibrium position (cm-1)
αe rotational constant – first term (cm-1)
γe rotation-vibration interaction constant (cm-1)
De centrifugal distortion constant (cm-1)
βe rotational constant – first term, centrifugal force (cm-1)
re internuclear distance (Å)
Trans. observed transition(s) corresponding to electronic state
ν00 position of 0-0 band (units noted in table)
Diatomic constants for (58)Ni16O
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
Three additional systems in the same spectral region.
Rosen, 1945; Malet and Rosen, 1945
b (a + 21262) (570) H         b rarrow a R (21135) H
Rosen, 1945; Malet and Rosen, 1945
a a (825) H          
B (16447) (560) H         B rarrow X R (16420) H
Rosen, 1945; Malet and Rosen, 1945
StateTeomegaeomegaexeomegaeyeBealphaegammaeDebetaereTrans.nu00
A (12725) (475) H         A rarrow X R (12655) H
Rosen, 1945; Malet and Rosen, 1945
(X) 0 (615) H          

Notes

1Thermochemical value (mass spectrometry.) Grimley, Burns, et al., 1961, recalculated Smoes, Mandy, et al., 1972. See also Brewer and Mastick, 1951, Huldt and Lagerqvist, 1954.

References

Go To: Top, Gas phase ion energetics data, Constants of diatomic molecules, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ramond, Davico, et al., 2002
Ramond, T.M.; Davico, G.E.; Hellberg, F.; Svedberg, F.; Salen, P.; Soderqvist, P.; Lineberger, W.C., Photoelectron spectroscopy of nickel, palladium, and platinum oxide anions, J. Molec. Spectros., 2002, 216, 1, 1-14, https://doi.org/10.1006/jmsp.2002.8669 . [all data]

Moravec and Jarrold, 1998
Moravec, V.D.; Jarrold, C.C., Study of the low-lying states of NiO- and NIO using anion photoelectron spectroscopy, J. Chem. Phys., 1998, 108, 5, 1804-1810, https://doi.org/10.1063/1.475557 . [all data]

Wu and Wang, 1997
Wu, H.; Wang, L.-S., A Study of Nickel Monoxide (NiO), Nickel Dioxide (NiO2) and Ni(O2) Complex by Anion Photoelectron Spectroscopy, J. Chem. Phys., 1997, 107, 1, 16, https://doi.org/10.1063/1.474362 . [all data]

Armentrout, Halle, et al., 1982
Armentrout, P.B.; Halle, L.F.; Beauchamp, J.L., Reaction of Cr+, Mn+, Fe+, Co+, and Ni+ with O2 and N2O. Examination of the translational energy dependence of the cross sections of endothermic reactions, J. Chem. Phys., 1982, 76, 2449. [all data]

Grimley, Burns, et al., 1961
Grimley, R.T.; Burns, R.P.; Inghram, M.G., Thermodynamics of the vaporization of nickel oxide, J. Chem. Phys., 1961, 35, 551. [all data]

Rosen, 1945
Rosen, B., Spectra of diatomic oxides by the method of exploded wire, Nature (London), 1945, 156, 570. [all data]

Malet and Rosen, 1945
Malet, L.; Rosen, B., Etude spectroscopique des molecules NiO et CoO, Bull. Soc. R. Sci. Liege, 1945, 14, 382. [all data]

Smoes, Mandy, et al., 1972
Smoes, S.; Mandy, F.; Vander Auwera-Mahieu, A.; Drowart, J., Determination by the mass spectrometric Knudsen cell method of the dissociation energies of the group IB chalcogenides, Bull. Soc. Chim. Belg., 1972, 81, 45. [all data]

Brewer and Mastick, 1951
Brewer, L.; Mastick, D.F., The stability of gaseous diatomic oxides, J. Chem. Phys., 1951, 19, 834. [all data]

Huldt and Lagerqvist, 1954
Huldt, L.; Lagerqvist, A., Uber die Dissoziationsenergie des gasformigen Nickeloxydes NiO, Z. Naturforsch. A, 1954, 9, 358. [all data]


Notes

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