Dimethyl ether

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
ΔfH°gas-43.99 ± 0.12kcal/molCcbPilcher, Pell, et al., 1964ALS
Quantity Value Units Method Reference Comment
ΔcH°gas-349.04 ± 0.11kcal/molCcbPilcher, Pell, et al., 1964Corresponding ΔfHºgas = -44.01 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
10.10100.Chao J., 1986p=1 bar. Selected values are in close agreement with other statistically calculated values [ Handi M.A., 1954, Seha Z., 1955, Banerjee S.C., 1964, Stull D.R., 1969] and ab initio result [ East A.L.L., 1997] at low temperatures. Discrepancies in S(1000 K) and Cp(1000 K) amount to about 5 and 3 J/mol*K, respectively, for [ Handi M.A., 1954, Banerjee S.C., 1964, Stull D.R., 1969].; GT
11.71150.
13.02200.
14.95273.15
15.67 ± 0.02298.15
15.73300.
18.80400.
21.84500.
24.584600.
27.015700.
29.156800.
31.033900.
32.6721000.
34.1041100.
35.3471200.
36.4271300.
37.3691400.
38.1861500.
39.8111750.
40.9892000.
41.8622250.
42.5222500.
43.0282750.
43.4273000.

Constant pressure heat capacity of gas

Cp,gas (cal/mol*K) Temperature (K) Reference Comment
14.82272.20Kistiakowsky G.B., 1940GT
15.75300.76
16.81333.25
17.96370.42

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
S°liquid35.031cal/mol*KN/AKennedy, Sagenkahn, et al., 1941 

Constant pressure heat capacity of liquid

Cp,liquid (cal/mol*K) Temperature (K) Reference Comment
24.450240.Kennedy, Sagenkahn, et al., 1941T = 14 to 240 K.

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
DH - Eugene S. Domalski and Elizabeth D. Hearing

Quantity Value Units Method Reference Comment
Tboil248.2KN/AWeast and Grasselli, 1989BS
Tboil248.3KN/AMajer and Svoboda, 1985 
Tboil248.25KN/AGrosse, 1937Uncertainty assigned by TRC = 1. K; TRC
Tboil249.2KN/AMaass and Boomer, 1922Uncertainty assigned by TRC = 0.4 K; TRC
Tboil249.5KN/AThiele and Schulte, 1920Uncertainty assigned by TRC = 0.6 K; TRC
Quantity Value Units Method Reference Comment
Tfus135.2KN/AMaass and Boomer, 1922Uncertainty assigned by TRC = 2. K; TRC
Quantity Value Units Method Reference Comment
Ttriple131.64KN/AWilhoit, Chao, et al., 1985Uncertainty assigned by TRC = 0.05 K; TRC
Ttriple131.66KN/AKennedy, Sagenkahn, et al., 1941, 2Uncertainty assigned by TRC = 0.06 K; TRC
Quantity Value Units Method Reference Comment
Tc401. ± 2.KAVGN/AAverage of 12 values; Individual data points
Quantity Value Units Method Reference Comment
Pc53. ± 3.atmAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Vc0.164l/molN/AZawisza and Glowka, 1970Uncertainty assigned by TRC = 0.003 l/mol; TRC
Quantity Value Units Method Reference Comment
ρc5.351mol/lN/AEdwards and Maass, 1935Uncertainty assigned by TRC = 0.43 mol/l; TRC
ρc4.895mol/lN/ATapp, Steacie, et al., 1933Uncertainty assigned by TRC = 0.65 mol/l; TRC
ρc5.891mol/lN/ACardoso and Coppola, 1923Uncertainty assigned by TRC = 0.07 mol/l; extraplation of rectilinear diameter, from obs L and G densities, to Tc = 126.9 deg C, from previous literature; TRC
Quantity Value Units Method Reference Comment
ΔvapH°4.61kcal/molN/AMajer and Svoboda, 1985 
ΔvapH°4.42kcal/molN/AAmbrose, Ellender, et al., 1976Based on data from 171. - 248. K.; AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
5.1410248.34N/AKennedy, Sagenkahn, et al., 1941P = 101.325 kPa; DH
5.141248.3N/AMajer and Svoboda, 1985 
5.40250.AStephenson and Malanowski, 1987Based on data from 183. - 265. K.; AC
5.45234.AStephenson and Malanowski, 1987Based on data from 180. - 249. K.; AC
5.07308.AStephenson and Malanowski, 1987Based on data from 293. - 360. K.; AC
5.04364.AStephenson and Malanowski, 1987Based on data from 349. - 400. K.; AC
5.31256.AStephenson and Malanowski, 1987Based on data from 241. - 303. K.; AC
5.11248.N/AAmbrose, Ellender, et al., 1976Based on data from 171. - 248. K.; AC
5.43233.N/AKennedy, Sagenkahn, et al., 1941Based on data from 195. - 248. K.; AC
5.14 ± 0.02248.CKennedy, Sagenkahn, et al., 1941AC

