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silicon fluoride


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to FSi+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
0.810 ± 0.020LPESKawamata, Neigishi, et al., 1996Vertical Detachment Energy: 0.81±0.05 eV.; B
>1.14009IMRBReents, Mandich, et al., 1986Si- + WF6 -> SiF- + WF5; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.54 ± 0.16ENDWeber and Armentrout, 1988LL
7.28EVALHuber and Herzberg, 1979LLK
7.26SJohns and Barrow, 1958RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kawamata, Neigishi, et al., 1996
Kawamata, H.; Neigishi, Y.; Kishi, R.; Iwata, S.; Nakajima, A.; Kaya, K., Photoelectron Spectroscopy of Silicon-Fluorine Binary Cluster Anions (SinFm-), J. Chem. Phys., 1996, 105, 13, 5369, https://doi.org/10.1063/1.472377 . [all data]

Reents, Mandich, et al., 1986
Reents, W.D.; Mandich, M.L.; Bondebey, V.E., Reaction of Anionic and Cationic Silicon Clusters with Tungsten Hexafluoride Studied by Fourier Transform Mass Spectrometry, Chem. Phys. Lett., 1986, 131, 1-2, 1, https://doi.org/10.1016/0009-2614(86)80507-3 . [all data]

Weber and Armentrout, 1988
Weber, M.E.; Armentrout, P.B., Energetics and dynamics in the reaction of Si+ with SiF4. Thermochemistry of SiFx and SiFx+ (x=1,2,3), J. Chem. Phys., 1988, 11, 6898. [all data]

Huber and Herzberg, 1979
Huber, K.P.; Herzberg, G., Molecular Spectra and Molecular Structure. IV. Constants of Diatomic Molecules,, Van Nostrand Reinhold Co., 1979, ,1. [all data]

Johns and Barrow, 1958
Johns, J.W.C.; Barrow, R.F., The band spectrum of silicon monofluoride, SiF, Proc. Phys. Soc. (London), 1958, 71, 476. [all data]


Notes

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