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Sulfur tetrafluoride

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to F4S+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)12.0 ± 0.3eVN/AN/AL

Electron affinity determinations

EA (eV) Method Reference Comment
1.50 ± 0.20IMRBMiller, Miller, et al., 1995B
1.50 ± 0.20IMRBViggiano, MIller, et al., 1991Between mCF3-nitrobenzene, C6F5NO2; B
2.35 ± 0.10IMRBBabcock and Streit, 1981EA: between NO2-, HS-; B
0.78 ± 0.20NBIECompton, Reinhardt, et al., 1978B
1.26 ± 0.10ESDonovan, Harland, et al., 1974B

Ionization energy determinations

IE (eV) Method Reference Comment
11.69 ± 0.06ENDFischer, Kickel, et al., 1992LL
12.3PECosta, Lloyd, et al., 1981LLK
12.8 ± 0.1PECosta, Lloyd, et al., 1981LLK
12.08 ± 0.10EIHildenbrand, 1973LLK
12.03 ± 0.05EIMuller and Fenderl, 1971LLK
12.28 ± 0.03EIGlemser, Muller, et al., 1968RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
F2S+17.4 ± 0.5?EIHildenbrand, 1973LLK
F3S+12.63 ± 0.10FEIHildenbrand, 1973LLK
SF3+12.70 ± 0.03FEIGlemser, Muller, et al., 1968RDSH

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Miller, Miller, et al., 1995
Miller, A.E.S.; Miller, T.M.; Viggiano, A.A.; Morris, R.A.; Vandoren, J.M.; Arnold, S.T.; Paulson, J., Negative ion chemistry of SF4, J. Chem. Phys., 1995, 102, 22, 8865, https://doi.org/10.1063/1.468940 . [all data]

Viggiano, MIller, et al., 1991
Viggiano, A.A.; MIller, T.M.; Miller, A.E.S.; Morris, R.A.; Van Doren, J.M.; Paulson, J.F., SF4: Electron Affinity Determination by Charge Transfer Reactions, Int. J. Mass Spectrom. Ion Proc., 1991, 109, 327, https://doi.org/10.1016/0168-1176(91)85112-Y . [all data]

Babcock and Streit, 1981
Babcock, L.M.; Streit, G.E., Negative ion-molecule reactions of SF4, J. Chem. Phys., 1981, 75, 3864. [all data]

Compton, Reinhardt, et al., 1978
Compton, R.N.; Reinhardt, P.W.; Cooper, C.D., Collisional ionization between fast alkali atoms and selected hexafluoride molecules, J. Chem. Phys., 1978, 68, 2023. [all data]

Donovan, Harland, et al., 1974
Donovan, R.J.; Harland, P.W.; Knox, J.H.; Makowski, J.A.; Thynne, J.C.J., Electron affinity of SF4, Int. J. Mass Spectrom. Ion Phys., 1974, 13, 464. [all data]

Fischer, Kickel, et al., 1992
Fischer, E.R.; Kickel, B.L.; Armentrout, P.B., Collision-induced dissociation and charge transfer reactions of SFx+ (x = 1-5_): Thermochemistry of sulfur fluoride ions and neutrals, J. Chem. Phys., 1992, 97, 4859. [all data]

Costa, Lloyd, et al., 1981
Costa, N.C.V.; Lloyd, D.R.; Roberts, P.J.; Cruickshank, D.W.J.; Avramides, E.; Chablo, A.; Collins, G.A.D.; Dobson, B.; Hillier, I.H., Experimental and theoretical study of the electronic structures of thionyl fluoride, sulphur tetrafluoride and sulphur tetrafluoride Oxode, J. Chem. Soc. Faraday Trans. 2, 1981, 77, 899. [all data]

Hildenbrand, 1973
Hildenbrand, D.L., Mass spectrometric studies of some gaseous sulfur fluorides, J. Phys. Chem., 1973, 77, 897. [all data]

Muller and Fenderl, 1971
Muller, J.; Fenderl, K., Reaktionen des «pi»-Cyclopentadienyl-Mangantricarbonyl-Kations mit einfachen Fluorverbindungen in der gasphase, Chem. Ber., 1971, 104, 2207. [all data]

Glemser, Muller, et al., 1968
Glemser, O.; Muller, A.; Bohler, D.; Krebs, B., Die N-S-Bindung: Bindungslangen Kraftkonstanten, Bindungsgrade und Bindungsenergien, Z. Anorg. Allgem. Chem., 1968, 357, 184. [all data]


Notes

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