Entropy of vaporization

ΔvapS (cal/mol*K) Temperature (K) Reference Comment
20.70248.34Kennedy, Sagenkahn, et al., 1941P; DH

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (atm)
    T = temperature (K)

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Temperature (K) A B C Reference Comment
194.93 - 248.244.10904894.669-30.604Kennedy, Sagenkahn, et al., 1941Coefficents calculated by NIST from author's data.

Enthalpy of fusion

ΔfusH (kcal/mol) Temperature (K) Reference Comment
1.1798131.66Kennedy, Sagenkahn, et al., 1941DH
1.18131.7Domalski and Hearing, 1996AC

Entropy of fusion

ΔfusS (cal/mol*K) Temperature (K) Reference Comment
8.960131.66Kennedy, Sagenkahn, et al., 1941DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:

Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) • Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°39.4 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°39.5kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°39.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°31.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
39.4 (+2.5,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

C3H7O2+ + Dimethyl ether = (C3H7O2+ • Dimethyl ether)

By formula: C3H7O2+ + C2H6O = (C3H7O2+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°30.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°28.8cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°21.6kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C4H9O2+ + Dimethyl ether = (C4H9O2+ • Dimethyl ether)

By formula: C4H9O2+ + C2H6O = (C4H9O2+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°29.9kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°29.1cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°21.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

(Sodium ion (1+) • Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 2Dimethyl ether)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 2.kcal/molAVGN/AAverage of 7 values; Individual data points

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) • Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°24.0 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.9 ± 1.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°22.0 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°22.2 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
17.6298.CIDCMcMahon and Ohanessian, 2000RCD

C10H10Fe+ + Dimethyl ether = (C10H10Fe+ • Dimethyl ether)

By formula: C10H10Fe+ + C2H6O = (C10H10Fe+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°9.kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M
Quantity Value Units Method Reference Comment
ΔrS°20.cal/mol*KN/AMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.7250.PHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M

(CH5O+ • 2Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (CH5O+ • 2CH4O) + C2H6O = (CH5O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°17.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°28.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 3Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (CH5O+ • 3CH4O) + C2H6O = (CH5O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°13.7kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°30.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • Methyl Alcohol)

By formula: (CH5O+ • CH4O) + C2H6O = (CH5O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°21.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°25.2cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

C2H7O+ + Dimethyl ether = (C2H7O+ • Dimethyl ether)

By formula: C2H7O+ + C2H6O = (C2H7O+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°32.0kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
ΔrH°30.7kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°31.9cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
ΔrS°29.6cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

Potassium ion (1+) + Dimethyl ether = (Potassium ion (1+) • Dimethyl ether)

By formula: K+ + C2H6O = (K+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°17.4 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°22.2kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
ΔrH°20.8kcal/molHPMSDavidson and Kebarle, 1976, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°26.8cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M
ΔrS°24.8cal/mol*KHPMSDavidson and Kebarle, 1976, 2gas phase; M

CH5O+ + Dimethyl ether = (CH5O+ • Dimethyl ether)

By formula: CH5O+ + C2H6O = (CH5O+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°35.0kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°24.7cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M

(C2H7O+ • Dimethyl ether • 2Water) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether • 2Water)

By formula: (C2H7O+ • C2H6O • 2H2O) + C2H6O = (C2H7O+ • 2C2H6O • 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°15.8kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°36.5cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

(C2H7O+ • Dimethyl ether) + Water = (C2H7O+ • Water • Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + H2O = (C2H7O+ • H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°16.3kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°38.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

(C2H7O+ • Dimethyl ether • Water) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether • Water)

By formula: (C2H7O+ • C2H6O • H2O) + C2H6O = (C2H7O+ • 2C2H6O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°16.8kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°26.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Dimethyl ether • Water) + Dimethyl ether = (C2H7O+ • 3Dimethyl ether • Water)

By formula: (C2H7O+ • 2C2H6O • H2O) + C2H6O = (C2H7O+ • 3C2H6O • H2O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
ΔrH°21.7kcal/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°41.6cal/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M

(C2H7O+ • 2Methyl Alcohol • Dimethyl ether) + Methyl Alcohol = (C2H7O+ • 3Methyl Alcohol • Dimethyl ether)

