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Bicyclo[4.1.0]heptane

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C7H12+ (ion structure unspecified)

Ionization energy determinations

IE (eV) Method Reference Comment
9.03 ± 0.02EIWinters and Collins, 1968RDSH
9.46PEHeilbronner, Gleiter, et al., 1973Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C3H3+12.53 ± 0.12?EIWinters and Collins, 1968RDSH
C3H5+11.90 ± 0.10?EIWinters and Collins, 1968RDSH
C4H5+12.42 ± 0.10?EIWinters and Collins, 1968RDSH
C4H6+10.10 ± 0.09?EIWinters and Collins, 1968RDSH
C4H7+10.27 ± 0.08?EIWinters and Collins, 1968RDSH
C5H7+9.53 ± 0.07C2H5EIWinters and Collins, 1968RDSH
C5H8+9.37 ± 0.07C2H4EIWinters and Collins, 1968RDSH
C6H9+9.30 ± 0.09CH3EIWinters and Collins, 1968RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Winters and Collins, 1968
Winters, R.E.; Collins, J.H., Mass spectrometric studies of structural isomers. I. Mono- and bicyclic C7H12 molecules, J. Am. Chem. Soc., 1968, 90, 1235. [all data]

Heilbronner, Gleiter, et al., 1973
Heilbronner, E.; Gleiter, R.; Hoshi, T.; Meijere, A., The interaction of Walsh-orbitals in diademane and related hydrocarbons, Helv. Chim. Acta, 1973, 56, 1594. [all data]


Notes

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