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Propene

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Kenneth Kroenlein director
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil225.6 ± 0.6KAVGN/AAverage of 9 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus88.0KN/AStreng, 1971Uncertainty assigned by TRC = 0.3 K; TRC
Tfus87.9KN/AHaselden and Snowden, 1962Uncertainty assigned by TRC = 0.4 K; TRC
Tfus88.25KN/AParks and Huffman, 1931Uncertainty assigned by TRC = 1. K; TRC
Tfus87.95KN/ACoffin and Maass, 1927Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Ttriple87.8 ± 0.8KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Ptriple9.50barN/AAngus, Armstrong, et al., 1980Uncertainty assigned by TRC = 0.15 bar; TRC
Quantity Value Units Method Reference Comment
Tc365.2 ± 0.8KAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Pc46.0 ± 0.3barN/ATsonopoulos and Ambrose, 1996 
Pc45.79barN/AOhgaki, Umezono, et al., 1990Uncertainty assigned by TRC = 0.15 bar; TRC
Pc46.646barN/AAngus, Armstrong, et al., 1980Uncertainty assigned by TRC = 2.00 bar; TRC
Pc46.21barN/AMarchman, Prengle, et al., 1949Uncertainty assigned by TRC = 0.1519 bar; TRC
Pc45.9468barN/ASeibert and Burrell, 1915Uncertainty assigned by TRC = 0.3333 bar; TRC
Quantity Value Units Method Reference Comment
Vc0.1846l/molN/ATsonopoulos and Ambrose, 1996 
Vc0.192l/molN/AMarchman, Prengle, et al., 1949Uncertainty assigned by TRC = 0.005 l/mol; TRC
Quantity Value Units Method Reference Comment
rhoc5.42 ± 0.03mol/lN/ATsonopoulos and Ambrose, 1996 
rhoc5.549mol/lN/AOhgaki, Umezono, et al., 1990Uncertainty assigned by TRC = 0.07 mol/l; TRC
rhoc5.309mol/lN/AAngus, Armstrong, et al., 1980Uncertainty assigned by TRC = 0.36 mol/l; TRC
Quantity Value Units Method Reference Comment
Deltavap16.04kJ/molN/AMajer and Svoboda, 1985 

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
18.42225.5N/AMajer and Svoboda, 1985 
18.418225.35N/APowell and Giauque, 1939DH
18.7312.AStephenson and Malanowski, 1987Based on data from 297. - 363. K.; AC
22.2146.AStephenson and Malanowski, 1987Based on data from 104. - 161. K.; AC
18.7256.AStephenson and Malanowski, 1987Based on data from 228. - 271. K.; AC
18.5285.AStephenson and Malanowski, 1987Based on data from 270. - 327. K.; AC
18.8340.AStephenson and Malanowski, 1987Based on data from 325. - 363. K.; AC
19.2227.AStephenson and Malanowski, 1987Based on data from 161. - 242. K. See also Dykyj, 1970.; AC
18.7360.N/AMichels, Wassenaar, et al., 1953Based on data from 298. - 423. K.; AC
19.6211.N/APowell and Giauque, 1939Based on data from 166. - 226. K.; AC
19.3268.N/AMaass and Wright, 1921Based on data from 236. - 283. K. See also Boublik, Fried, et al., 1984.; AC

Entropy of vaporization

DeltavapS (J/mol*K) Temperature (K) Reference Comment
81.73225.35Powell and Giauque, 1939DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
165.81 - 225.983.97488795.819-24.884Powell and Giauque, 1939Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
3.00387.85Chao, Hall, et al., 1983DH
3.00287.85Powell and Giauque, 1939DH
2.93388.2Huffman, Parks, et al., 1931DH
2.9388.2Domalski and Hearing, 1996AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
34.1887.85Chao, Hall, et al., 1983DH
34.1887.85Powell and Giauque, 1939DH
33.388.2Huffman, Parks, et al., 1931DH

Temperature of phase transition

Ttrs (K) Initial Phase Final Phase Reference Comment
56.0crystalineglassTakeda, Oguni, et al., 1990DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Streng, 1971
Streng, A.G., Miscibility and Compatibility of Some Liquid and Solidified Gases at Low Temperature, J. Chem. Eng. Data, 1971, 16, 357. [all data]

