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(2H)formaldehyde


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to CD2O+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
10.9076 ± 0.0030PENiu, Shirley, et al., 1993LL
10.901 ± 0.006SDrury-Lessard and Moule, 1977LLK
10.904PEBaker, Baker, et al., 1968RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CDO+13.10 ± 0.12DEIReed, 1956RDSH
CO+18.8 ± 0.3?EIBrand and Reed, 1957RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Niu, Shirley, et al., 1993
Niu, B.; Shirley, D.A.; Bai, Y., High resolution photoelectron spectroscopy and femtosecond intramolecular dynamics of H2CO+ and D2CO+, J. Chem. Phys., 1993, 98, 4377. [all data]

Drury-Lessard and Moule, 1977
Drury-Lessard, C.R.; Moule, D.C., The higher Rydberg states of formaldehyde, Chem. Phys. Lett., 1977, 47, 300. [all data]

Baker, Baker, et al., 1968
Baker, A.D.; Baker, C.; Brundle, C.R.; Turner, D.W., The electronic structures of methane, ethane, ethylene and formaldehyde studied by high-resolution molecular photoelectron spectroscopy, Intern. J. Mass Spectrom. Ion Phys., 1968, 1, 285. [all data]

Reed, 1956
Reed, R.I., Studies in electron impact methods. Part 1.- Formaldehyde, deuteroformaldehyde, and some related compounds, J. Chem. Soc. Faraday Trans., 1956, 52, 1195. [all data]

Brand and Reed, 1957
Brand, J.C.D.; Reed, R.I., The electronic spectrum of formaldehyde. Part II. Mechanisms of dissociation of formaldehyde and the formaldehyde molecular ion, J. Chem. Soc., 1957, 2386. [all data]


Notes

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