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Methane, nitro-

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-81. ± 1.kJ/molCcbKnobel, Miroshnichenko, et al., 1971 

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-113. ± 0.4kJ/molCcbLebedeva and Ryadenko, 1973ALS
Deltafliquid-113.1 ± 0.63kJ/molCcbCass, Fletcher, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -93. ± 1. kJ/mol; ALS
Deltafliquid-89.04 ± 0.75kJ/molCcbHolcomb and Dorsey, 1949ALS
Quantity Value Units Method Reference Comment
Deltacliquid-709.6 ± 0.4kJ/molCcbLebedeva and Ryadenko, 1973ALS
Deltacliquid-703. ± 1.kJ/molCcbKnobel, Miroshnichenko, et al., 1971ALS
Deltacliquid-709.15 ± 0.59kJ/molCcbCass, Fletcher, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -730. ± 1. kJ/mol; ALS
Deltacliquid-733.25 ± 0.75kJ/molCcbHolcomb and Dorsey, 1949ALS
Deltacliquid-709.2kJ/molCcbSwientoslawski, 1910ALS
Quantity Value Units Method Reference Comment
liquid171.75J/mol*KN/AJones and Giauque, 1947DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
106.22308.Berman and West, 1969T = 308 to 473 K.; DH
108.8313.Hough, Mason, et al., 1950T = 313 to 363 K.; DH
105.98298.15Jones and Giauque, 1947T = 15 to 300 K.; DH
100.298.Williams, 1925T = 288 to 343 K. Equation only.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil374.1 ± 0.8KAVGN/AAverage of 17 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus244.6KN/AToops, 1956Uncertainty assigned by TRC = 0.05 K; TRC
Tfus244.55KN/ATimmermans, 1952Uncertainty assigned by TRC = 0.4 K; TRC
Tfus243.11KN/ADreisbach and Martin, 1949Uncertainty assigned by TRC = 0.05 K; TRC
Tfus244.KN/AJoukovsky, 1934Uncertainty assigned by TRC = 2. K; TRC
Tfus243.95KN/ATimmermans, 1921Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Ttriple244.77KN/AJones and Giauque, 1947, 2Uncertainty assigned by TRC = 0.02 K; TRC
Quantity Value Units Method Reference Comment
Tc588.KN/AMajer and Svoboda, 1985 
Tc588.KN/AGriffin, 1949Uncertainty assigned by TRC = 3. K; taken from a plot of total P vs 1/T; TRC
Quantity Value Units Method Reference Comment
Pc58.70barN/AAmbrose, Counsell, et al., 1978Uncertainty assigned by TRC = 0.5865 bar; TRC
Pc63.10barN/AGriffin, 1949Uncertainty assigned by TRC = 1.0342 bar; from value pf vapor pressure at Tc, based on unpublished measurements; TRC
Quantity Value Units Method Reference Comment
rhoc5.77mol/lN/AGriffin, 1949Uncertainty assigned by TRC = 0.05 mol/l; deduced from a series of P vs 1/T plots for various sample sizes in a fixed volume bomb; TRC
Quantity Value Units Method Reference Comment
Deltavap38. ± 3.kJ/molAVGN/AAverage of 7 values; Individual data points

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
33.99374.4N/AMajer and Svoboda, 1985 
38.271298.15N/AJones and Giauque, 1947P = 4.89 kPA; DH
35.2420.AStephenson and Malanowski, 1987Based on data from 405. - 476. K. See also Berman and West, 1967.; AC
36.8343.AStephenson and Malanowski, 1987Based on data from 328. - 410. K. See also McCullough, Scott, et al., 1954.; AC
37.2 ± 0.1318.CMcCullough, Scott, et al., 1954AC
36.3 ± 0.1335.CMcCullough, Scott, et al., 1954AC
35.2 ± 0.1353.CMcCullough, Scott, et al., 1954AC
34.0 ± 0.1374.CMcCullough, Scott, et al., 1954AC

Enthalpy of vaporization

ΔvapH = A exp(-βTr) (1 − Tr)β
    ΔvapH = Enthalpy of vaporization (at saturation pressure) (kJ/mol)
    Tr = reduced temperature (T / Tc)

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Temperature (K) A (kJ/mol) beta Tc (K) Reference Comment
318. - 374.53.330.2732588.Majer and Svoboda, 1985 

Entropy of vaporization

DeltavapS (J/mol*K) Temperature (K) Reference Comment
128.36298.15Jones and Giauque, 1947P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
405.0 - 476.4.11351229.574-76.221Berman and West, 1967Coefficents calculated by NIST from author's data.
328.86 - 409.64.405421446.196-45.633McCullough, Scott, et al., 1954Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
9.703244.77Jones and Giauque, 1947DH
9.7244.8Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
39.64244.77Jones and Giauque, 1947DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CH2NO2- + Hydrogen cation = Methane, nitro-

