Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Lithium fluoride

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to FLi+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
>1.34997EIAEEbinghaus, 1964From (LiF)2; G3MP2B3 calculations indicate an EA of ca.0.5 eV; B

Ionization energy determinations

IE (eV) Method Reference Comment
11.3EIBerkowitz, Tasman, et al., 1962RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
Li+11.40FEIVeljkovic, Neskovic, et al., 1993LL
Li+11.5FEIBerkowitz, Tasman, et al., 1962RDSH
Li+~12.FEIPorter and Schoonmaker, 1958RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ebinghaus, 1964
Ebinghaus, H.Z., Negative Ionen aus Alkalihalogeniden und Electronenaffinitaten der Alkalimetalle und Alkalihalogenide, Z. Naturfor., 1964, 19A, 727. [all data]

Berkowitz, Tasman, et al., 1962
Berkowitz, J.; Tasman, H.A.; Chupka, W.A., Double-oven experiments with lithium halide vapors, J. Chem. Phys., 1962, 36, 2170. [all data]

Veljkovic, Neskovic, et al., 1993
Veljkovic, M.V.; Neskovic, O.M.; Miletic, M.B.; Zmbov, K.F., Mass spectrometric study of ionization and fragmentation of lithium fluoride vapor by electron impact, J. Serb. Chem. Soc., 1993, 58, 101. [all data]

Porter and Schoonmaker, 1958
Porter, R.F.; Schoonmaker, R.C., Mass spectrometric study of the vaporization of LiF, NaF, and LiF-NaF mixtures, J. Chem. Phys., 1958, 29, 1070. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References