By formula: (C2H7O+ • 2CH4O • C2H6O) + CH4O = (C2H7O+ • 3CH4O • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°12.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°26.5cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Methyl Alcohol • Dimethyl ether) + Methyl Alcohol = (C2H7O+ • 2Methyl Alcohol • Dimethyl ether)

By formula: (C2H7O+ • CH4O • C2H6O) + CH4O = (C2H7O+ • 2CH4O • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°15.1kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°30.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water • 2Dimethyl ether) + Water = (C2H7O+ • 2Water • 2Dimethyl ether)

By formula: (C2H7O+ • H2O • 2C2H6O) + H2O = (C2H7O+ • 2H2O • 2C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°11.4kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°30.3cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water • 3Dimethyl ether) + Water = (C2H7O+ • 2Water • 3Dimethyl ether)

By formula: (C2H7O+ • H2O • 3C2H6O) + H2O = (C2H7O+ • 2H2O • 3C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°11.4kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°30.3cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Water • Dimethyl ether) + Water = (C2H7O+ • 3Water • Dimethyl ether)

By formula: (C2H7O+ • 2H2O • C2H6O) + H2O = (C2H7O+ • 3H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°11.6kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°26.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 2Water)

By formula: (C2H7O+ • 2H2O) + C2H6O = (C2H7O+ • C2H6O • 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°16.4kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°22.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 3Water)

By formula: (C2H7O+ • 3H2O) + C2H6O = (C2H7O+ • C2H6O • 3H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°16.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°32.9cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water • Dimethyl ether) + Water = (C2H7O+ • 2Water • Dimethyl ether)

By formula: (C2H7O+ • H2O • C2H6O) + H2O = (C2H7O+ • 2H2O • C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
ΔrH°13.6kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°24.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • Water)

By formula: (C2H7O+ • H2O) + C2H6O = (C2H7O+ • C2H6O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°18.5kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°26.3cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (C2H7O+ • 2CH4O) + C2H6O = (C2H7O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°16.6kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°31.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (C2H7O+ • 3CH4O) + C2H6O = (C2H7O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°12.5kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°25.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Dimethyl ether) + Methyl Alcohol = (C2H7O+ • Methyl Alcohol • Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + CH4O = (C2H7O+ • CH4O • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°18.1kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°30.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • Methyl Alcohol)

By formula: (C2H7O+ • CH4O) + C2H6O = (C2H7O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°20.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°29.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Dimethyl ether) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + C2H6O = (C2H7O+ • 2C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°10.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

CH6N+ + Dimethyl ether = (CH6N+ • Dimethyl ether)

By formula: CH6N+ + C2H6O = (CH6N+ • C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
ΔrH°21.5kcal/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°29.3cal/mol*KPHPMSMeot-Ner, 1984gas phase; M

(Lithium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 3Dimethyl ether)

By formula: (Li+ • 2C2H6O) + C2H6O = (Li+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°21.3 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
26.3 (+1.4,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 4Dimethyl ether)

By formula: (Li+ • 3C2H6O) + C2H6O = (Li+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°16.3 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
22.8 (+1.6,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 2Dimethyl ether)

By formula: (Li+ • C2H6O) + C2H6O = (Li+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°28.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
31.1 (+0.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Chlorine anion + Dimethyl ether = C2H6ClO-

By formula: Cl- + C2H6O = C2H6ClO-

Quantity Value Units Method Reference Comment
ΔrH°7.50 ± 0.40kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°2.9 ± 1.0kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B

C2H5O- + Hydrogen cation = Dimethyl ether

By formula: C2H5O- + H+ = C2H6O

Quantity Value Units Method Reference Comment
ΔrH°407.0 ± 2.0kcal/molBranDePuy, Bierbaum, et al., 1984gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°398.2 ± 2.2kcal/molH-TSDePuy, Bierbaum, et al., 1984gas phase; B

(Sodium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 3Dimethyl ether)

By formula: (Na+ • 2C2H6O) + C2H6O = (Na+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°16.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°16.0 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

(Sodium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 4Dimethyl ether)

By formula: (Na+ • 3C2H6O) + C2H6O = (Na+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°14.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°13.9 ± 1.0kcal/molCIDTMore, Ray, et al., 1997RCD

(Potassium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 3Dimethyl ether)

By formula: (K+ • 2C2H6O) + C2H6O = (K+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°13.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 4Dimethyl ether)

By formula: (K+ • 3C2H6O) + C2H6O = (K+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°12.0 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) • 3Dimethyl ether)

