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1,2-Ethanediol, diacetate

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny, director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Tboil459.7KN/AAldrich Chemical Company Inc., 1990BS
Tboil463.2KN/AWeast and Grasselli, 1989BS
Tboil466.15KN/AKusano, 1978Uncertainty assigned by TRC = 1.5 K; accompanied by decomposition; TRC
Quantity Value Units Method Reference Comment
Deltavap61.4 ± 0.2kJ/molGSVerevkin, Emel'yanenko, et al., 2009Based on data from 291. - 334. K.; AC
Deltavap61.44 ± 0.15kJ/molCNilsson and Wadso, 1986ALS
Deltavap61.4 ± 0.2kJ/molCNilsson and Wadso, 1986AC
Deltavap61.04 ± 0.02kJ/molCKusano and Wads, 1970ALS
Deltavap61.0 ± 0.1kJ/molCKusano and Wadso, 1970AC

Enthalpy of vaporization

DeltavapH (kJ/mol) Temperature (K) Method Reference Comment
55.2326.AStephenson and Malanowski, 1987Based on data from 311. - 464. K.; AC
57.6388.N/ATaylor and Rinkenbach, 1926Based on data from 373. - 463. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
373. - 463.3.34065990.526-166.6Taylor and Rinkenbach, 1926Coefficents calculated by NIST from author's data.

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Go To: Top, Phase change data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Kusano, 1978
Kusano, K., Densities, Refractive Indexes, and Normal Boiling Points of 1,2-Disubstituted Ethylene Glycol Derivatives, J. Chem. Eng. Data, 1978, 23, 141. [all data]

Verevkin, Emel'yanenko, et al., 2009
Verevkin, Sergey P.; Emel'yanenko, Vladimir N.; Toktonov, Alexey V.; Leolko, Anna S.; Duwensee, Julia; Kragl, Udo; Sarge, Stefan M., Thermochemical and Ab Initio Studies of Biodiesel Fuel Surrogates: 1,2,3-Propanetriol Triacetate, 1,2-Ethanediol Diacetate, and 1,2-Ethanediol Monoacetate «8224», Ind. Eng. Chem. Res., 2009, 48, 15, 7388-7399, https://doi.org/10.1021/ie900308u . [all data]

Nilsson and Wadso, 1986
Nilsson, S.-O.; Wadso, I., Thermodynamic properties of some mono-, di-, and tri esters. Enthalpies of solution in water at 288.15 to 318.15 K and enthalpies of vaporization and heat capacities at 298.15 K, J. Chem. Thermodyn., 1986, 18, 673-681. [all data]

Kusano and Wads, 1970
Kusano, K.; Wads, I., Enthalpies of vaporization of organic compounds, Acta Chem. Scand., 1970, 24, 2037. [all data]

Kusano and Wadso, 1970
Kusano, K.; Wadso, I., Enthalpies of vaporization of organic compounds, Acta Chem. Scand., 1970, 24, 2037-2042. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Taylor and Rinkenbach, 1926
Taylor, C.A.; Rinkenbach, Wm.H., THE PROPERTIES OF GLYCOL DIACETATE 1, J. Am. Chem. Soc., 1926, 48, 5, 1305-1309, https://doi.org/10.1021/ja01416a026 . [all data]

Boublik, Fried, et al., 1984
Boublik, T.; Fried, V.; Hala, E., The Vapour Pressures of Pure Substances: Selected Values of the Temperature Dependence of the Vapour Pressures of Some Pure Substances in the Normal and Low Pressure Region, 2nd ed., Elsevier, New York, 1984, 972. [all data]


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