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Pentane, 3-chloro-3-methyl-

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Deltafliquid-260. ± 3.kJ/molCmArnett and Pienta, 1980Hydrochlorination

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
BS - Robert L. Brown and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil341.65KN/AWhitmore and Badertscher, 1933Uncertainty assigned by TRC = 3. K; TRC

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
388.71.01Aldrich Chemical Company Inc., 1990BS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen chloride + 2-Pentene, 3-methyl-, (Z)- = Pentane, 3-chloro-3-methyl-

By formula: HCl + C6H12 = C6H13Cl

Quantity Value Units Method Reference Comment
Deltar-67.2 ± 1.9kJ/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochlorination

Pentane, 3-methylene- + Hydrogen chloride = Pentane, 3-chloro-3-methyl-

By formula: C6H12 + HCl = C6H13Cl

Quantity Value Units Method Reference Comment
Deltar-58.9 ± 2.0kJ/molCmArnett and Pienta, 1980liquid phase; solvent: Methylene chloride; Hydrochlorination

Pentane, 2-chloro-2-methyl- = Pentane, 3-chloro-3-methyl-

By formula: C6H13Cl = C6H13Cl

Quantity Value Units Method Reference Comment
Deltar2.8 ± 0.3kJ/molEqkAndreevskii, Kabo, et al., 1974liquid phase; Isomerization

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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IR spectrum
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Additional Data

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Owner NIST Standard Reference Data Program
Collection (C) 2018 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin NIST Mass Spectrometry Data Center
State gas
Instrument HP-GC/MS/IRD

This IR spectrum is from the NIST/EPA Gas-Phase Infrared Database .


Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Chuck Anderson, Aldrich Chemical Co.
NIST MS number 107600

All mass spectra in this site (plus many more) are available from the NIST/EPA/NIH Mass Spectral Library. Please see the following for information about the library and its accompanying search program.


References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Arnett and Pienta, 1980
Arnett, E.M.; Pienta, N.J., Stabilities of carbonium ions in solution. 12. Heats of formation of alkyl chlorides as an entree to heats of solvation of aliphatic carbonium ions, J. Am. Chem. Soc., 1980, 102, 3329-3334. [all data]

Whitmore and Badertscher, 1933
Whitmore, F.C.; Badertscher, D.E., The Yields of Some Aliphatic Tertiary Grignard Reagents and the Limits of their Usefulness as Synthetic Reagents, J. Am. Chem. Soc., 1933, 55, 1559. [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Andreevskii, Kabo, et al., 1974
Andreevskii, D.N.; Kabo, G.Ya.; Esipenok, G.E., Equilibria and thermodynamics of the isomerisation of methylchloropentanes, Russ. J. Phys. Chem. (Engl. Transl.), 1974, 48, 955. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References