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2-Pentanone, 4,4-dimethyl-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

2,2-Dimethoxy-4,4-dimethylpentane + Water = 2-Pentanone, 4,4-dimethyl- + 2Methyl Alcohol

By formula: C9H20O2 + H2O = C7H14O + 2CH4O

Quantity Value Units Method Reference Comment
Deltar6.870 ± 0.088kJ/molCmWiberg, 1980liquid phase; solvent: Water; Hydrolysis
Deltar6.86 ± 0.08kJ/molCmWiberg and Squires, 1979liquid phase; Heat of hydrolysis

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg, 1980
Wiberg, K.B., Energies of organic compounds, Rept. DOE-E(11-1)4060 Prepared for US Dept. of Energy by Yale Univ., New Haven, CT. Avail. NTIS, 1980, 1-24. [all data]

Wiberg and Squires, 1979
Wiberg, K.B.; Squires, R.R., Thermodynamics of hydrolysis aliphatic ketals. An entropy component of steric effects, J. Am. Chem. Soc., 1979, 101, 5512-5515. [all data]


Notes

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