By formula: CH2NO2- + H+ = CH3NO2

Quantity Value Units Method Reference Comment
Deltar1498. ± 21.kJ/molD-EAMetz, Cyr, et al., 1991gas phase; B
Deltar1491. ± 9.2kJ/molG+TSBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Deltar1495. ± 12.kJ/molG+TSCumming and Kebarle, 1978gas phase; B
Quantity Value Units Method Reference Comment
Deltar1463. ± 8.4kJ/molIMREBartmess, Scott, et al., 1979gas phase; value altered from reference due to change in acidity scale; B
Deltar1467. ± 8.4kJ/molIMRECumming and Kebarle, 1978gas phase; B
Deltar1467. ± 8.4kJ/molIMREMacKay and Bohme, 1978gas phase; EA: < NO2; B

Chlorine anion + Methane, nitro- = (Chlorine anion bullet Methane, nitro-)

By formula: Cl- + CH3NO2 = (Cl- bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar65.3 ± 2.5kJ/molTDAsWincel, 2003gas phase; B
Deltar69.87 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Deltar68. ± 13.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984; B
Quantity Value Units Method Reference Comment
Deltar71.5J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar38.5kJ/molTDAsWincel, 2003gas phase; B
Deltar48.53 ± 0.42kJ/molTDAsSieck, 1985gas phase; B

(Chlorine anion bullet Methane, nitro-) + Methane, nitro- = (Chlorine anion bullet 2Methane, nitro-)

By formula: (Cl- bullet CH3NO2) + CH3NO2 = (Cl- bullet 2CH3NO2)

Quantity Value Units Method Reference Comment
Deltar54.4 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Deltar54.81 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar76.6J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar23.8kJ/molTDAsWincel, 2003gas phase; B
Deltar31.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B

Nitrogen oxide anion + Methane, nitro- = (Nitrogen oxide anion bullet Methane, nitro-)

By formula: NO2- + CH3NO2 = (NO2- bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar60.7 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Deltar59.83 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar64.9J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.6kJ/molTDAsWincel, 2003gas phase; B
Deltar40.6 ± 0.84kJ/molTDAsSieck, 1985gas phase; B

C6H7N+ + Methane, nitro- = (C6H7N+ bullet Methane, nitro-)

By formula: C6H7N+ + CH3NO2 = (C6H7N+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar60.2kJ/molPHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar75.J/mol*KN/AMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
34.343.PHPMSMeot-Ner (Mautner) and El-Shall, 1986gas phase; Entropy change calculated or estimated; M

(CH3NO2- bullet Methane, nitro-) + Methane, nitro- = (CH3NO2- bullet 2Methane, nitro-)

By formula: (CH3NO2- bullet CH3NO2) + CH3NO2 = (CH3NO2- bullet 2CH3NO2)

Quantity Value Units Method Reference Comment
Deltar50. ± 150.kJ/molN/ACompton, Carman Jr., et al., 1996gas phase; shift in electron detachment from less solvated ion; B
Deltar53.6 ± 1.3kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar24.7kJ/molTDAsWincel, 2003gas phase; B

CH6N+ + Methane, nitro- = (CH6N+ bullet Methane, nitro-)

By formula: CH6N+ + CH3NO2 = (CH6N+ bullet CH3NO2)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
Deltar85.8kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSMeot-Ner, 1984gas phase; M

CH2NO2- + Methane, nitro- = C2H5N2O4-

By formula: CH2NO2- + CH3NO2 = C2H5N2O4-

Quantity Value Units Method Reference Comment
Deltar66.5 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar35.1kJ/molTDAsWincel, 2003gas phase; B

C3H9N3O6- + 3Methane, nitro- = C4H12N4O8-

By formula: C3H9N3O6- + 3CH3NO2 = C4H12N4O8-

Quantity Value Units Method Reference Comment
Deltar43.5 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar15.9kJ/molTDAsWincel, 2003gas phase; B

C2H5N2O4- + 2Methane, nitro- = C3H8N3O6-

By formula: C2H5N2O4- + 2CH3NO2 = C3H8N3O6-

Quantity Value Units Method Reference Comment
Deltar55.6 ± 2.9kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar24.3kJ/molTDAsWincel, 2003gas phase; B

C3H8N3O6- + 3Methane, nitro- = C4H11N4O8-

By formula: C3H8N3O6- + 3CH3NO2 = C4H11N4O8-

Quantity Value Units Method Reference Comment
Deltar52.7 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.0kJ/molTDAsWincel, 2003gas phase; B

