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Pentafluoromethylamine


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas-169.0 ± 0.6kcal/molCcbWalker, 1972Decompostion reaction

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Reference Comment
4.45135.Stephenson and Malanowski, 1987Based on data from 128. - 141. K. See also Fahim, Fleifel, et al., 1951.

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

CF5N = Tetrafluoromethane + 0.5Nitrogen + 0.5fluorine

By formula: CF5N = CF4 + 0.5N2 + 0.5F2

Quantity Value Units Method Reference Comment
Deltar-54.0 ± 0.4kcal/molCcbWalker, 1972gas phase; Decompostion reaction

Tetrafluoromethane + 0.5Nitrogen + 0.5fluorine = CF5N

By formula: CF4 + 0.5N2 + 0.5F2 = CF5N

Quantity Value Units Method Reference Comment
Deltar54.0 ± 0.4kcal/molCcbWalker, 1972gas phase; Decompostion reaction

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard

Ionization energy determinations

IE (eV) Method Reference Comment
11.9PEBurger, Pawelke, et al., 1982LBLHLM
12.62PEBurger, Pawelke, et al., 1982Vertical value; LBLHLM

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Walker, 1972
Walker, L.C., The enthalpy of decomposition of CF3NF2(g) to CF4(g), N2(g), and F2(g), J. Chem. Thermodyn., 1972, 4, 219-223. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Fahim, Fleifel, et al., 1951
Fahim, Hussein A.; Fleifel, Abdallah M.; Coates, G.E.; Harris, J.; Sutcliffe, T.; Lane, E.S.; Lewis, K.G.; Hassall, C.H.; Martin, S.L.; Hilton, Marjorie L.; Webb, M.; McGookin, A.; Page, H., Notes, J. Chem. Soc., 1951, 2761, https://doi.org/10.1039/jr9510002761 . [all data]

Burger, Pawelke, et al., 1982
Burger, H.; Pawelke, G.; Dammel, R.; Bock, H., Effects of fluorine substitution on methyl amines, J. Fluorine Chem., 1982, 19, 565. [all data]


Notes

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