Aluminum monofluoride
- Formula: AlF
- Molecular weight: 45.9799418
- IUPAC Standard InChI: InChI=1S/Al.FH/h;1H/q+1;/p-1
- IUPAC Standard InChIKey: APURLPHDHPNUFL-UHFFFAOYSA-M
- CAS Registry Number: 13595-82-9
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.73 ± 0.01 | PE | Dyke, Kirby, et al., 1984 | LBLHLM |
| 9.8 | EVAL | Huber and Herzberg, 1979 | LLK |
| 9.86 ± 0.05 | S | Barrow, Kopp, et al., 1974 | LLK |
| 9. | EI | Uy, Srivastava, et al., 1972 | LLK |
| 9.2 | EI | Hildenbrand and Murad, 1966 | RDSH |
| 8.9 ± 0.6 | EI | Hildenbrand and Theard, 1965 | RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Al+ | 9.2 ± 0.3 | F-? | EI | Ehlert and Margrave, 1964 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dyke, Kirby, et al., 1984
Dyke, J.M.; Kirby, C.; Morris, A.; Gravenor, B.W.J.; Klein, R.; Rosmus, P.,
A study of aluminium monofluoride and aluminium trifluoride by high-temperature photoelectron spectroscopy,
Chem. Phys., 1984, 88, 289. [all data]
Huber and Herzberg, 1979
Huber, K.P.; Herzberg, G.,
Molecular Spectra and Molecular Structure. IV. Constants of Diatomic Molecules,, Van Nostrand Reinhold Co., 1979, ,1. [all data]
Barrow, Kopp, et al., 1974
Barrow, R.F.; Kopp, I.; Malmberg, C.,
The electronic spectrum of gaseous AlF,
Phys. Scr., 1974, 10, 86. [all data]
Uy, Srivastava, et al., 1972
Uy, O.M.; Srivastava, R.D.; Farber, M.,
Mass spectrometric determination of the heats of formation of the gaseous molecules AlOF2 and AlF2,
High Temp. Sci., 1972, 4, 227. [all data]
Hildenbrand and Murad, 1966
Hildenbrand, D.L.; Murad, E.,
Mass-spectrometric determination of the dissociation energy of beryllium monofluoride,
J. Chem. Phys., 1966, 44, 1524. [all data]
Hildenbrand and Theard, 1965
Hildenbrand, D.L.; Theard, L.P.,
Effusion studies, mass spectra, and thermodynamics of beryllium fluoride vapor,
J. Chem. Phys., 1965, 42, 3230. [all data]
Ehlert and Margrave, 1964
Ehlert, T.C.; Margrave, J.L.,
The heat of atomization of aluminum difluoride,
J. Am. Chem. Soc., 1964, 86, 3901. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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