C4H11N4O8- + 4Methane, nitro- = C5H14N5O10-

By formula: C4H11N4O8- + 4CH3NO2 = C5H14N5O10-

Quantity Value Units Method Reference Comment
Deltar47.70 ± 0.84kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.69kJ/molTDAsWincel, 2003gas phase; B

C2H6N2O6- + 2Methane, nitro- = C3H9N3O8-

By formula: C2H6N2O6- + 2CH3NO2 = C3H9N3O8-

Quantity Value Units Method Reference Comment
Deltar45.6 ± 2.5kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar15.5kJ/molTDAsWincel, 2003gas phase; B

C4H12N4O8- + 4Methane, nitro- = C5H15N5O10-

By formula: C4H12N4O8- + 4CH3NO2 = C5H15N5O10-

Quantity Value Units Method Reference Comment
Deltar35.1 ± 0.84kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar10.0kJ/molTDAsWincel, 2003gas phase; B

C3H9N3O8- + 3Methane, nitro- = C4H12N4O10-

By formula: C3H9N3O8- + 3CH3NO2 = C4H12N4O10-

Quantity Value Units Method Reference Comment
Deltar39.7 ± 3.8kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar9.62kJ/molTDAsWincel, 2003gas phase; B

CH3N2O4- + 2Methane, nitro- = C2H6N3O6-

By formula: CH3N2O4- + 2CH3NO2 = C2H6N3O6-

Quantity Value Units Method Reference Comment
Deltar51.9 ± 2.1kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar22.6kJ/molTDAsWincel, 2003gas phase; B

C2H6ClN2O4- + 3Methane, nitro- = C3H9ClN3O6-

By formula: C2H6ClN2O4- + 3CH3NO2 = C3H9ClN3O6-

Quantity Value Units Method Reference Comment
Deltar46.4 ± 2.1kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar15.5kJ/molTDAsWincel, 2003gas phase; B

C11H10+ + Methane, nitro- = (C11H10+ bullet Methane, nitro-)

By formula: C11H10+ + CH3NO2 = (C11H10+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar46.9kJ/molPHPMSEl-Shall and Meot-Ner (Mautner), 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KPHPMSEl-Shall and Meot-Ner (Mautner), 1987gas phase; M

C2H6N3O6- + 3Methane, nitro- = C3H9N4O8-

By formula: C2H6N3O6- + 3CH3NO2 = C3H9N4O8-

Quantity Value Units Method Reference Comment
Deltar47.3 ± 3.3kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar13.8kJ/molTDAsWincel, 2003gas phase; B

C3H9N4O8- + 4Methane, nitro- = C4H12N5O10-

By formula: C3H9N4O8- + 4CH3NO2 = C4H12N5O10-

Quantity Value Units Method Reference Comment
Deltar40.6 ± 1.3kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar6.69kJ/molTDAsWincel, 2003gas phase; B

C5H10NO2+ + Methane, nitro- = (C5H10NO2+ bullet Methane, nitro-)

By formula: C5H10NO2+ + CH3NO2 = (C5H10NO2+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar73.2kJ/molHPMSMeot-Ner and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.4J/mol*KHPMSMeot-Ner and Field, 1974gas phase; M

C5H12NO2+ + Methane, nitro- = (C5H12NO2+ bullet Methane, nitro-)

By formula: C5H12NO2+ + CH3NO2 = (C5H12NO2+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar82.8kJ/molHPMSMeot-Ner and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KHPMSMeot-Ner and Field, 1974gas phase; M

C3H9ClN3O6- + 4Methane, nitro- = C4H12ClN4O8-

By formula: C3H9ClN3O6- + 4CH3NO2 = C4H12ClN4O8-

Quantity Value Units Method Reference Comment
Deltar40. ± 4.2kJ/molN/AWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar11.3kJ/molTDAsWincel, 2003gas phase; B

C4H12N4O10- + 4Methane, nitro- = C5H15N5O12-

By formula: C4H12N4O10- + 4CH3NO2 = C5H15N5O12-

Quantity Value Units Method Reference Comment
Deltar25.1kJ/molTDAsWincel, 2003gas phase; B
Quantity Value Units Method Reference Comment
Deltar2.5kJ/molTDAsWincel, 2003gas phase; B

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) bullet Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar165.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

CH3NO2- + Methane, nitro- = (CH3NO2- bullet Methane, nitro-)

By formula: CH3NO2- + CH3NO2 = (CH3NO2- bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar63.60 ± 0.84kJ/molN/ACompton, Carman Jr., et al., 1996gas phase; Shift in electron detachment from non-solvated ion; B