Haselden and Snowden, 1962
Haselden, G.G.; Snowden, P., Equilibrium Properties of the Carbon Dioxide+ Propylene and Carbon Dioxide + Cyclopropane Systems at Low Temperatures, Trans. Faraday Soc., 1962, 58, 1515-28. [all data]

Parks and Huffman, 1931
Parks, G.S.; Huffman, H.M., Some fusion and transition data for hydrocarbons, Ind. Eng. Chem., 1931, 23, 1138-9. [all data]

Coffin and Maass, 1927
Coffin, C.C.; Maass, O., The Prepartion and Physical Properties of Isobutylene, Trans. R. Soc. Can., Sect. 3, 1927, 21, 33. [all data]

Angus, Armstrong, et al., 1980
Angus, S.; Armstrong, B.; de Reuck, K.M., International Thermodynamic Tables of the Fluid State-7 Propylene, International Union of Pure and Applied Chemistry, Pergamon Press, Oxford, 1980, 0. [all data]

Tsonopoulos and Ambrose, 1996
Tsonopoulos, C.; Ambrose, D., Vapor-Liquid Critical Properties of Elements and Compounds. 6. Unsaturated Aliphatic Hydrocarbons, J. Chem. Eng. Data, 1996, 41, 645-656. [all data]

Ohgaki, Umezono, et al., 1990
Ohgaki, K.; Umezono, S.; Katayama, T., Pressure-density-temperature (p-«rho»-T) relations of fluoroform, nitrous oxide, and propene in the critical region, J. Supercrit. Fluids, 1990, 3, 78-84. [all data]

Marchman, Prengle, et al., 1949
Marchman, H.; Prengle, H.W.; Motard, R.L., Compressibility and Critical Constants of Propylene Vapor, Ind. Eng. Chem., 1949, 41, 2658. [all data]

Seibert and Burrell, 1915
Seibert, F.M.; Burrell, G.A., The Critical Constants of Normal Butane, Iso-butane and Propylene and Their Vapor Pressures at Temperatures Bewtween 0 deg.C and 120 deg.C, J. Am. Chem. Soc., 1915, 37, 2683-91. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Powell and Giauque, 1939
Powell, T.M.; Giauque, W.F., Propylene. The heat capacity, vapor pressure, heats of fusion and vaporization. The third law of thermodynamics and orientation equilibrium in the solid, J. Am. Chem. Soc., 1939, 61, 2366-2370. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Dykyj, 1970
Dykyj, J., Petrochemica, 1970, 10, 2, 51. [all data]

Michels, Wassenaar, et al., 1953
Michels, A.; Wassenaar, T.; Louwerse, P.; Lunbeck, R.J.; Wolkers, G.J., Isotherms and thermodynamical functions of propene at temperatures between 25° and 150°c and at densities up to 340 amagat (pressures up to 2800 atm), Physica, 1953, 19, 1-12, 287-297, https://doi.org/10.1016/S0031-8914(53)80030-3 . [all data]

Maass and Wright, 1921
Maass, O.; Wright, C.H., SOME PHYSICAL PROPERTIES OF HYDROCARBONS CONTAINING TWO AND THREE CARBON ATOMS., J. Am. Chem. Soc., 1921, 43, 5, 1098-1111, https://doi.org/10.1021/ja01438a013 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]

Chao, Hall, et al., 1983
Chao, J.; Hall, K.R.; Yao, J.M., Thermodynamic properties of simple alkenes, Thermochim. Acta, 1983, 64(3), 285-303. [all data]

Huffman, Parks, et al., 1931
Huffman, H.M.; Parks, G.S.; Barmore, M., Thermal data on organic compounds. X. Further studies on the heat capacities, entropies and free energies of hydrocarbons, J. Am. Chem. Soc., 1931, 53, 3876-3888. [all data]

Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D., Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III, J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985 . [all data]

Takeda, Oguni, et al., 1990
Takeda, K.; Oguni, M.; Suga, H., A DTA apparatus for vapour-deposited samples. Characterisation of some vapour-deposited hydrocarbons, Thermochim. Acta, 1990, 158(1), 195-203. [all data]


Notes

Go To: Top, Phase change data, References