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Acetone

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Deltafliquid-249.4 ± 0.63kJ/molCmWiberg, Crocker, et al., 1991ALS
Quantity Value Units Method Reference Comment
Deltacliquid-1772.kJ/molCcbGuinchant, 1918Corresponding «DELTA»fliquid = -267. kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Deltacliquid-1804.2kJ/molCcbEmery and Benedict, 1911Corresponding «DELTA»fliquid = -233.8 kJ/mol (simple calculation by NIST; no Washburn corrections); ALS
Quantity Value Units Method Reference Comment
liquid200.4J/mol*KN/AKelley, 1929DH
liquid200.0J/mol*KN/AParks, Kelley, et al., 1929Extrapolation below 90 K, 54.0 J/mol*K. Revision of previous data.; DH
liquid220.5J/mol*KN/AParks and Kelley, 1928Extrapolation below 70 K, 60.04 J/mol*K.; DH
liquid217.6J/mol*KN/AParks and Kelley, 1925Extrapolation below 90 K, 71.63 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
125.45298.15Malhotra and Woolf, 1991T = 278 to 323 K. Cp(liq) = 1.337 + 2.7752x10-3(T/K) kJ/kg*K (278.15 to 323.15 K).; DH
123.80298.15Costas, Yao, et al., 1989DH
126.6298.15Petrov, Peshekhodov, et al., 1989T = 258.15, 278.15, 298.15, 318.15 K.; DH
126.6298.15Al'per, Peshekhodov, et al., 1986DH
123.8298.15Costas and Patterson, 1985T = 283.15, 298.15, 313.15 K.; DH
123.8298.15Costas and Patterson, 1985, 2DH
125.9298.15Saluja, Peacock, et al., 1979DH
129.7298.Deshpande and Bhatagadde, 1971T = 298 to 318 K.; DH
126.3293.Rastorguev and Ganiev, 1967T = 293 to 333 K.; DH
125.56298.2Low and Moelwyn-Hughes, 1962T = 253 to 308 K.; DH
128.24298.Staveley, Tupman, et al., 1955T = 288 to 323 K.; DH
128.4302.4Phillip, 1939DH
124.7298.Trew and Watkins, 1933DH
124.7298.Trew, 1932DH
124.68296.99Kelley, 1929T = 16 to 298 K. Value is unsmoothed experimental datum.; DH
124.3260.Mitsukuri and Hara, 1929T = 200 to 260 K.; DH
123.8298.4Parks and Kelley, 1928T = 70 to 289 K. Value is unsmoothed experimental datum.; DH
124.7289.4Parks and Kelley, 1925T = 70 to 290 K. Value is unsmoothed experimental datum.; DH
125.9293.2Williams and Daniels, 1925T = 20 to 40°C.; DH
121.3283.Bramley, 1916Mean value, 0 to 20°C.; DH
133.9298.von Reis, 1881T = 289 to 352 K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
96.173.Maass and Walbauer, 1925T = 93 to 173 K.; DH

References

Go To: Top, Condensed phase thermochemistry data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Wiberg, Crocker, et al., 1991
Wiberg, K.B.; Crocker, L.S.; Morgan, K.M., Thermochemical studies of carbonyl compounds. 5. Enthalpies of reduction of carbonyl groups, J. Am. Chem. Soc., 1991, 113, 3447-3450. [all data]

Guinchant, 1918
Guinchant, M.J., Etude sur la fonction acide dans les derives metheniques et methiniques, Ann. Chem., 1918, 10, 30-84. [all data]

Emery and Benedict, 1911
Emery, A.G.; Benedict, F.G., The heat of combustion of compounds of physiological importance, Am. J. Physiol., 1911, 28, 301-307. [all data]

Kelley, 1929
Kelley, K.K., The heats capacities of isopropyl alcohol and acetone from 16 to 298 °K and the corresponding entropies and free energies, J. Am. Chem. Soc., 1929, 51, 1145-1150. [all data]

Parks, Kelley, et al., 1929
Parks, G.S.; Kelley, K.K.; Huffman, H.M., Thermal data on organic compounds. V. A revision of the entropies and free energies of nineteen organic compounds, J. Am. Chem. Soc., 1929, 51, 1969-1973. [all data]

Parks and Kelley, 1928
Parks, G.S.; Kelley, K.K., The application of the third law of thermodynamics to some organic reactions, J. Phys. Chem., 1928, 32, 734-750. [all data]

