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Methane, tetranitro-

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafgas19.7 ± 0.5kcal/molCcbLebedev, Miroshnichenko, et al., 1975 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid9.2 ± 0.4kcal/molCcbLebedev, Miroshnichenko, et al., 1975 
Deltafliquid8.8 ± 0.7kcal/molCcbGardner and Grigger, 1963 
Deltafliquid9.9 ± 1.0kcal/molCcbRoth and Isecke, 1944Reanalyzed by Cox and Pilcher, 1970, Original value = 8.9 ± 0.5 kcal/mol
Quantity Value Units Method Reference Comment
Deltacliquid-103.2 ± 0.4kcal/molCcbLebedev, Miroshnichenko, et al., 1975 
Deltacliquid-103.9 ± 1.0kcal/molCcbRoth and Isecke, 1944Reanalyzed by Cox and Pilcher, 1970, Original value = -102.9 kcal/mol

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil399.2KN/AMajer and Svoboda, 1985 
Quantity Value Units Method Reference Comment
Tfus287.05KN/ATimmermans and Hennaut-Roland, 1955Uncertainty assigned by TRC = 0.2 K; TRC
Quantity Value Units Method Reference Comment
Deltavap11.94kcal/molN/AMajer and Svoboda, 1985 
Deltavap10.5 ± 0.1kcal/molCLebedev, Miroshnichenko, et al., 1975ALS

Enthalpy of vaporization

DeltavapH (kcal/mol) Temperature (K) Method Reference Comment
10.3301.AStephenson and Malanowski, 1987Based on data from 286. - 373. K.; AC
10.3328.AStephenson and Malanowski, 1987Based on data from 313. - 373. K. See also Boublik, Fried, et al., 1984 and Edwards, 1952.; AC
11.1288.N/AStephenson and Malanowski, 1987Based on data from 273. - 313. K. See also Boublik, Fried, et al., 1984 and Nicholson, 1949.; AC
9.737399.2N/AMajer and Svoboda, 1985 
10.30 ± 0.50313.VEdwards, 1952, 2Reanalyzed by Pedley, Naylor, et al., 1986, Original value = 9.7 kcal/mol; ALS

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
313. - 373.4.543481582.071-49.74Edwards, 1952, 3Coefficents calculated by NIST from author's data.
273. - 313.1.75117498.772-158.538Nicholson, 1949, 2Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

DeltasubH (kcal/mol) Temperature (K) Reference Comment
11.3271.Stephenson and Malanowski, 1987Based on data from 255. - 286. K. See also Seki and Nitta, 1941.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Methane, tetranitro- + 6Carbon monoxide = 7Carbon dioxide + 2Nitrogen

By formula: CN4O8 + 6CO = 7CO2 + 2N2

Quantity Value Units Method Reference Comment
Deltar-508.7 ± 0.7kcal/molCcbGardner and Grigger, 1963liquid phase

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin J.T.LARKINS U.S. DEPT. OF COMMERCE, WASHINGTON, D.C., USA
NIST MS number 38932

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lebedev, Miroshnichenko, et al., 1975
Lebedev, V.P.; Miroshnichenko, E.A.; Matyushin, Yu.N.; Larionov, V.P.; Romanov, V.S.; Bukolov, Yu.E.; Denisov, G.M.; Balepin, A.A.; Lebedev, Yu.A., Semimicrocalorimetric determination of gas-phase enthalpies of formation of compounds containing nitrogen and oxygen. II. calorimetric determinationi of enthalpies of formation [of Tetranitromethane], Russ. J. Phys. Chem. (Engl. Transl.), 1975, 49, 1133-1136, In original 1933. [all data]

Gardner and Grigger, 1963
Gardner, D.M.; Grigger, J.C., Heat of formation of tetranitromethane by combustion calorimetry, J. Chem. Eng. Data, 1963, 8, 73-74. [all data]

Roth and Isecke, 1944
Roth, W.A.; Isecke, K., Die verbrennungs- und bildungswarme des tetranitromethans, Ber., 1944, 77, 537-539. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Timmermans and Hennaut-Roland, 1955
Timmermans, J.; Hennaut-Roland, M., Work of the International Bureau of Physical-Chemical Standards. IX. The Physical Constants of Twenty Organic Compounds, J. Chim. Phys. Phys.-Chim. Biol., 1955, 52, 223. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Edwards, 1952
Edwards, G., The vapour pressure of tetranitromethane, Trans. Faraday Soc., 1952, 48, 513, https://doi.org/10.1039/tf9524800513 . [all data]

Nicholson, 1949
Nicholson, A.J.C., 331. Some physical properties of tetranitromethane, J. Chem. Soc., 1949, 1553, https://doi.org/10.1039/jr9490001553 . [all data]

Edwards, 1952, 2
Edwards, G., The vapour pressure of tetranitromethane, Trans. Faraday Soc., 1952, 48, 000. [all data]

Pedley, Naylor, et al., 1986
Pedley, J.B.; Naylor, R.D.; Kirby, S.P., Thermochemical Data of Organic Compounds, Chapman and Hall, New York, 1986, 1-792. [all data]

Edwards, 1952, 3
Edwards, G., The Vapour Pressure of Tetranitromethane, Trans. Faraday Soc., 1952, 48, 513-515, https://doi.org/10.1039/tf9524800513 . [all data]

Nicholson, 1949, 2
Nicholson, A.J.C., Some Physical Properties of Tetranitromethane, J. Chem. Soc., 1949, 1553-1555, https://doi.org/10.1039/jr9490001553 . [all data]

Seki and Nitta, 1941
Seki, S.; Nitta, I., J. Chem. Soc. Jpn., 1941, 62, 907. [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Mass spectrum (electron ionization), References