Ethane, 1,1,2,2-tetrafluoro-1,2-dinitro-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfgas-812. ± 3.kJ/molCcbPepekin, Lebedev, et al., 1973hf_HF.30H2O=-77.01 kcal/mol and hf_CF4=-223.0 kcal/mol

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfliquid-880. ± 3.kJ/molCcbPepekin, Lebedev, et al., 1973hf_HF.30H2O=-77.01 kcal/mol and hf_CF4=-223.0 kcal/mol
Quantity Value Units Method Reference Comment
Δcliquid-602. ± 2.kJ/molCcbPepekin, Lebedev, et al., 1973hf_HF.30H2O=-77.01 kcal/mol and hf_CF4=-223.0 kcal/mol

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil331.7KN/AWeast and Grasselli, 1989BS
Quantity Value Units Method Reference Comment
Δvap67.8 ± 0.8kJ/molVPepekin, Lebedev, et al., 1973hf_HF.30H2O=-77.01 kcal/mol and hf_CF4=-223.0 kcal/mol; ALS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
34.7274.A,IStephenson and Malanowski, 1987Based on data from 259. - 333. K. See also Frazer and Sanborn, 1957.; AC
67.8323.N/APepekin, Lebedev, et al., 1973, 2Based on data from 303. - 343. K.; AC

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 8400

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pepekin, Lebedev, et al., 1973
Pepekin, V.I.; Lebedev, Yu.A.; Apin, A.Ya., Dissociation energies of C-F and C-C bonds in α-fluoronitro derivatives of methane and ethane, Dokl. Akad. Nauk SSSR, 1973, 208, 153-155. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Frazer and Sanborn, 1957
Frazer, J.W.; Sanborn, R.H., , U.S. Atomic Energy Commission Report No. UCRL-4978, 1957, 1. [all data]

Pepekin, Lebedev, et al., 1973, 2
Pepekin, V.I.; Lebedev, Y.A.; Apin, A.Y., Dokl. Phys. Chem., 1973, 208, 35. [all data]


Notes

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