By formula: (Cs+ • 2C2H6O) + C2H6O = (Cs+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°9.6 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) • Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) • 2Dimethyl ether)

By formula: (Cs+ • C2H6O) + C2H6O = (Cs+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°11.2 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) • 3Dimethyl ether)

By formula: (Rb+ • 2C2H6O) + C2H6O = (Rb+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°8.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) • Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) • 2Dimethyl ether)

By formula: (Rb+ • C2H6O) + C2H6O = (Rb+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°13.1 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) • Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 2Dimethyl ether)

By formula: (K+ • C2H6O) + C2H6O = (K+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°16.5 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Copper ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 3Dimethyl ether)

By formula: (Cu+ • 2C2H6O) + C2H6O = (Cu+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°13.1 ± 1.0kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 4Dimethyl ether)

By formula: (Cu+ • 3C2H6O) + C2H6O = (Cu+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°10.8 ± 2.4kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 2Dimethyl ether)

By formula: (Cu+ • C2H6O) + C2H6O = (Cu+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°46.1 ± 1.9kcal/molCIDTKoizumi, 2001RCD

Cesium ion (1+) + Dimethyl ether = (Cesium ion (1+) • Dimethyl ether)

By formula: Cs+ + C2H6O = (Cs+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°13.6 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Rubidium ion (1+) + Dimethyl ether = (Rubidium ion (1+) • Dimethyl ether)

By formula: Rb+ + C2H6O = (Rb+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°14.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

k°H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference
1.0 VN/A
0.99 RN/A

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to C2H6O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)10.025 ± 0.025eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)189.kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity182.7kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
10.025 ± 0.025PIPECOButler, Holland, et al., 1984LBLHLM
9.95 ± 0.07EIBowen and Maccoll, 1984LBLHLM
10.04PEKimura, Katsumata, et al., 1981LLK
9.8 ± 0.1PEAue, Webb, et al., 1980LLK
9.8PEAue and Bowers, 1979LLK
10.01 ± 0.01PIBotter, Pechine, et al., 1977LLK
9.94 ± 0.01PECocksey, Eland, et al., 1971LLK
10.1 ± 0.2EIIvko, 1970RDSH
9.94PEDewar and Worley, 1969RDSH
9.96 ± 0.05SHernandez, 1963RDSH
10.00 ± 0.02PIWatanabe, 1957RDSH
10.0PEBajic, Humski, et al., 1985Vertical value; LBLHLM
10.1PEBieri, Asbrink, et al., 1982Vertical value; LBLHLM
11.94PEUtsunomiya, Kobayashi, et al., 1980Vertical value; LLK
10.0 ± 0.2PECarnovale, Livett, et al., 1980Vertical value; LLK
10.1PEAue and Bowers, 1979Vertical value; LLK
10.03PEKobayashi, 1978Vertical value; LLK
9.98PEBenoit and Harrison, 1977Vertical value; LLK
10.052PEAue, Webb, et al., 1975Vertical value; LLK
10.04PEBock, Mollere, et al., 1973Vertical value; LLK
10.04PECradock and Whiteford, 1972Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CHO+≤12.85 ± 0.10H2+CH3PIPECOButler, Holland, et al., 1984T = 298K; LBLHLM
CHO+14.0 ± 0.2?EIIvko, 1970RDSH
CH3+≤14.4 ± 0.1CH2O+HPIPECOButler, Holland, et al., 1984T = 298K; LBLHLM
CH3+14.93 ± 0.13?EIHaney and Franklin, 1969RDSH
CH3O+≤11.85 ± 0.10CH3PIPECOButler, Holland, et al., 1984T = 298K; LBLHLM
CH3O+≤11.8CH3EILossing, 1977LLK
CH3O+12.4 ± 0.1CH3EIIvko, 1970RDSH
CH3O+11.95 ± 0.05CH3EIHaney and Franklin, 1969RDSH
C2H5O+11.115 ± 0.010HPIPECOButler, Holland, et al., 1984T = 0K; LBLHLM
C2H5O+10.99 ± 0.08HEIBowen and Maccoll, 1984LBLHLM
C2H5O+10.99HEILossing, 1977LLK
C2H5O+11.23 ± 0.04HEISolka and Russell, 1974LLK
C2H5O+10.70 ± 0.13HEIFinney and Harrison, 1972LLK
C2H5O+11.55 ± 0.15HEIIvko, 1970RDSH
C2H5O+11.42 ± 0.01HEIMartin, Lampe, et al., 1966RDSH

