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Diphenyl carbonate

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil574.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil579.2KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Deltavap80.9 ± 0.6kJ/molGSVerevkin, Emel'yanenko, et al., 2008Based on data from 355. - 381. K.; AC
Quantity Value Units Method Reference Comment
Deltasub90. ± 8.4kJ/molECarson, Fine, et al., 1971See also Pedley and Rylance, 1977.; AC
Deltasub90.0 ± 8.4kJ/molVCarson, Fine, et al., 1971, 2Hfusion=5.6±0.3; ALS

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
23.43355.Carson, Fine, et al., 1971AC

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Verevkin, Emel'yanenko, et al., 2008
Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Kozlova, Svetlana A., Organic Carbonates: Experiment and ab Initio Calculations for Prediction of Thermochemical Properties, J. Phys. Chem. A, 2008, 112, 42, 10667-10673, https://doi.org/10.1021/jp8024705 . [all data]

Carson, Fine, et al., 1971
Carson, A.S.; Fine, D.H.; Gray, P.; Laye, P.G., Standard enthalpies of formation of diphenyl oxalate and benzoic anhydride and some related bond dissociation energies, J. Chem. Soc., B:, 1971, 1611, https://doi.org/10.1039/j29710001611 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., , Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brighton, 1977. [all data]

Carson, Fine, et al., 1971, 2
Carson, A.S.; Fine, D.H.; Gray, P.; Laye, P.G., Standard enthalpies of formation of diphenyl oxalate and benzoic anhydride and some related bond dissociation energies, J. Chem. Soc. B, 1971, 1611-1615. [all data]


Notes

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