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Benzyl alcohol

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-154.9 ± 3.0kJ/molCcrPapina, Pimenova, et al., 1995ALS
Deltafliquid-161.0 ± 1.3kJ/molCcbParks, Manchester, et al., 1954ALS
Deltafliquid-174.kJ/molCcbLandrieu, Baylocq, et al., 1929ALS
Deltafliquid-167.kJ/molCcbSchmidlin, 1906ALS
Quantity Value Units Method Reference Comment
Deltacliquid-3743.0 ± 2.8kJ/molCcrPapina, Pimenova, et al., 1995Corresponding «DELTA»fliquid = -154.9 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3736.9kJ/molCcbParks, Manchester, et al., 1954Corresponding «DELTA»fliquid = -161.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3723.kJ/molCcbLandrieu, Baylocq, et al., 1929Corresponding «DELTA»fliquid = -174. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3724.kJ/molCcbBarker, 1925Author was aware that data differs from previously reported values; Corresponding «DELTA»fliquid = -174. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3731.kJ/molCcbSchmidlin, 1906Corresponding «DELTA»fliquid = -167. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid216.7J/mol*KN/AParks, Todd, et al., 1936Extrapolation below 90 K, 54.06 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
223.6307.5Griigo'ev, Yanin, et al., 1979T = 307 to 461 K. p = 0.98 bar.; DH
215.94298.15Nichols and Wads, 1975DH
217.86298.1Parks, Todd, et al., 1936T = 90 to 300 K.; DH
215.9298.5Smith and Andrews, 1931T = 102 to 299 K. Value is unsmoothed experimental datum.; DH
220.5298.von Reis, 1881T = 290 to 485 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Papina, Pimenova, et al., 1995
Papina, T.S.; Pimenova, S.M.; Luk'yanova, V.A.; Kolesov, V.P., Standard enthalpies of formation of benzyl alcohol and «alpha»,«alpha»,«alpha»-trichlorotoluene, Russ. J. Phys. Chem. (Engl. Transl.), 1995, 69, 1951-1953, In original 2148. [all data]

Parks, Manchester, et al., 1954
Parks, G.S.; Manchester, K.E.; Vaughan, L.M., Heats of combustion and formation of some alcohols, phenols, and ketones, J. Chem. Phys., 1954, 22, 2089-2090. [all data]

Landrieu, Baylocq, et al., 1929
Landrieu, P.; Baylocq, F.; Johnson, J.R., Etude thermochimique dans la serie furanique, Bull. Soc. Chim. France, 1929, 45, 36-49. [all data]

Schmidlin, 1906
Schmidlin, M.J., Recherches chimiques et thermochimiques sur la constitution des rosanilines, Ann. Chim. Phys., 1906, 1, 195-256. [all data]

Barker, 1925
Barker, M.F., Calorific value and constitution, J. Phys. Chem., 1925, 29, 1345-1363. [all data]

Parks, Todd, et al., 1936
Parks, G.S.; Todd, S.S.; Moore, W.A., Thermal data on organic compounds. XVI. Some heat capacity, entropy and free energy data for typical benzene derivatives and heterocyclic compounds, J. Am. Chem. Soc., 1936, 58, 398-401. [all data]

Griigo'ev, Yanin, et al., 1979
Griigo'ev, B.A.; Yanin, G.S.; Rastorguev, Yu.L.; Thermophysical parameters of alcohols, Tr. GIAP, 54, 1979, 57-64. [all data]

Nichols and Wads, 1975
Nichols, N.; Wads, I., Thermochemistry of solutions of biochemical model compounds. 3. Some benzene derivatives in aqueous solution, J. Chem. Thermodynam., 1975, 7, 329-336. [all data]

Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H., Thermal energy studies. I. Phenyl derivatives of methane, ethane and some related compounds. J. Am. Chem. Soc., 1931, 53, 3644-3660. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]


Notes

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