Carbon Tetrachloride
- Formula: CCl4
- Molecular weight: 153.823
- IUPAC Standard InChIKey: VZGDMQKNWNREIO-UHFFFAOYSA-N
- CAS Registry Number: 56-23-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Methane, tetrachloro-; Benzinoform; Carbon chloride (CCl4); Carbona; Fasciolin; Flukoids; Freon 10; Necatorina; Perchloromethane; Tetrachlorocarbon; Tetrachloromethane; Tetrafinol; Tetraform; Tetrasol; Univerm; Vermoestricid; CCl4; Benzenoform; Carbon tet; Methane tetrachloride; Czterochlorek wegla; ENT 4,705; Halon 1040; Necatorine; R 10; Tetrachloorkoolstof; Tetrachloormetaan; Tetrachlorkohlenstoff, tetra; Tetrachlormethan; Tetrachlorure de carbone; Tetraclorometano; Tetracloruro di carbonio; Chlorid uhlicity; ENT 27164; Rcra waste number U211; UN 1846; Katharin; Seretin; Thawpit; NSC 97063; R 10 (Refrigerant)
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
- NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data)
- NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Gas phase thermochemistry data
Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | -100. ± 20. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
S°gas,1 bar | 309.65 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1968 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | 298. to 6000. |
---|---|
A | 103.1134 |
B | 4.188644 |
C | -1.126475 |
D | 0.095677 |
E | -1.919624 |
F | -133.3357 |
G | 422.4334 |
H | -95.98096 |
Reference | Chase, 1998 |
Comment | Data last reviewed in December, 1968 |
Condensed phase thermochemistry data
Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -128.1 ± 2.5 | kJ/mol | Review | Manion, 2002 | adopted combustion calorimetry data of Hu and Sinke, 1969 with increased uncertainty to reflect other data; DRB |
ΔfH°liquid | -128.4 | kJ/mol | Ccr | Hu and Sinke, 1969, 2 | ALS |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -359.9 | kJ/mol | Ccr | Hu and Sinke, 1969, 2 | ALS |
ΔcH°liquid | -365.7 ± 8.4 | kJ/mol | Ccb | Smith, Bjellerup, et al., 1953 | Reanalyzed by Cox and Pilcher, 1970, Original value = -370. ± 10. kJ/mol; ALS |
Quantity | Value | Units | Method | Reference | Comment |
S°liquid | 214.39 | J/mol*K | N/A | Hicks, Hooley, et al., 1944 | DH |
S°liquid | 205.4 | J/mol*K | N/A | Latimer, 1922 | DH |
S°liquid | 219.2 | J/mol*K | N/A | Stull, 1937 | Extrapolation below 91 K; 74.31 J/mol*K.; DH |
Constant pressure heat capacity of liquid
Cp,liquid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
131.3 | 298.15 | Shehatta, 1993 | DH |
133.35 | 298.15 | Lainez, Rodrigo, et al., 1989 | DH |
133.0 | 298.15 | Petrov, Peshekhodov, et al., 1989 | T = 258.15, 278.15, 298.15, 318.15 K.; DH |
132.9 | 298.15 | Nkinamubanzi, Charlet, et al., 1985 | DH |
131.34 | 298.15 | Tanaka, 1982 | T = 293.15, 298.15, 303.15 K. Data at three temperatures.; DH |
129.8 | 293.15 | Atalla, El-Sharkawy, et al., 1981 | DH |
131.6 | 298.15 | Grolier, Hamedi, et al., 1979 | DH |
131.40 | 298.15 | Vesely, Zabransky, et al., 1979 | DH |
131.36 | 298.15 | Wilhelm, Faradjzadeh, et al., 1979 | DH |
131.57 | 298.15 | Grolier, Wilhelm, et al., 1978 | DH |
131.40 | 298.15 | Vesely, Svoboda, et al., 1977 | T = 298 to 318 K.; DH |
131.36 | 298.15 | Fortier, Benson, et al., 1976 | DH |
131.401 | 298.15 | Fortier and Benson, 1976 | DH |
131.9 | 298.15 | Grolier, Benson, et al., 1975 | DH |
131.66 | 293.15 | Wilhelm, Zettler, et al., 1974 | T = 273 to 323 K.; DH |
130.8 | 298.15 | Subrahmanyam and Rajagopal, 1973 | T = 298 to 323 K.; DH |
131.8 | 256.10 | Arentsen and Van Miltenburg, 1972 | T = 243 to 256 K. Value is unsmoothed experimental datum.; DH |
131.0 | 298. | Deshpande and Bhatagadde, 1971 | T = 298 to 318 K.; DH |
131.5 | 293. | Rastorguev and Ganiev, 1967 | T = 293 to 333 K.; DH |
130.9 | 300. | Harrison and Moelwyn-Hughes, 1957 | T = 243 to 303 K.; DH |