Parks and Kelley, 1925
Parks, G.S.; Kelley, K.K., Thermal data on organic compounds. II. The heat capacities of five organic compounds. The entropies and free energies of some homologous series of aliphatic compounds, J. Am. Chem. Soc., 1925, 47, 2089-2097. [all data]

Malhotra and Woolf, 1991
Malhotra, R.; Woolf, L.A., Thermodynamic properties of propanone (acetone) at temperatures from 278 K to 323 K and pressures up to 400 Mpa, J. Chem. Thermodynam., 1991, 23, 867-876. [all data]

Costas, Yao, et al., 1989
Costas, M.; Yao, Z.; Patterson, D., Complex formation and self-association in ternary mixtures, J. Chem. Soc., Faraday Trans., 1989, 1 85(8), 2211-2227. [all data]

Petrov, Peshekhodov, et al., 1989
Petrov, A.N.; Peshekhodov, P.B.; Al'per, G.A., Heat capacity of non-aqueous solutions of non-electrolyts with N,N-dimethylformamide as a base, Sbornik Nauch. Trud., Termodin. Rast. neelect., Ivanovo, Inst. nevod. rast., 1989, Akad. [all data]

Al'per, Peshekhodov, et al., 1986
Al'per, G.A.; Peshekhodov, P.B.; Nikiforov, M.Yu.; Petrov, A.N.; Krestov, G.A., Specific heats and features of the intermolecular interactions in the system chloroform-acetone, Zhur. Obshchei Khim., 1986, 56(8), 1688-1691. [all data]

Costas and Patterson, 1985
Costas, M.; Patterson, D., Heat capacities of water + organic-solvent mixtures, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 2381-2398. [all data]

Costas and Patterson, 1985, 2
Costas, M.; Patterson, D., Self-association of alcohols in inert solvents, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 635-654. [all data]

Saluja, Peacock, et al., 1979
Saluja, P.P.S.; Peacock, L.A.; Fuchs, R., Enthalpies of interaction of aliphatic ketones with polar and nonpolar solvents, J. Am. Chem. Soc., 1979, 101, 1958-1962. [all data]

Deshpande and Bhatagadde, 1971
Deshpande, D.D.; Bhatagadde, L.G., Heat capacities at constant volume, free volumes, and rotational freedom in some liquids, Aust. J. Chem., 1971, 24, 1817-1822. [all data]

Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A., Study of the heat capacity of selected solvents, Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]

Low and Moelwyn-Hughes, 1962
Low, D.I.R.; Moelwyn-Hughes, E.A., The heat capacities of acetone, methyl iodide and mixtures thereof in the liquid state, Proc. Roy. Soc. (London), 1962, A267, 384-394. [all data]

Staveley, Tupman, et al., 1955
Staveley, L.A.K.; Tupman, W.I.; Hart, K.R., Some thermodynamice properties of the systems benzene + ethylene dichloride, benzene + carbon tetrachloride, acetone + chloroform, and acetone + carbon disulphide, Trans. Faraday Soc., 1955, 51, 323-342. [all data]

Phillip, 1939
Phillip, N.M., Adiabatic and isothermal compressibilities of liquids, Proc. Indian Acad. Sci., 1939, A9, 109-120. [all data]

Trew and Watkins, 1933
Trew, V.C.G.; Watkins, G.M.C., Some physical properties of mixtures of certain organic liquids, Trans. Faraday Soc., 1933, 29, 1310-1318. [all data]

Trew, 1932
Trew, V.C.G., Physical properties of mixtures of acetone and bromoform, Trans. Faraday Soc., 1932, 28, 509-514. [all data]

Mitsukuri and Hara, 1929
Mitsukuri, S.; Hara, K., Specific heats of acetone, methyl-, ethyl-, and n-propyl-alcohols at low temperatures, Bull. Chem. Soc. Japan, 1929, 4, 77-81. [all data]

Williams and Daniels, 1925
Williams, J.W.; Daniels, F., The specific heats of binary mixtures, J. Am. Chem. Soc., 1925, 47, 1490-1503. [all data]

Bramley, 1916
Bramley, A., The study of binary mixtures. Part IV. Heats of reaction and specific heats, J. Chem. Soc. (London), 1916, 109, 496-515. [all data]

von Reis, 1881
von Reis, M.A., Die specifische Wärme flüssiger organischer Verbindungen und ihre Beziehung zu deren Moleculargewicht, Ann. Physik [3], 1881, 13, 447-464. [all data]

Maass and Walbauer, 1925
Maass, O.; Walbauer, L.J., The specific heats and latent heats of fusion of ice and of several organic compounds, J. Am. Chem. Soc., 1925, 47, 1-9. [all data]


Notes

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