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Dimanganese decacarbonyl


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafgas-1585.3 ± 4.3kJ/molReviewMartinho SimõesSelected data.
Deltafgas-1582.2 ± 9.4kJ/molReviewMartinho Simões 
Deltafgas-1582.8 ± 9.2kJ/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltafsolid-1677.6 ± 3.7kJ/molReviewMartinho SimõesSelected data.
Deltafsolid-1674.5 ± 9.2kJ/molReviewMartinho Simões 
Deltafsolid-1675.1 ± 9.0kJ/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Deltacsolid-3251.0 ± 3.3kJ/molCC-RBGood, Fairbrother, et al., 1958Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões

Quantity Value Units Method Reference Comment
Deltasub80.3 ± 4.2kJ/molN/APilcher and Skinner, 1983See also Good, Fairbrother, et al., 1958, 2.; AC
Deltasub92.3 ± 2.1kJ/molCC-RBConnor, Zafarani-Moattar, et al., 1982Other values for the enthalpy of sublimation have been reported: 80.3 ± 4.2 kJ/mol Brown, Connor, et al., 1974 Baev, Dem'yanchuk, et al., 1971 Lemoine, Gross, et al., 1975 (see also Behrens, 1976) and 62.8 ± 4.2 kJ/mol Cotton and Monchamp, 1960; MS
Deltasub92.3 ± 2.1kJ/molCConnor, Zafarani-Moattar, et al., 1982, 2AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Reference Comment
60.7 ± 1.3446.Baev, Dem'yanchuk, et al., 1971Based on data from 428. - 463. K.; AC

Enthalpy of sublimation

DeltasubH (kJ/mol) Temperature (K) Method Reference Comment
80.3 ± 2.1390.MMBaev, Dem'yanchuk, et al., 1971Based on data from 351. - 428. K.; AC

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Dimanganese decacarbonyl (solution) = 2C5MnO5 (solution)

By formula: C10Mn2O10 (solution) = 2C5MnO5 (solution)

Quantity Value Units Method Reference Comment
Deltar158. ± 17.kJ/molES/EChemPugh and Meyer T.J., 1992solvent: Acetonitrile; The value relies on the reaction Gibbs energy, 118. ± 17. kJ/mol Pugh and Meyer T.J., 1992, and an estimated value, 133.9 J/(mol K), for the reaction entropy Pugh and Meyer T.J., 1992
Deltar>104.2kJ/molES/EChemPugh and Meyer, 1988solvent: Acetonitrile; The lower limit is the reaction Gibbs energy
Deltar159. ± 21.kJ/molPACGoodman, Peters, et al., 1986solvent: Hexane, cyclohexane, thf or acetonitrile; The average value of the enthalpy of the reaction Mn2(CO)10(solution) = 2xMn(CO)5(solution) + (1-x)Mn2(CO)9(solution) + (1-x)CO(solution) in the solvents indicated is 53.4 ± 5.2 kJ/mol. This value, together with several estimates and auxiliary data led to the reaction enthalpy for the cleavage of Mn-Mn bond
Deltar>154.kJ/molKinSHopgood and Poë, 1966solvent: Decalin; Please also see Poë, 1981. The reaction enthalpy was derived from the enthalpy of activation, 153.8 ± 1.6 kJ/mol Hopgood and Poë, 1966 Poë, 1981, by assuming a negligible barrier for the radical recombination. This procedure was later considered to yield a low limit of the reaction enthalpy Poë, 1983 Marcomini and Poë, 1984 Marcomini and Poë, 1983 Coville, Stolzenberg, et al., 1983. See also Schmidt, Trogler, et al., 1984

Dimanganese decacarbonyl (solution) + Dirhenium decacarbonyl (solution) = 2C10MnO10Re (solution)

By formula: C10Mn2O10 (solution) + C10O10Re2 (solution) = 2C10MnO10Re (solution)

