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Pyrrolidine

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

(C4H10N+ bullet Pyrrolidine) + Pyrrolidine = (C4H10N+ bullet 2Pyrrolidine)

By formula: (C4H10N+ bullet C4H9N) + C4H9N = (C4H10N+ bullet 2C4H9N)

Quantity Value Units Method Reference Comment
Deltar15.3kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar24.3cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

C4H10N+ + Pyrrolidine = (C4H10N+ bullet Pyrrolidine)

By formula: C4H10N+ + C4H9N = (C4H10N+ bullet C4H9N)

Quantity Value Units Method Reference Comment
Deltar22.3kcal/molPHPMSHiraoka, Takimoto, et al., 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.8cal/mol*KPHPMSHiraoka, Takimoto, et al., 1987gas phase; M

3Hydrogen + Dodecahydrotripyrrolo[1,2-a:1',2'-c:1",2"-e][1,3,5]triazine = 3Pyrrolidine

By formula: 3H2 + C12H21N3 = 3C4H9N

Quantity Value Units Method Reference Comment
Deltar-25.0 ± 0.1kcal/molChydWiberg, Nakaji, et al., 1993liquid phase; solvent: Acetic acid; ALS

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka, Takimoto, et al., 1987
Hiraoka, K.; Takimoto, H.; Yamabe, S., Stabilities and Structures in Cluster Ions of Five-Membered Heterocyclic Compounds Containing O, N and S Atoms, J. Am. Chem. Soc., 1987, 109, 24, 7346, https://doi.org/10.1021/ja00258a018 . [all data]

Wiberg, Nakaji, et al., 1993
Wiberg, K.B.; Nakaji, D.Y.; Morgan, K.M., Heat of hydrogenation of a cis imine. An experimental and theoretical study, J. Am. Chem. Soc., 1993, 115, 3527-3532. [all data]


Notes

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