3,3'-Dimethylbiphenyl

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcliquid-1799.7 ± 1.8kcal/molCcbBrull, 1935Reanalyzed by Cox and Pilcher, 1970, Original value = -1799.14 kcal/mol; Corresponding Δfliquid = 4.78 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

Go To: Top, Condensed phase thermochemistry data, IR Spectrum, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil559.KN/ABlades, Blades, et al., 1954Uncertainty assigned by TRC = 8. K; TRC
Tboil556.KN/ABrull, 1935Uncertainty assigned by TRC = 3. K; TRC
Tboil559.KN/AMayer and Freitak, 1921Uncertainty assigned by TRC = 3. K; TRC
Tboil561.KN/APerrier, 1892Uncertainty assigned by TRC = 5. K; TRC
Tboil562.KN/AStolle, 1888Uncertainty assigned by TRC = 5. K; TRC
Quantity Value Units Method Reference Comment
Tfus278.KN/ACastro, Andrews, et al., 1958Uncertainty assigned by TRC = 3. K; TRC
Tfus282.4KN/AJohnson, 1957Uncertainty assigned by TRC = 1.5 K; TRC
Tfus279.KN/ASchultz, Rohde, et al., 1907Uncertainty assigned by TRC = 3. K; TRC
Quantity Value Units Method Reference Comment
Δvap17.2kcal/molAStephenson and Malanowski, 1987Based on data from 288. - 308. K. See also Pribilová and Pouchlý, 1974.; AC
Quantity Value Units Method Reference Comment
Δsub17.2kcal/molMEPribilová and Pouchlý, 1974Based on data from 288. - 308. K.; AC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
559.20.938Aldrich Chemical Company Inc., 1990BS
423.20.024Weast and Grasselli, 1989BS

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


IR Spectrum

Go To: Top, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Coblentz Society, Inc.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director


Mass spectrum (electron ionization)

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-8383
NIST MS number 229735

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References

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brull, 1935
Brull, L., Sui calori di combustione di alcuni derivati del bifenil, Gazz. Chim. Ital., 1935, 65, 19-28. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Blades, Blades, et al., 1954
Blades, H.; Blades, A.; Steacie, E.W.R., The Kinetics of Pyrolysis of Toluene, Can. J. Chem., 1954, 32, 298-311. [all data]

Mayer and Freitak, 1921
Mayer, F.; Freitak, K., Chem. Ber., 1921, 54, 347. [all data]

Perrier, 1892
Perrier, G., Bull. Soc. Chim. Fr., 1892, 7, 180. [all data]

Stolle, 1888
Stolle, E., Chem. Ber., 1888, 21, 1096. [all data]

Castro, Andrews, et al., 1958
Castro, C.E.; Andrews, L.J.; Keefer, R.M., Molecular Complexes of Hindered Biphenyl Derivatives, J. Am. Chem. Soc., 1958, 80, 2322-6. [all data]

Johnson, 1957
Johnson, E.A., J. Chem. Soc., 1957, 1957, 4155. [all data]

Schultz, Rohde, et al., 1907
Schultz, G.; Rohde, G.; Vicari, F., Justus Liebigs Ann. Chem., 1907, 352, 111. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Pribilová and Pouchlý, 1974
Pribilová, J.; Pouchlý, J., Vapour pressure of some low-volatile hydrocarbons determined by the effusion method, Collect. Czech. Chem. Commun., 1974, 39, 5, 1118-1124, https://doi.org/10.1135/cccc19741118 . [all data]

Aldrich Chemical Company Inc., 1990
Aldrich Chemical Company Inc., Catalog Handbook of Fine Chemicals, Aldrich Chemical Company, Inc., Milwaukee WI, 1990, 1. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]


Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, IR Spectrum, Mass spectrum (electron ionization), References