Quantity Value Units Method Reference Comment
Deltar121. ± 31.kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane; The reaction enthalpy was calculated from the enthalpies of the following reactions: Mn2(CO)10(solution) + I2(solution) = 2Mn(CO)5(I)(solution), -187.9 ± 8.4 kJ/mol, Re2(CO)10(solution) + I2(solution) = 2Re(CO)5(I)(solution), -157. ± 16. kJ/mol, and MnRe(CO)10(solution) + I2(solution) = Mn(CO)5(I)(solution) + Re(CO)5(I)(solution), -233. ± 13. kJ/mol
Deltar34.4 ± 1.3kJ/molEqSMarcomini and Poë, 1984solvent: Decalin; Temperature range: 443-463 K

Dimanganese decacarbonyl (cr) + Iodine (cr) = 2Manganese, pentacarbonyliodo- (cr)

By formula: C10Mn2O10 (cr) + I2 (cr) = 2C5IMnO5 (cr)

Quantity Value Units Method Reference Comment
Deltar-185.0 ± 8.7kJ/molPCHarel and Adamson, 1986The reaction enthalpy was calculated from the enthalpy of the same reaction in cyclohexane, -187.9 ± 8.4 kJ/mol Harel and Adamson, 1986, and from the solution enthalpies of Mn2(CO)10(cr), 36.0 ± 2.1 kJ/mol, I2(cr), 20.5 ± 0.4 kJ/mol, and Mn(CO)5(I)(cr), 26.8 ± 0.5 kJ/mol Harel and Adamson, 1986. The latter value refers to the solution in benzene and is therefore taken as an approximation

Dimanganese decacarbonyl (g) = 2C5MnO5 (g)

By formula: C10Mn2O10 (g) = 2C5MnO5 (g)

Quantity Value Units Method Reference Comment
Deltar>176.kJ/molESTSmith, 1988 
Deltar94.kJ/molESTConnor, Zafarani-Moattar, et al., 1982 
Deltar96. ± 13.kJ/molEG/EIMSBidinosti and McIntyre, 1970The reaction enthalpy includes an estimated correction to 298 K. A value of 104.2 ± 8.4 kJ/mol was reported at an average temperature of 540 K Bidinosti and McIntyre, 1970. The enthalpy of formation relies on -1585.3 ± 4.3 kJ/mol for the enthalpy of formation of Mn2(CO)10(g)

Dimanganese decacarbonyl (solution) + Hydrogen (solution) = 2Hydromanganese pentacarbonyl (solution)

By formula: C10Mn2O10 (solution) + H2 (solution) = 2C5HMnO5 (solution)

Quantity Value Units Method Reference Comment
Deltar36.4 ± 1.3kJ/molEqSKlingler R.J. and Rathke, 1992solvent: Supercritical carbon dioxide; Temperature range: 373-463 K

Dimanganese decacarbonyl (solution) + Dicobalt octacarbonyl (solution) = 2C9CoMnO9 (solution)

By formula: C10Mn2O10 (solution) + C8Co2O8 (solution) = 2C9CoMnO9 (solution)

Quantity Value Units Method Reference Comment
Deltar3.3 ± 1.3kJ/molEqSKlingler R.J. and Rathke, 1992solvent: Supercritical carbon dioxide; Temperature range: 353-453 K

Dimanganese decacarbonyl (g) = C9Mn2O9 (g) + Carbon monoxide (g)

By formula: C10Mn2O10 (g) = C9Mn2O9 (g) + CO (g)

Quantity Value Units Method Reference Comment
Deltar159.0 ± 8.4kJ/molLPHPSmith, 1988The reaction enthalpy relies on an activation energy of 159.0 ± 8.4 kJ/mol and assumes a negligible activation barrier for product recombination.

Dimanganese decacarbonyl (solution) + Iodine (solution) = 2Manganese, pentacarbonyliodo- (solution)

By formula: C10Mn2O10 (solution) + I2 (solution) = 2C5IMnO5 (solution)

Quantity Value Units Method Reference Comment
Deltar-187.9 ± 8.4kJ/molPCHarel and Adamson, 1986solvent: Cyclohexane

Dimanganese decacarbonyl (cr) + 2Bromine (g) = 2manganese dibromide (cr) + 10Carbon monoxide (g)

By formula: C10Mn2O10 (cr) + 2Br2 (g) = 2Br2Mn (cr) + 10CO (g)

