Ethanol, 2-ethoxy-
- Formula: C4H10O2
- Molecular weight: 90.1210
- IUPAC Standard InChIKey: ZNQVEEAIQZEUHB-UHFFFAOYSA-N
- CAS Registry Number: 110-80-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: β-Ethoxyethanol; Cellosolve; Emkanol; Ethyl cellosolve; Ethylene glycol ethyl ether; Ethylene glycol monoethyl ether; Glycol monoethyl ether; Oxitol; Plastiazan 60; Poly-Solv EE; 2-Ethoxyethanol; HOCH2CH2OC2H5; Cellosolve solvent; 2-Ethoxyethyl alcohol; Ethyl-2-hydroxyethyl ether; Dowanol EE; Ether monoethylique de l'ethylene-glycol; Ethyl glycol; Ethylethylene glycol; Etoksyetylowy alkohol; Glycol ethyl ether; Hydroxy ether; NCI-C54853; 2EE; EE solvent; EGEE; Ektasolve EE; Ethoxyethanol; Ethyl icinol; Glycol ether EE; Jeffersol EE; Bikanol E 1; NSC 8837; Solvid; 2-ethoxyethanol (cellosolve)
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
209.82 | 298.15 | Svoboda, Zabransky, et al., 1991 | T = 298 to 330 K. Cp(liq) = 84.928 + 0.4189(T/K) J/mol*K. Cp value calculated from equation. |
210.5 | 298.15 | Roux, Perron, et al., 1978 | T = 283.15, 298.15, 313.15 K. Data at three temperatures. |
210.8 | 298.15 | Kusano, Suurkuusk, et al., 1973 |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 408.2 ± 0.3 | K | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 48.23 | kJ/mol | N/A | Majer and Svoboda, 1985 | |
ΔvapH° | 49.4 | kJ/mol | EB | Antosik, Fras, et al., 1999 | Based on data from 313. to 353. K.; AC |
ΔvapH° | 50.0 | kJ/mol | EB | Antosik, Fras, et al., 1999 | Based on data from 313. to 363. K.; AC |
ΔvapH° | 48.2 ± 0.1 | kJ/mol | C | Kusano, Wadsö, et al., 1971 | AC |
ΔvapH° | 49.2 | kJ/mol | I | Sunwoo and Eisen, 1971 | AC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
39.22 | 408.1 | N/A | Majer and Svoboda, 1985 | |
45.9 | 338. | TGA | Al-Najjar and Al-Sammerrai, 2007 | Based on data from 323. to 353. K.; AC |
47.4 | 325. | EB | Chylinski, Fras, et al., 2001 | Based on data from 310. to 385. K.; AC |
44.7 | 351. | A | Stephenson and Malanowski, 1987 | Based on data from 336. to 408. K. See also Pick, Fried, et al., 1956.; AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
336. to 407. | 4.86877 | 1756.857 | -46.92 | Pick, Fried, et al., 1956, 2 | Coefficents calculated by NIST from author's data. |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Svoboda, Zabransky, et al., 1991
Svoboda, V.; Zabransky, M.; Barta, M.,
Molar heat capacities of 2-methoxyethanol, 2-ethoxyethanol, and 2-propoxyethanol in the temperature range from 298K to 330K,
J. Chem. Thermodynam., 1991, 23, 711-712. [all data]
Roux, Perron, et al., 1978
Roux, G.; Perron, G.; Desnoyers, J.E.,
Model systems for hydrophobic interactions: volumes and heat capacities of n-alkoxyethanols in water,
J. Solution Chem., 1978, 7, 639-654. [all data]
Kusano, Suurkuusk, et al., 1973
Kusano, K.; Suurkuusk, J.; Wads, I.,
Thermochemistry of solutions of biochemical model compounds. 2. Alkoxyethanols and 1,2-dialkoxyethanes in water, J. Chem. Thermodynam. 5,757-767 (1973).73LEB/TSV Lebedev, B.V., Tsvetkova, L.Ya., and Rabinovich, I.B., Specific heat and thermodynamic functions of poly(vinyltrimethylsilane),
Tr. Khim. Khim. Tekhnol., 1973, (1), 17-18. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Antosik, Fras, et al., 1999
Antosik, Maria; Fras, Zbigniew; Malanowski, Stanislaw K.,
Vapor-Liquid Equilibrium in 2-Ethoxyethanol + Methanol at 313.15 to 333.15 K,
J. Chem. Eng. Data, 1999, 44, 3, 368-372, https://doi.org/10.1021/je9801011
. [all data]
Kusano, Wadsö, et al., 1971
Kusano, Kazuhito; Wadsö, Ingemar; Rømming, Chr.; Lindberg, Alf A.; Lagerlund, Inger; Ehrenberg, L.,
Enthalpies of Vaporization of Organic Compounds. VIII. Alkoxyethanols.,
Acta Chem. Scand., 1971, 25, 219-224, https://doi.org/10.3891/acta.chem.scand.25-0219
. [all data]
Sunwoo and Eisen, 1971
Sunwoo, Chimin; Eisen, Henry,
Solubility parameter of selected sulfonamides,
J. Pharm. Sci., 1971, 60, 2, 238-244, https://doi.org/10.1002/jps.2600600217
. [all data]
Al-Najjar and Al-Sammerrai, 2007
Al-Najjar, Hazim; Al-Sammerrai, Dhoaib,
Thermogravimetric determination of the heat of vaporization of some highly polar solvents,
J. Chem. Technol. Biotechnol., 2007, 37, 3, 145-152, https://doi.org/10.1002/jctb.280370302
. [all data]
Chylinski, Fras, et al., 2001
Chylinski, K.; Fras, Z.; Malanowski, S.K.,
Vapor-Liquid Equilibrium in Phenol + 2-Ethoxyethanol at 363.15 to 383.15 K,
J. Chem. Eng. Data, 2001, 46, 1, 29-33, https://doi.org/10.1021/je0001072
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Pick, Fried, et al., 1956
Pick, J.; Fried, V.; Hala, E.; Vilim, O.,
Collect. Czech. Chem. Commun., 1956, 21, 260. [all data]
Pick, Fried, et al., 1956, 2
Pick, J.; Fried, V.; Hala, E.; Vilim, O.,
Der Dampfdruck des Athylenglykolmonomethylathers und des Athylenglykolmonoathylathers,
Collect. Czech. Chem. Commun., 1956, 21, 1, 260-261, https://doi.org/10.1135/cccc19560260
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Cp,liquid Constant pressure heat capacity of liquid Tboil Boiling point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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