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Benzene-D6

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil345.430KN/AIngold, Raisin, et al., 1935Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Tfus280.0KN/AIngold, Raisin, et al., 1935Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Ttriple279.9KN/AZiegler and Andrews, 1942Uncertainty assigned by TRC = 0.1 K; TRC
Quantity Value Units Method Reference Comment
Deltavap34.2kJ/molN/ADavis and Schiessler, 1953Based on data from 283. - 352. K.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
283. - 355.4.013791196.51-53.932Davis and Schiessler, 1953Coefficents calculated by NIST from author's data.

Enthalpy of fusion

DeltafusH (kJ/mol) Temperature (K) Reference Comment
9.791279.85Ziegler and Andrews, 1942, 2DH
9.79279.9Ziegler and Andrews, 1942, 2AC

Entropy of fusion

DeltafusS (J/mol*K) Temperature (K) Reference Comment
34.99279.85Ziegler and Andrews, 1942, 2DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ingold, Raisin, et al., 1935
Ingold; Raisin, C.G.; Wilson, J. Chem. Soc., 1935, 1935, 915. [all data]

Ziegler and Andrews, 1942
Ziegler, W.T.; Andrews, D.H., The heat capacity of benzene-d6, J. Am. Chem. Soc., 1942, 64, 2482. [all data]

Davis and Schiessler, 1953
Davis, Raymond T.; Schiessler, Robert W., Vapor Pressures of Perdeuterobenzene and of Perdeuterocyclohex ane, J. Phys. Chem., 1953, 57, 9, 966-968, https://doi.org/10.1021/j150510a027 . [all data]

Ziegler and Andrews, 1942, 2
Ziegler, W.T.; Andrews, D.H., The heat capacity of benzene-d6, J. Am. Chem. Soc., 1942, 64, 2482-2485. [all data]


Notes

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