Methyl rhenium pentacarbonyl
- Formula: C6H3O5Re
- Molecular weight: 341.292
- CAS Registry Number: 14524-92-6
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔsubH° | 16.7 ± 0.5 | kcal/mol | HAL-HFC | Al-Takhin, Connor, et al., 1983 | Another value has been reported for the enthalpy of sublimation: 15.6 ± 0.24 kcal/mol Hieber, Braun, et al., 1960; MS |
| ΔsubH° | 16.7 ± 0.5 | kcal/mol | C | Al-Takhin, Connor, et al., 1983, 2 | AC |
| ΔsubH° | 15.6 ± 0.24 | kcal/mol | N/A | Pilcher and Skinner, 1983 | See also Lalage, Brown, et al., 1974.; AC |
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 15.6 | 347.5 | A | Stephenson and Malanowski, 1987 | Based on data from 315. - 380. K. See also Hieber, Braun, et al., 1960, 2.; AC |
| 15.5 | 313. - 383. | N/A | Hieber and Wagner, 1958 | AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Al-Takhin, Connor, et al., 1983
Al-Takhin, G.; Connor, J.A.; Skinner, H.A.,
J. Organomet. Chem., 1983, 259, 313. [all data]
Hieber, Braun, et al., 1960
Hieber, W.; Braun, G.; Beck, W.,
Chem. Ber., 1960, 93, 901. [all data]
Al-Takhin, Connor, et al., 1983, 2
Al-Takhin, Ghassan; Connor, Joseph A.; Skinner, Henry A.,
Enthalpies of formation of decacarbonyldirhenium and some pentacarbonylrhenium derivatives,
Journal of Organometallic Chemistry, 1983, 259, 3, 313-320, https://doi.org/10.1016/0022-328X(83)87182-4
. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Lalage, Brown, et al., 1974
Lalage, D.; Brown, S.; Connor, Joseph A.; Skinner, Henry A.,
The enthalpies of formation of CH3Mn(CO)5 and of CH3Re(CO)5, and the strengths of the CH3«58872»Mn and CH3«58872»Re bonds,
Journal of Organometallic Chemistry, 1974, 81, 3, 403-409, https://doi.org/10.1016/S0022-328X(00)88209-1
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Hieber, Braun, et al., 1960, 2
Hieber, Walter; Braun, Gerhard; Beck, Wolfgang,
Über Organometallcarbonyle, II. Organorheniumpentacarbonyle,
Chem. Ber., 1960, 93, 4, 901-908, https://doi.org/10.1002/cber.19600930422
. [all data]
Hieber and Wagner, 1958
Hieber, Walter; Wagner, Gerhard,
Über Organomanganpentacarbonyle, I,
Justus Liebigs Ann. Chem., 1958, 618, 1, 24-30, https://doi.org/10.1002/jlac.19586180104
. [all data]
Notes
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- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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