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Nitric acid, ethyl ester

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-155. ± 3.kJ/molEqkGray, Pratt, et al., 1956See Gray and Smith, 1954

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-190.4 ± 1.0kJ/molCcbFairbrother, Skinner, et al., 1957ALS
Deltafliquid-191. ± 3.kJ/molEqkGray, Pratt, et al., 1956See Gray and Smith, 1954; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1311.2 ± 0.96kJ/molCcbFairbrother, Skinner, et al., 1957ALS
Quantity Value Units Method Reference Comment
liquid247.2J/mol*KN/AGray and Smith, 1954DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
170.3298.Gray and Smith, 1954T = 21 to 293 K.; DH

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Nitrogen oxide anion + Nitric acid, ethyl ester = (Nitrogen oxide anion bullet Nitric acid, ethyl ester)

By formula: NO2- + C2H5NO3 = (NO2- bullet C2H5NO3)

Quantity Value Units Method Reference Comment
Deltar87.4kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; switching reaction(NO2-)SO2; Keesee, Lee, et al., 1980; M
Quantity Value Units Method Reference Comment
Deltar148.J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; switching reaction(NO2-)SO2; Keesee, Lee, et al., 1980; M

(Nitrogen oxide anion bullet Sulfur dioxide) + Nitric acid, ethyl ester = (Nitrogen oxide anion bullet Nitric acid, ethyl ester bullet Sulfur dioxide)

By formula: (NO2- bullet O2S) + C2H5NO3 = (NO2- bullet C2H5NO3 bullet O2S)

Quantity Value Units Method Reference Comment
Deltar31.kJ/molHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar43.5J/mol*KHPMSWlodek, Luczynski, et al., 1983, 2gas phase; Entropy change is questionable; M

(Nitrogen oxide anion bullet 2Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (Nitrogen oxide anion bullet 3Nitric acid, ethyl ester)

By formula: (NO2- bullet 2C2H5NO3) + C2H5NO3 = (NO2- bullet 3C2H5NO3)

Quantity Value Units Method Reference Comment
Deltar31.kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar59.0J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

(Nitrogen oxide anion bullet Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (Nitrogen oxide anion bullet 2Nitric acid, ethyl ester)

By formula: (NO2- bullet C2H5NO3) + C2H5NO3 = (NO2- bullet 2C2H5NO3)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar53.6J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

(NO3 anion bullet Nitric acid, ethyl ester) + Nitric acid, ethyl ester = (NO3 anion bullet 2Nitric acid, ethyl ester)

By formula: (NO3- bullet C2H5NO3) + C2H5NO3 = (NO3- bullet 2C2H5NO3)

Quantity Value Units Method Reference Comment
Deltar30.kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar36.J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; Entropy change is questionable; M

NO3 anion + Nitric acid, ethyl ester = (NO3 anion bullet Nitric acid, ethyl ester)

By formula: NO3- + C2H5NO3 = (NO3- bullet C2H5NO3)

Quantity Value Units Method Reference Comment
Deltar72.0kJ/molHPMSWlodek, Luczynski, et al., 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar135.J/mol*KHPMSWlodek, Luczynski, et al., 1983gas phase; M

Ethanol + Nitric acid = Nitric acid, ethyl ester + Water

By formula: C2H6O + HNO3 = C2H5NO3 + H2O

Quantity Value Units Method Reference Comment
Deltar-25.1kJ/molEqkRubtsov, 1986liquid phase; ALS

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gray, Pratt, et al., 1956
Gray, P.; Pratt, M.W.T.; Larkin, M.J., 39. The latent heat of vaporization and the thermochemistry of ethyl nitrate, J. Chem. Soc., 1956, 210-212. [all data]

Gray and Smith, 1954
Gray, P.; Smith, P.L., Low-temperature calorimetry and the thermodynamic properties of ethyl nitrate, J. Chem. Soc., 1954, 769-773. [all data]

Fairbrother, Skinner, et al., 1957
Fairbrother, D.M.; Skinner, H.A.; Evans, F.W., The heats of combustion of organic compounds of nitrogen, Trans. Faraday Soc., 1957, 53, 779-783. [all data]

Wlodek, Luczynski, et al., 1983
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas - Phase Solvation of NO2- and NO3- by Ethyl Nitrate, Int. J. Mass Spectrom. Ion Phys., 1983, 52, 2-3, 149, https://doi.org/10.1016/0020-7381(83)85036-0 . [all data]

Keesee, Lee, et al., 1980
Keesee, R.G.; Lee, N.; Castleman, A.W., Jr., Properties of clusters in the gas phase: V. Complexes of neutral molecules onto negative ions, J. Chem. Phys., 1980, 73, 2195. [all data]

Wlodek, Luczynski, et al., 1983, 2
Wlodek, S.; Luczynski, Z.; Wincel, H., Gas phase complexes of NO2- and NO3- with SO2, Int. J. Mass Spectrom. Ion Processes, 1983, 49, 301. [all data]

Rubtsov, 1986
Rubtsov, Yu.I., Thermodynamic calculation of equilibrium in nitration of alcohols, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1986, 19-22. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, References