De-protonation reactions

C2H5O- + Hydrogen cation = Dimethyl ether

By formula: C2H5O- + H+ = C2H6O

Quantity Value Units Method Reference Comment
ΔrH°407.0 ± 2.0kcal/molBranDePuy, Bierbaum, et al., 1984gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°398.2 ± 2.2kcal/molH-TSDePuy, Bierbaum, et al., 1984gas phase; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(CH5O+ • Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • Methyl Alcohol)

By formula: (CH5O+ • CH4O) + C2H6O = (CH5O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°21.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°25.2cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 2Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (CH5O+ • 2CH4O) + C2H6O = (CH5O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°17.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°28.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

(CH5O+ • 3Methyl Alcohol) + Dimethyl ether = (CH5O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (CH5O+ • 3CH4O) + C2H6O = (CH5O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°13.7kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°30.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be (CH3)2OH+; M

CH5O+ + Dimethyl ether = (CH5O+ • Dimethyl ether)

By formula: CH5O+ + C2H6O = (CH5O+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°35.0kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M
Quantity Value Units Method Reference Comment
ΔrS°24.7cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, note proton affinities, core ion may be ((CH3)2OH+; M

CH6N+ + Dimethyl ether = (CH6N+ • Dimethyl ether)

By formula: CH6N+ + C2H6O = (CH6N+ • C2H6O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity Value Units Method Reference Comment
ΔrH°21.5kcal/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°29.3cal/mol*KPHPMSMeot-Ner, 1984gas phase; M

(C2H7O+ • Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • Methyl Alcohol)

By formula: (C2H7O+ • CH4O) + C2H6O = (C2H7O+ • C2H6O • CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°20.2kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°29.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 2Methyl Alcohol)

By formula: (C2H7O+ • 2CH4O) + C2H6O = (C2H7O+ • C2H6O • 2CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°16.6kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°31.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Methyl Alcohol) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 3Methyl Alcohol)

By formula: (C2H7O+ • 3CH4O) + C2H6O = (C2H7O+ • C2H6O • 3CH4O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°12.5kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°25.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C2H7O+ + Dimethyl ether = (C2H7O+ • Dimethyl ether)

By formula: C2H7O+ + C2H6O = (C2H7O+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°32.0kcal/molPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
ΔrH°30.7kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°31.9cal/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1991gas phase; M
ΔrS°29.6cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(C2H7O+ • Dimethyl ether) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether)

By formula: (C2H7O+ • C2H6O) + C2H6O = (C2H7O+ • 2C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°10.1kcal/molPHPMSGrimsrud and Kebarle, 1973gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°27.9cal/mol*KPHPMSGrimsrud and Kebarle, 1973gas phase; M

(C2H7O+ • Dimethyl ether • Water) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether • Water)

By formula: (C2H7O+ • C2H6O • H2O) + C2H6O = (C2H7O+ • 2C2H6O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°16.8kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°26.6cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • Dimethyl ether • 2Water) + Dimethyl ether = (C2H7O+ • 2Dimethyl ether • 2Water)

By formula: (C2H7O+ • C2H6O • 2H2O) + C2H6O = (C2H7O+ • 2C2H6O • 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°15.8kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°36.5cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

(C2H7O+ • 2Dimethyl ether • Water) + Dimethyl ether = (C2H7O+ • 3Dimethyl ether • Water)

By formula: (C2H7O+ • 2C2H6O • H2O) + C2H6O = (C2H7O+ • 3C2H6O • H2O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity Value Units Method Reference Comment
ΔrH°21.7kcal/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°41.6cal/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M

(C2H7O+ • Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • Water)

By formula: (C2H7O+ • H2O) + C2H6O = (C2H7O+ • C2H6O • H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°18.5kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°26.3cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 2Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 2Water)

By formula: (C2H7O+ • 2H2O) + C2H6O = (C2H7O+ • C2H6O • 2H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°16.4kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°22.8cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ • 3Water) + Dimethyl ether = (C2H7O+ • Dimethyl ether • 3Water)

By formula: (C2H7O+ • 3H2O) + C2H6O = (C2H7O+ • C2H6O • 3H2O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°16.9kcal/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
ΔrS°32.9cal/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C3H7O2+ + Dimethyl ether = (C3H7O2+ • Dimethyl ether)

By formula: C3H7O2+ + C2H6O = (C3H7O2+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°30.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°28.8cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°21.6kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C4H9O2+ + Dimethyl ether = (C4H9O2+ • Dimethyl ether)

By formula: C4H9O2+ + C2H6O = (C4H9O2+ • C2H6O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity Value Units Method Reference Comment
ΔrH°29.9kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°29.1cal/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrG°21.2kcal/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C10H10Fe+ + Dimethyl ether = (C10H10Fe+ • Dimethyl ether)