Bromine anion + Methane, nitro- = CH3BrNO2-

By formula: Br- + CH3NO2 = CH3BrNO2-

Quantity Value Units Method Reference Comment
Deltar40. ± 8.4kJ/molIMRETanabe, Morgon, et al., 1996gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

Iodide + Methane, nitro- = (Iodide bullet Methane, nitro-)

By formula: I- + CH3NO2 = (I- bullet CH3NO2)

Quantity Value Units Method Reference Comment
Deltar51.0 ± 4.2kJ/molTDAsCaldwell, Masucci, et al., 1989gas phase; B,M

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin CARL DJERASSI DEPT OF CHEM STANFORD UNIV STANFORD CALIF 94305
NIST MS number 49304

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Knobel, Miroshnichenko, et al., 1971
Knobel, Y.K.; Miroshnichenko, E.A.; Lebedev, Y.A., Heats of combustion of nitromethane and dinitromethane: enthalpies of formation of nitromethyl radicals and energies of dissociation of bonds in nitro derivatives of methane, Bull. Acad. Sci. USSR, Div. Chem. Sci., 1971, 425-428. [all data]

Lebedeva and Ryadenko, 1973
Lebedeva, N.D.; Ryadenko, V.L.R., Enthalpies of formation of nitroalkanes, Russ. J. Phys. Chem. (Engl. Transl.), 1973, 47, 1382. [all data]

Cass, Fletcher, et al., 1958
Cass, R.C.; Fletcher, S.E.; Mortimer, C.T.; Quincey, P.G.; Springall, H.D., Heats of combustion and molecular structure. Part IV. Aliphatic nitroalkanes and nitric esters, J. Chem. Soc., 1958, 958-962. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Holcomb and Dorsey, 1949
Holcomb, D.E.; Dorsey, C.L., Jr., Thermodynamic properties of nitroparaffins, Ind. Eng. Chem., 1949, 41, 2788-2792. [all data]

Swientoslawski, 1910
Swientoslawski, W., Thermochemische Untersuchungen der organischen Verbindungen. Dritte Mitteilung. Stickstoffhaltige Verbindungen., Z. Phys. Chem., 1910, 72, 49-83. [all data]

Jones and Giauque, 1947
Jones, W.M.; Giauque, W.F., The entropy of nitromethane. Heat capacity of solid and liquid. Vapor pressure, heats of fusion and vaporization, J. Am. Chem. Soc., 1947, 69, 983-987. [all data]

Berman and West, 1969
Berman, H.A.; West, E.D., Heat capacity of liquid nitromethane from 35 to 200°C, J. Chem. Eng. Data, 1969, 14, 107-109. [all data]

Hough, Mason, et al., 1950
Hough, E.W.; Mason, D.M.; Sage, B.H., Heat capacities of several organic liquids, J. Am. Chem. Soc., 1950, 72, 5775-5777. [all data]

Williams, 1925
Williams, J.W., A study of the physical properties of nitromethane, J. Am. Chem. Soc., 1925, 47, 2644-2652. [all data]

Toops, 1956
Toops, E.E., Physical Properties of High Purity Nitroparaffins, J. Phys. Chem., 1956, 60, 304-6. [all data]

Timmermans, 1952
Timmermans, J., Freezing points of organic compounds. VVI New determinations., Bull. Soc. Chim. Belg., 1952, 61, 393. [all data]

Dreisbach and Martin, 1949
Dreisbach, R.R.; Martin, R.A., Physical Data on Some Organic Compounds, Ind. Eng. Chem., 1949, 41, 2875-8. [all data]

Joukovsky, 1934
Joukovsky, N.I., Experimental Study of the Theory of Concentrated Solutions. XI. Thermodynamic Properties of Concentrated Solutions of Aliphatic Organic Compounds Containing Nitrogen., Bull. Soc. Chim. Belg., 1934, 43, 397. [all data]

Timmermans, 1921
Timmermans, J., The Freezing Points of Organic Substances IV. New Exp. Determinations, Bull. Soc. Chim. Belg., 1921, 30, 62. [all data]

Jones and Giauque, 1947, 2
Jones, W.M.; Giauque, W.F., The Entropy of Nitromethane. Heat Capacity of Solid and Liquid. Vapor Pressure, Heats of Fusion and Vaporizaion, J. Am. Chem. Soc., 1947, 69, 983-7. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Griffin, 1949
Griffin, D.N., The Critical Point of Nitromethane., J. Am. Chem. Soc., 1949, 71, 1423. [all data]

Ambrose, Counsell, et al., 1978
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Notes

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