Quantity Value Units Method Reference Comment
Deltar-263.6 ± 8.2kJ/molHAL-HFCConnor, Zafarani-Moattar, et al., 1982 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.32 ± 0.01EIMichels and Svec, 1981LLK
7.7PEHigginson, Lloyd, et al., 1975LLK
7.69 ± 0.01PEConnor, Zafarani-Moattar, et al., 1972LLK
8.46 ± 0.03EIJunk and Svec, 1970RDSH
8.4 ± 0.1EIBidinosti and McIntyre, 1970RDSH
8.55 ± 0.10EIWinters and Kiser, 1965RDSH
8.02PEHigginson, Lloyd, et al., 1975Vertical value; LLK
8.02PEEvans, Green, et al., 1969Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
MnCO+18.21?EISvec and Junk, 1967RDSH
MnCO+17.5 ± 0.2?EIWinters and Kiser, 1965RDSH
MnC2O2+14.80?EISvec and Junk, 1967RDSH
Mn2C2O2+16.438COEISvec and Junk, 1967RDSH
Mn2C3O3+15.347COEISvec and Junk, 1967RDSH
Mn2C4O4+13.986COEISvec and Junk, 1967RDSH
Mn2C4O4+14.0 ± 0.26COEIWinters and Kiser, 1965RDSH
MnC5O5+9.40?EISvec and Junk, 1967RDSH
MnC5O5+9.3 ± 0.1?EIBidinosti and McIntyre, 1966RDSH
Mn2C5O5+11.915COEISvec and Junk, 1967RDSH
Mn2C5O5+12.6 ± 0.25COEIWinters and Kiser, 1965RDSH
Mn+22.13?EISvec and Junk, 1967RDSH
Mn+20.8 ± 0.4?EIWinters and Kiser, 1965RDSH
Mn2+18.7310COEISvec and Junk, 1967RDSH
Mn2+18.8 ± 0.310COEIWinters and Kiser, 1965RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chemical Concepts
NIST MS number 153792

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Good, Fairbrother, et al., 1958
Good, W.D.; Fairbrother, D.M.; Waddington, G., J. Phys. Chem., 1958, 62, 853. [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A., Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2 . [all data]

Good, Fairbrother, et al., 1958, 2
Good, W.D.; Fairbrother, D.M.; Waddington, Guy, Manganese Carbonyl: Heat of Formation by Rotating-Bomb Calorimetry, J. Phys. Chem., 1958, 62, 7, 853-856, https://doi.org/10.1021/j150565a021 . [all data]

Connor, Zafarani-Moattar, et al., 1982
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; El-Saied, N.I.; Suradi, S.; Carson, R.; Al Takkhin, G.; Skinner, H.A., Organomet., 1982, 1, 1166. [all data]

Brown, Connor, et al., 1974
Brown, D.L.S.; Connor, J.A.; Skinner, H.A., J. Organometal. Chem., 1974, 81, 403. [all data]

Baev, Dem'yanchuk, et al., 1971
Baev, A.K.; Dem'yanchuk, V.V.; Mirzoev, G.; Noikov, G.I.; Kolobova, N.E., Russ. J. Phys. Chem., 1971, 45, 6, 777. [all data]

Lemoine, Gross, et al., 1975
Lemoine, P.; Gross, M.; Bousquet, J.; Letoffe, J.M.; Diot, M., J. Chem. Thermodyn., 1975, 7, 913. [all data]

Behrens, 1976
Behrens, R.G., J. Organometal. Chem., 1976, 121, C63. [all data]

Cotton and Monchamp, 1960
Cotton, F.A.; Monchamp, R.R., J. Chem. Soc., 1960, 533.. [all data]

Connor, Zafarani-Moattar, et al., 1982, 2
Connor, Joseph A.; Zafarani-Moattar, Mohamed T.; Bickerton, James; El Saied, Nabila I.; Suradi, Sukiman; Carson, Ronald; Al Takhin, Ghassan; Skinner, Henry A., Enthalpy of formation of acyl-, alkyl- and hydridopentacarbonyl-manganese complexes. The enthalpy contributions of manganese-hydrogen and manganese-carbon bonds in these molecules. Thermochemical aspects of models in Fischer-Tropsch reactions, Organometallics, 1982, 1, 9, 1166-1174, https://doi.org/10.1021/om00069a011 . [all data]

