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Phenol, 3-methyl-

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Deltafgas-133.6 ± 1.1kJ/molCcbCox, 1961ALS
Deltafgas-132.3 ± 1.1kJ/molCcbAndon, Biddiscombe, et al., 1960ALS
Deltafgas-117.3kJ/molN/APushin, 1954Value computed using «DELTA»fHliquid° value of -177.0 kj/mol from Pushin, 1954 and «DELTA»vapH° value of 59.7 kj/mol from Cox, 1961.; DRB
Deltafgas-133.8kJ/molN/ABadoche, 1941Value computed using «DELTA»fHliquid° value of -193.5 kj/mol from Badoche, 1941 and «DELTA»vapH° value of 59.7 kj/mol from Cox, 1961.; DRB

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
38.6950.Kudchadker S.A., 1978Selected entropies and heat capacities are in close agreement with statistical values calculated by [ Green J.H.S., 1962].; GT
50.75100.
67.59150.
86.00200.
114.73273.15
124.68298.15
125.41300.
162.97400.
194.54500.
219.94600.
240.45700.
257.31800.
271.41900.
283.341000.
293.511100.
302.241200.
309.771300.
316.281400.
321.941500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-193.3kJ/molCcbCox, 1961ALS
Deltafliquid-194.1 ± 1.1kJ/molCcbAndon, Biddiscombe, et al., 1960ALS
Deltafliquid-177.kJ/molCcbPushin, 1954Author's hf298_condensed=-44.4 kcal/mol; ALS
Deltafliquid-193.5kJ/molCcbBadoche, 1941Author's hf298_condensed=-48.97 kcal/mol; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-3704.7 ± 0.3kJ/molCcbCox, 1961Corresponding «DELTA»fliquid = -193.2 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3703.9 ± 0.59kJ/molCcbAndon, Biddiscombe, et al., 1960Corresponding «DELTA»fliquid = -194.0 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3721.kJ/molCcbPushin, 1954Author's hf298_condensed=-44.4 kcal/mol; Corresponding «DELTA»fliquid = -177. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3704.4kJ/molCcbBadoche, 1941Author's hf298_condensed=-48.97 kcal/mol; Corresponding «DELTA»fliquid = -193.5 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-3694.kJ/molCcbBarker, 1925Author was aware that data differs from previously reported values; Corresponding «DELTA»fliquid = -203. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid212.59J/mol*KN/AAndon, Counsell, et al., 1967DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
224.93298.15Andon, Counsell, et al., 1967T = 10 to 400 K.; DH
220.993.Rastorguev and Ganiev, 1967T = 293 to 373 K.; DH
218.8298.Tschamler and Krischai, 1951DH
216.7283.Bramley, 1916Mean value, 0 to 20 C.; DH

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Cox, 1961
Cox, J.D., The heats of combustion of phenol and the three cresols, Pure Appl. Chem., 1961, 2, 125-128. [all data]

Andon, Biddiscombe, et al., 1960
Andon, R.J.L.; Biddiscombe, D.P.; Cox, J.D.; Handley, R.; Harrop, D.; Herington, E.F.G.; Martin, J.F., Thermodynamic properties of organic oxygen compounds. Part I. Preparation and physical properties of pure phenol, cresols, and xylenols, J. Chem. Soc., 1960, 5246-5254. [all data]

Pushin, 1954
Pushin, N.A., Heats of combustion and heats of formation of isomeric organic compounds, Bull. Soc. Chim. Belgrade, 1954, 19, 531-547. [all data]

Badoche, 1941
Badoche, M., No 19. - Chaleurs de combustion du phenol, du-m-cresol et del leurs ethers; par M. Marius BADOCHE., Bull. Soc. Chim. Fr., 1941, 8, 212-220. [all data]

Kudchadker S.A., 1978
Kudchadker S.A., Ideal gas thermodynamic properties of phenol and cresols, J. Phys. Chem. Ref. Data, 1978, 7, 417-423. [all data]

Green J.H.S., 1962
Green J.H.S., Normal frequencies, thermodynamic properties and equilibrium of the cresols, Chem. Ind. (London), 1962, 1575-1576. [all data]

Barker, 1925
Barker, M.F., Calorific value and constitution, J. Phys. Chem., 1925, 29, 1345-1363. [all data]

Andon, Counsell, et al., 1967
Andon, R.J.L.; Counsell, J.F.; Lees, E.B.; Martin, J.F.; Mash, C.J., Thermodynamic properties of organic oxygen compounds. Part 17. Low-temperature heat capacity and entropy of the cresols, Trans. Faraday Soc., 1967, 63, 1115-1121. [all data]

Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A., Study of the heat capacity of selected solvents, Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]

Tschamler and Krischai, 1951
Tschamler, H.; Krischai, H., Chinolin-m-Kresol, ein stark negatives System, Monatsh. Chem., 1951, 82, 259-270. [all data]

Bramley, 1916
Bramley, A., The study of binary mixtures. Part IV. Heats of reaction and specific heats, J. Chem. Soc. (London), 1916, 109, 496-515. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References