By formula: C10H10Fe+ + C2H6O = (C10H10Fe+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°9.kcal/molPHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M
Quantity Value Units Method Reference Comment
ΔrS°20.cal/mol*KN/AMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
3.7250.PHPMSMeot-Ner (Mautner), 1989gas phase; Entropy change calculated or estimated, ΔrH<, DG<; M

Chlorine anion + Dimethyl ether = C2H6ClO-

By formula: Cl- + C2H6O = C2H6ClO-

Quantity Value Units Method Reference Comment
ΔrH°7.50 ± 0.40kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°2.9 ± 1.0kcal/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Cesium ion (1+) + Dimethyl ether = (Cesium ion (1+) • Dimethyl ether)

By formula: Cs+ + C2H6O = (Cs+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°13.6 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) • Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) • 2Dimethyl ether)

By formula: (Cs+ • C2H6O) + C2H6O = (Cs+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°11.2 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

(Cesium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Cesium ion (1+) • 3Dimethyl ether)

By formula: (Cs+ • 2C2H6O) + C2H6O = (Cs+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°9.6 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

Copper ion (1+) + Dimethyl ether = (Copper ion (1+) • Dimethyl ether)

By formula: Cu+ + C2H6O = (Cu+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°44.2 ± 2.9kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 2Dimethyl ether)

By formula: (Cu+ • C2H6O) + C2H6O = (Cu+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°46.1 ± 1.9kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 3Dimethyl ether)

By formula: (Cu+ • 2C2H6O) + C2H6O = (Cu+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°13.1 ± 1.0kcal/molCIDTKoizumi, 2001RCD

(Copper ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Copper ion (1+) • 4Dimethyl ether)

By formula: (Cu+ • 3C2H6O) + C2H6O = (Cu+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°10.8 ± 2.4kcal/molCIDTKoizumi, 2001RCD

Potassium ion (1+) + Dimethyl ether = (Potassium ion (1+) • Dimethyl ether)

By formula: K+ + C2H6O = (K+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°17.4 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°22.2kcal/molHPMSDavidson and Kebarle, 1976gas phase; M
ΔrH°20.8kcal/molHPMSDavidson and Kebarle, 1976, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°26.8cal/mol*KHPMSDavidson and Kebarle, 1976gas phase; M
ΔrS°24.8cal/mol*KHPMSDavidson and Kebarle, 1976, 2gas phase; M

(Potassium ion (1+) • Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 2Dimethyl ether)

By formula: (K+ • C2H6O) + C2H6O = (K+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°16.5 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 3Dimethyl ether)

By formula: (K+ • 2C2H6O) + C2H6O = (K+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°13.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD

(Potassium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Potassium ion (1+) • 4Dimethyl ether)

By formula: (K+ • 3C2H6O) + C2H6O = (K+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°12.0 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) • Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°39.4 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°39.5kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
ΔrH°39.kcal/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrS°27.cal/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
ΔrG°31.3kcal/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
39.4 (+2.5,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 2Dimethyl ether)

By formula: (Li+ • C2H6O) + C2H6O = (Li+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°28.9 ± 1.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
31.1 (+0.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 3Dimethyl ether)

By formula: (Li+ • 2C2H6O) + C2H6O = (Li+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°21.3 ± 1.9kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
26.3 (+1.4,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) • 4Dimethyl ether)

By formula: (Li+ • 3C2H6O) + C2H6O = (Li+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°16.3 ± 2.4kcal/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

ΔrH° (kcal/mol) T (K) Method Reference Comment
22.8 (+1.6,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Sodium ion (1+) + Dimethyl ether = (Sodium ion (1+) • Dimethyl ether)

By formula: Na+ + C2H6O = (Na+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°24.0 ± 1.3kcal/molCIDCAmicangelo and Armentrout, 2001Anchor NH3=24.41; RCD
ΔrH°21.9 ± 1.1kcal/molCIDTArmentrout and Rodgers, 2000RCD
ΔrH°22.0 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°22.2 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
17.6298.IMREMcMahon and Ohanessian, 2000Anchor alanine=39.89; RCD
17.6298.CIDCMcMahon and Ohanessian, 2000RCD

(Sodium ion (1+) • Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 2Dimethyl ether)

By formula: (Na+ • C2H6O) + C2H6O = (Na+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°20. ± 2.kcal/molAVGN/AAverage of 7 values; Individual data points

(Sodium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 3Dimethyl ether)