Pugh and Meyer T.J., 1992
Pugh, J.R.; Meyer T.J., J. Am. Chem. Soc., 1992, 114, 3784. [all data]

Pugh and Meyer, 1988
Pugh, J.R.; Meyer, T.J., J. Am. Chem. Soc., 1988, 110, 8245. [all data]

Goodman, Peters, et al., 1986
Goodman, J.L.; Peters, K.S.; Vaida, V., Organometallics, 1986, 5, 815. [all data]

Hopgood and Poë, 1966
Hopgood, D.; Poë, A.J., J. Chem. Soc., Chem. Commun., 1966, 831.. [all data]

Poë, 1981
Poë, A., ACS Symp. Ser., 1981, No. 155, 135. [all data]

Poë, 1983
Poë, A., Chem. Brit., 1983, 19, 997. [all data]

Marcomini and Poë, 1984
Marcomini, A.; Poë, A., J. Chem. Soc., Dalton Trans., 1984, 95.. [all data]

Marcomini and Poë, 1983
Marcomini, A.; Poë, A., J. Am. Chem. Soc., 1983, 105, 6952. [all data]

Coville, Stolzenberg, et al., 1983
Coville, N.J.; Stolzenberg, A.M.; Muetterties, E.L., J. Am. Chem. Soc., 1983, 105, 2499. [all data]

Schmidt, Trogler, et al., 1984
Schmidt, S.P.; Trogler, W.C.; Basolo, F., J. Am. Chem. Soc., 1984, 106, 1308. [all data]

Harel and Adamson, 1986
Harel, Y.; Adamson, A.W., J. Phys. Chem., 1986, 90, 6693. [all data]

Smith, 1988
Smith, G.P., Polyhedron, 1988, 7, 1605. [all data]

Bidinosti and McIntyre, 1970
Bidinosti, D.R.; McIntyre, N.S., Mass spectrometric study of the thermal decomposition of dimanganese decacarbonyl and dicobalt octacarbonyl, Can. J. Chem., 1970, 48, 593. [all data]

Klingler R.J. and Rathke, 1992
Klingler R.J.; Rathke, J.W., Inorg. Chem., 1992, 31, 804. [all data]

Michels and Svec, 1981
Michels, G.D.; Svec, H.J., Characterization of MnTc(CO)10 and TcRe(CO)10, Inorg. Chem., 1981, 20, 3445. [all data]

Higginson, Lloyd, et al., 1975
Higginson, B.R.; Lloyd, D.R.; Evans, S.; Orchard, A.F., Photoelectron studies of metal carbonyls. Part 5. - Substituted group VIIA carbonyls, J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1913. [all data]

Connor, Zafarani-Moattar, et al., 1972
Connor, J.A.; Zafarani-Moattar, M.T.; Bickerton, J.; ElSaied, N.I.; Suradi, S.; Carson, R.; AlTakhin, G.; Skinner, H.A., [Title unavailable], Organometallics, 1972, 1, 1166. [all data]

Junk and Svec, 1970
Junk, G.A.; Svec, H.J., The mass spectra, ionization potentials, and bond energies of the group VIIA decacarbonyls, J. Chem. Soc. A, 1970, 2102. [all data]

Winters and Kiser, 1965
Winters, R.E.; Kiser, R.W., Ions produced by electron impact with the dimetallic carbonyls of cobalt and manganese, J. Phys. Chem., 1965, 69, 1618. [all data]

Evans, Green, et al., 1969
Evans, S.; Green, J.C.; Green, M.L.H.; Orchard, A.F.; Turner, D.W., Study of the bonding in pentacarbonylmanganese derivatives by photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1969, 47, 112. [all data]

Svec and Junk, 1967
Svec, H.J.; Junk, G.A., Energetics of the ionization and dissociation of Mn2(CO)10, Re2(CO)10, and ReMn(CO)10, J. Am. Chem. Soc., 1967, 89, 2836. [all data]

Bidinosti and McIntyre, 1966
Bidinosti, D.R.; McIntyre, N.S., The metal-metal bond dissociation energy in manganese carbonyl, Chem. Commun., 1966, 555. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), References