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Diethyl sulfide

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-20.0 ± 0.55kcal/molCcbVoronkov, Klyuchnikov, et al., 1989 
Deltafgas-19.77 ± 0.19kcal/molCcrHubbard, Good, et al., 1958see Hubbard, Katz, et al., 1954

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-28.51 ± 0.48kcal/molCcbVoronkov, Klyuchnikov, et al., 1989ALS
Deltafliquid-28.54 ± 0.20kcal/molCcrHubbard, Good, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -28.34 ± 0.19 kcal/mol; see Hubbard, Katz, et al., 1954; ALS
Quantity Value Units Method Reference Comment
Deltacliquid-833.20 ± 0.16kcal/molCcrHubbard, Good, et al., 1958Reanalyzed by Cox and Pilcher, 1970, Original value = -833.04 ± 0.16 kcal/mol; see Hubbard, Katz, et al., 1954; ALS
Deltacliquid-829.6kcal/molCcbBerthelot, 1901ALS
Quantity Value Units Method Reference Comment
liquid64.359cal/mol*KN/AScott, Finke, et al., 1952DH

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
40.970298.15Scott, Finke, et al., 1952T = 16 to 316 K.; DH

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C4H10S+ + Diethyl sulfide = (C4H10S+ bullet Diethyl sulfide)

By formula: C4H10S+ + C4H10S = (C4H10S+ bullet C4H10S)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Deltar24.9kcal/molDTJames, McKee, et al., 1996gas phase; «DELTA»rH(0K) = 25.6 kcal/mol
Deltar26.8kcal/molDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 28.8 kcal/mol
Quantity Value Units Method Reference Comment
Deltar28.2cal/mol*KDTJames, McKee, et al., 1996gas phase; «DELTA»rH(0K) = 25.6 kcal/mol
Deltar34.2cal/mol*KDTDeng, Illies, et al., 1995gas phase; «DELTA»rH(0K) = 28.8 kcal/mol

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Voronkov, Klyuchnikov, et al., 1989
Voronkov, M.G.; Klyuchnikov, V.A.; Kolabin, S.N.; Shvets, G.N.; Varusin, P.I.; Deryagina, E.N.; Korchevin, N.A.; Tsvetnitskaya, S.I., Thermochemical properties of diorganyl chalcogenides and dichalcogenides RMnR(M = S, Se, Te; n = 1, 2)., Dokl. Phys. Chem. (Engl. Transl.), 1989, 307, 650-653, In original 1139. [all data]

Hubbard, Good, et al., 1958
Hubbard, W.N.; Good, W.D.; Waddington, G., The heats of combustion, formation and isomerization of the seven isomeric C4H10S alkane thiols and sulfides, J. Phys. Chem., 1958, 62, 614-617. [all data]

Hubbard, Katz, et al., 1954
Hubbard, W.N.; Katz, C.; Waddington, G., A rotating combustion bomb for precision calorimetry. Heats of combustion of some sulfur-containing compounds, J. Phys. Chem., 1954, 58, 142. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Berthelot, 1901
Berthelot, M., Chimie Organique. - Nouvelles recherches sur l'isomerie des ethers sulfocyaniques, Compt. Rend., 1901, 132, 57-58. [all data]

Scott, Finke, et al., 1952
Scott, D.W.; Finke, H.L.; Hubbard, W.N.; McCullough, J.P.; Oliver, G.D.; Gross, M.E.; Katz, C.; Williamson, K.D.; Waddington, G.; Huffman, H.M., 3-Thiapentane: heat capacity, heats of fusion and vaporization, vapor pressure, entropy, heat of formation and thermodynamic functions, J. Am. Chem. Soc., 1952, 74, 4656-4662. [all data]

James, McKee, et al., 1996
James, M.A.; McKee, M.L.; Illies, A.J., Gas-phase bond strength and atomic connectivity studies of the unsymmetrical two-center three-electron ion, [Et2S...SMe2]+, J. Am. Chem. Soc., 1996, 118, 33, 7836, https://doi.org/10.1021/ja960455h . [all data]

Deng, Illies, et al., 1995
Deng, Y.; Illies, A.J.; James, M.A.; McKee, M.L.; Peschke, M., A Definitive Investigation of the Gas-Phase Two-Center Three-electron Bond in [H2S:SH2+], [Me2S:SMe2]+, and [Et2S:SEt2]+: Therory and Experiment, J. Am. Chem. Soc., 1995, 117, 1, 420, https://doi.org/10.1021/ja00106a048 . [all data]


Notes

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