By formula: (Na+ • 2C2H6O) + C2H6O = (Na+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°16.7 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°16.0 ± 1.2kcal/molCIDTMore, Ray, et al., 1997RCD

(Sodium ion (1+) • 3Dimethyl ether) + Dimethyl ether = (Sodium ion (1+) • 4Dimethyl ether)

By formula: (Na+ • 3C2H6O) + C2H6O = (Na+ • 4C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°14.6 ± 1.0kcal/molCIDTRodgers and Armentrout, 2000RCD
ΔrH°13.9 ± 1.0kcal/molCIDTMore, Ray, et al., 1997RCD

Rubidium ion (1+) + Dimethyl ether = (Rubidium ion (1+) • Dimethyl ether)

By formula: Rb+ + C2H6O = (Rb+ • C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°14.8 ± 2.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) • Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) • 2Dimethyl ether)

By formula: (Rb+ • C2H6O) + C2H6O = (Rb+ • 2C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°13.1 ± 1.2kcal/molCIDTRodgers and Armentrout, 2000RCD

(Rubidium ion (1+) • 2Dimethyl ether) + Dimethyl ether = (Rubidium ion (1+) • 3Dimethyl ether)

By formula: (Rb+ • 2C2H6O) + C2H6O = (Rb+ • 3C2H6O)

Quantity Value Units Method Reference Comment
ΔrH°8.8 ± 2.6kcal/molCIDTRodgers and Armentrout, 2000RCD

IR Spectrum

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
NIST MS number 78

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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Takehiko Shimanouchi

Symmetry:   C2ν     Symmetry Number σ = 2
 Sym.   No   Approximate   Selected Freq.  Infrared   Raman   Comments 
 Species   type of mode   Value   Rating   Value  Phase  Value  Phase
a1 1 CH3 d-str 2996  B 2996 S gas 2989 S liq.
a1 2 CH3 s-str 2817  B 2817 S gas 2815 VS p liq.
a1 3 CH3 d-deform 1464  D 1464 M gas
a1 4 CH3 s-deform 1452  D 1452 M gas 1452 S dp liq.
a1 5 CH3 rock 1244  B 1244 W gas
a1 6 CO s-str 928  B 928 S gas 922 S p liq.
a1 7 COC deform 418  C 418 M gas 428 M p liq.
a2 8 CH3 d-str 2952  C  ia 2952 S liq.
a2 9 CH3 d-deform 1464  D  ia SF(ν3)
a2 10 CH3 rock 1150  C  ia 1150 M d liq.
a2 11 Torsion 203  E  ia CF
b1 12 CH3 d-str 2996  B 2996 S gas 2989 S liq. OV(ν1)
b1 13 CH3 s-str 2817  B 2817 S gas 2815 VS p liq. OV(ν2)
b1 14 CH3 d-deform 1464  D 1464 M gas OV(ν3)
b1 15 CH3 s-deform 1452  D 1452 M gas 1452 S dp liq. OV(ν4)
b1 16 CH3 rock 1227  C 1227 W liq.
b1 17 CO a-str 1102  B 1102 VS gas 1104 M dp liq.
b2 18 CH3 d-str 2925  B 2925 S gas
b2 19 CH3 d-deform 1464  D 1464 M gas OV(ν3)
b2 20 CH3 rock 1179  B 1179 VS gas 1170 sh liq.
b2 21 Torsion 242  C 242 W gas

Source: Shimanouchi, 1972

Notes

dPhotodissociation threshold
VSVery strong
SStrong
MMedium
WWeak
iaInactive
shShoulder
pPolarized
dpDepolarized
CFCalculated frequency
SFCalculation shows that the frequency approximately equals that of the vibration indicated in the parentheses.
OVOverlapped by band indicated in parentheses.
B1~3 cm-1 uncertainty
C3~6 cm-1 uncertainty
D6~15 cm-1 uncertainty
E15~30 cm-1 uncertainty

Gas Chromatography

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, NIST Free Links, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
PackedSqualane50.323.Becerra, Sánchez, et al., 1982N2, Chromosorb W-AM; Column length: 6. m
PackedSqualane50.325.Becerra, Sánchez, et al., 1982N2, Chromosorb W-AM; Column length: 6. m
PackedApiezon L120.324.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon L160.331.Bogoslovsky, Anvaer, et al., 1978Celite 545
PackedApiezon M130.323.Golovnya and Garbuzov, 1974N2, Chromosorb W; Column length: 2.1 m

Normal alkane RI, non-polar column, temperature ramp

View large format table.

Column type Active phase I Reference Comment
CapillaryOV-101327.Zenkevich, 200525. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

Normal alkane RI, non-polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillarySE-30350.Vinogradov, 2004Program: not specified
CapillarySPB-1328.Flanagan, Streete, et al., 199760. m/0.53 mm/5. μm, He; Program: 40C(6min) => 5C/min => 80C => 10C/min => 200C
CapillaryPolydimethyl siloxanes327.Zenkevich and Chupalov, 1996Program: not specified
CapillarySPB-1328.Strete, Ruprah, et al., 199260. m/0.53 mm/5.0 μm, Helium; Program: 40 0C (6 min) 5 0C/min -> 80 0C 10 0C/min -> 200 0C

Normal alkane RI, polar column, isothermal

View large format table.

Column type Active phase Temperature (C) I Reference Comment
CapillaryCarbowax 20M60.478.Sun, Siepmann, et al., 200630. m/0.25 mm/0.25 μm, Helium
CapillaryCarbowax 20M80.481.Sun, Siepmann, et al., 200630. m/0.25 mm/0.25 μm, Helium

Normal alkane RI, polar column, custom temperature program

View large format table.

Column type Active phase I Reference Comment
CapillaryCarbowax 20M524.Vinogradov, 2004Program: not specified

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Gas Chromatography, NIST Free Links, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Pilcher, Pell, et al., 1964
Pilcher, G.; Pell, A.S.; Coleman, D.J., Measurements of heats of combustion by flame calorimetry. Part 2-Dimethyl ether, methyl ethyl ether, methyl n-propyl ether, methyl isopropyl ether, Trans. Faraday Soc., 1964, 60, 499-505. [all data]

Chao J., 1986
Chao J., Thermodynamic properties of key organic oxygen compounds in the carbon range C1 to C4. Part 2. Ideal gas properties, J. Phys. Chem. Ref. Data, 1986, 15, 1369-1436. [all data]

Handi M.A., 1954
Handi M.A., Molecular spectroscopy. Determination and interpretation of fundamental frequencies of dimethyl ether from infrared absorption spectrum; application for thermodynamic functions calculation, Compt. Rend. Acad. Sci., 1954, 239, 349-351. [all data]

Seha Z., 1955
Seha Z., Thermodynamic functions of dimethyl ether, Chem. Listy, 1955, 49, 1569-1570. [all data]

Banerjee S.C., 1964
Banerjee S.C., Thermodynamic properties of organic compounds. Part 1. Normal symmetrical aliphatic ethers, Brit. Chem. Eng., 1964, 9, 311-313. [all data]

Stull D.R., 1969
Stull D.R., Jr., The Chemical Thermodynamics of Organic Compounds. Wiley, New York, 1969. [all data]

East A.L.L., 1997
East A.L.L., Ab initio statistical thermodynamical models for the computation of third-law entropies, J. Chem. Phys., 1997, 106, 6655-6674. [all data]

Kistiakowsky G.B., 1940
Kistiakowsky G.B., Gaseous heat capacities. III, J. Chem. Phys., 1940, 8, 618-622. [all data]

Kennedy, Sagenkahn, et al., 1941
Kennedy, R.M.; Sagenkahn, M.; Aston, J.G., The heat capacity and entropy, heats of fusion and vaporization, and the vapor pressure of dimethyl ether. The density of gaseous dimethyl ether, J. Am. Chem. Soc., 1941, 63, 2267-2272. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Majer and Svoboda, 1985
Majer, V.; Svoboda, V., Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]

Grosse, 1937
Grosse, A.V., Refractive Indices at Low Temperatures, J. Am. Chem. Soc., 1937, 59, 2739-41. [all data]

Maass and Boomer, 1922
Maass, O.; Boomer, E.H., Vapor Densities at Low Pressures and Over and Extended Temperature Range. I. The Properties of Ethylene Oxide Compared to Oxygen Compounds of Similar Molecular Weight, J. Am. Chem. Soc., 1922, 44, 8, 1709-1728, https://doi.org/10.1021/ja01429a013 . [all data]

Thiele and Schulte, 1920
Thiele, A.; Schulte, E., Binary equilibrium systems with solid carbon dioxide, Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1920, 96, 312-42. [all data]

Wilhoit, Chao, et al., 1985
Wilhoit, R.C.; Chao, J.; Hall, K.R., Thermodynamic Properties of Key Organic Compounds in the Carbon Range C1 to C4. Part 1. Properties of Condensed Phases, J. Phys. Chem. Ref. Data, 1985, 14, 1. [all data]

Kennedy, Sagenkahn, et al., 1941, 2
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Notes

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