130.5 | 303.3 | Harrison and Moelwyn-Hughes, 1957 | T = 254 to 303 K. Unsmoothed experimental datum.; DH |
132.59 | 298. | Staveley, Tupman, et al., 1955 | T = 295 to 339 K.; DH |
128.8 | 298. | Kurbatov, 1948 | T = -20 to 72°C. Mean Cp, four temperatures.; DH |
131.67 | 298.15 | Hicks, Hooley, et al., 1944 | T = 15 to 300 K.; DH |
132.2 | 298.1 | Zhdanov, 1941 | T = 5 to 46°C.; DH |
133.1 | 301.2 | Phillip, 1939 | DH |
132.63 | 298.1 | Stull, 1937 | T = 90 to 320 K.; DH |
133.1 | 298. | Vold, 1937 | DH |
133.0 | 298. | Vold, 1937 | Cp given as 0.2066 cal/g*K.; DH |
126.4 | 288.3 | Kolosovskii and Udovenko, 1934 | DH |
126.4 | 288.3 | de Kolossowsky and Udowenko, 1933 | DH |
130.5 | 298.1 | Richards and Wallace, 1932 | T = 293 to 323 K.; DH |
128.0 | 293.2 | Williams and Daniels, 1925 | T = 20 to 50°C.; DH |
128.9 | 303. | Willams and Daniels, 1924 | T = 303 to 330 K. Equation only.; DH |
133.9 | 290. | Latimer, 1922 | T = 39.1 to 290 K.; DH |
Constant pressure heat capacity of solid
Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
44.22 | 46. | Atake and Chihara, 1971 | T = 3 to 46 K.; DH |
Phase change data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
BS - Robert L. Brown and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis
DH - Eugene S. Domalski and Elizabeth D. Hearing
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 349.8 ± 0.3 | K | AVG | N/A | Average of 82 out of 89 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 250.3 ± 0.3 | K | AVG | N/A | Average of 31 out of 37 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Ttriple | 249. ± 3. | K | AVG | N/A | Average of 7 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 556.36 | K | N/A | Altunin, Geller, et al., 1987 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tc | 556.4 | K | N/A | Majer and Svoboda, 1985 | |
Tc | 556.3 | K | N/A | Campbell and Chatterjee, 1969 | Uncertainty assigned by TRC = 0.2 K; TRC |
Tc | 558.35 | K | N/A | Livingston, Morgan, et al., 1908 | Uncertainty assigned by TRC = 5. K; calculation based on extrap. of density and surface tension; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 44.93 | bar | N/A | Altunin, Geller, et al., 1987 | Uncertainty assigned by TRC = 0.50 bar; TRC |
Pc | 45.576 | bar | N/A | Campbell and Chatterjee, 1969 | Uncertainty assigned by TRC = 0.1013 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ρc | 3.62 | mol/l | N/A | Campbell and Chatterjee, 1969 | Uncertainty assigned by TRC = 0.02 mol/l; TRC |
ρc | 3.625 | mol/l | N/A | Kordes, 1954 | Uncertainty assigned by TRC = 0.02 mol/l; TRC |
ρc | 3.625 | mol/l | N/A | Lewis, 1953 | Uncertainty assigned by TRC = 0.03 mol/l; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 32. ± 2. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
29.82 | 349.9 | N/A | Majer and Svoboda, 1985 | |
30.4 | 364. | A | Stephenson and Malanowski, 1987 | Based on data from 349. to 416. K.; AC |
29.2 | 427. | A | Stephenson and Malanowski, 1987 | Based on data from 412. to 497. K.; AC |
30.6 | 509. | A | Stephenson and Malanowski, 1987 | Based on data from 494. to 555. K.; AC |
33.7 | 277. | A,EB | Stephenson and Malanowski, 1987 | Based on data from 262. to 349. K. See also Boublík and Aim, 1972.; AC |
32.3 | 308. | N/A | Hildenbrand and McDonald, 1959 | Based on data from 293. to 351. K.; AC |
31.7 | 325. | N/A | Barker, Brown, et al., 1953 | Based on data from 313. to 338. K.; AC |
Enthalpy of vaporization
ΔvapH =
A exp(-βTr) (1 − Tr)β
ΔvapH =
Enthalpy of vaporization (at saturation pressure)
(kJ/mol)
Tr = reduced temperature (T / Tc)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A (kJ/mol) | β | Tc (K) | Reference | Comment |
---|---|---|---|---|---|
298. to 358. | 45.85 | 0.2656 | 556.4 | Majer and Svoboda, 1985 |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
View plot Requires a JavaScript / HTML 5 canvas capable browser.
Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
293.03 to 350.86 | 4.02291 | 1221.781 | -45.739 | Hildenbrand and McDonald, 1959, 2 | Coefficents calculated by NIST from author's data. |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
37.9 | 227. to 248. | N/A | Goto, Fujinawa, et al., 1996 | AC |
43.3 | 226. | B | Bondi, 1963 | AC |
38.8 | 217. | N/A | Jones, 1960 | Based on data from 209. to 225. K. See also Goto, Fujinawa, et al., 1996.; AC |
Enthalpy of fusion
ΔfusH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
2.69 | 249. | Domalski and Hearing, 1996 | AC |
Entropy of fusion
ΔfusS (J/mol*K) | Temperature (K) | Reference | Comment |
---|---|---|---|
20.49 | 224.6 | Domalski and Hearing, 1996 | CAL |
10.82 | 249. | ||
20.3 | 225.4 | ||
10.1 | 250.3 | ||
20.5 | 225.7 | ||
10.2 | 250.5 |
Enthalpy of phase transition
ΔHtrs (kJ/mol) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
4.631 | 225.7 | crystaline, II | crystaline, I | Morrison and Richards, 1976 | DH |
2.562 | 250.53 | crystaline, I | liquid | Morrison and Richards, 1976 | DH |
1.848 | 245.70 | crystaline, II | liquid | Arentsen and Van Miltenburg, 1972 | DH |
2.588 | 250.28 | crystaline, I | liquid | Arentsen and Van Miltenburg, 1972 | Stable phase.; DH |
4.581 | 225.35 | crystaline, II | crystaline, I | Chang and Westrum, 1970 | DH |
2.515 | 250.3 | crystaline, I | liquid | Chang and Westrum, 1970 | DH |
4.582 | 225.35 | crystaline, II | crystaline, I | Hicks, Hooley, et al., 1944 | DH |
2.515 | 250.3 | crystaline, I | liquid | Hicks, Hooley, et al., 1944 | DH |
4.600 | 224.6 | crystaline, II | crystaline, I | Latimer, 1922 | DH |
2.694 | 249. | crystaline, I | liquid | Latimer, 1922 | DH |
4.602 | 225.63 | crystaline, II | crystaline, I | Stull, 1937 | DH |
2.431 | 250.37 | crystaline, I | liquid | Stull, 1937 | DH |
Entropy of phase transition
ΔStrs (J/mol*K) | Temperature (K) | Initial Phase | Final Phase | Reference | Comment |
---|---|---|---|---|---|
20.52 | 225.7 | crystaline, II | crystaline, I | Morrison and Richards, 1976 | DH |
10.226 | 250.53 | crystaline, I | liquid | Morrison and Richards, 1976 | DH |
7.52 | 245.70 | crystaline, II | liquid | Arentsen and Van Miltenburg, 1972 | DH |
10.22 | 250.28 | crystaline, I | liquid | Arentsen and Van Miltenburg, 1972 | Stable; DH |
20.33 | 225.35 | crystaline, II | crystaline, I | Chang and Westrum, 1970 | DH |
10.04 | 250.3 | crystaline, I | liquid | Chang and Westrum, 1970 | DH |
20.33 | 225.35 | crystaline, II | crystaline, I | Hicks, Hooley, et al., 1944 | DH |
10.05 | 250.3 | crystaline, I | liquid | Hicks, Hooley, et al., 1944 | DH |
20.5 | 224.6 | crystaline, II | crystaline, I | Latimer, 1922 | DH |
10.8 | 249. | crystaline, I | liquid | Latimer, 1922 | DH |
26.40 | 225.63 | crystaline, II | crystaline, I | Stull, 1937 | DH |
9.71 | 250.37 | crystaline, I | liquid | Stull, 1937 | DH |
Reaction thermochemistry data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.
Individual Reactions
By formula: Cl- + CCl4 = (Cl- • CCl4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.1 ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
ΔrH° | 59.4 ± 2.9 | kJ/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 116. | J/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 21.1 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
ΔrG° | 24.7 ± 3.8 | kJ/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B |
C8H6MoO3 (solution) + (solution) =
(solution) +
(solution)
By formula: C8H6MoO3 (solution) + CCl4 (solution) = C8H5ClMoO3 (solution) + CHCl3 (solution)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -133.1 ± 3.8 | kJ/mol | RSC | Nolan, López de la Vega, et al., 1986 | solvent: Tetrahydrofuran; The enthalpy of solution of Mo(Cp)(CO)3(H)(cr) was measured as 8.8 ± 0.4 kJ/mol Nolan, López de la Vega, et al., 1986, 2. Reaction temperature: 323 K; MS |
By formula: CO2 + CCl4 = 2CCl2O
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 70. ± 2. | kJ/mol | Eqk | Lord and Pritchard, 1969 | gas phase; Two values for Hf; ALS |
ΔrH° | 70. ± 2. | kJ/mol | Eqk | Lord and Pritchard, 1969 | gas phase; Two values for Hf; ALS |
By formula: CCl5- + 2CCl4 = C2Cl9-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 38.9 | kJ/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 12.7 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
By formula: CHCl3 + Cl2 = CCl4 + HCl
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -93.30 | kJ/mol | Cm | Kirkbride, 1956 | liquid phase; Heat of chlorination; ALS |
By formula: CCl4 + Br2 = BrCl + CBrCl3
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 37. ± 1. | kJ/mol | Eqk | Mendenhall, Golden, et al., 1973 | gas phase; ALS |
C10H12Mo (cr) + 2 (l) = C10H10Cl2Mo (cr) + 2
(l)
By formula: C10H12Mo (cr) + 2CCl4 (l) = C10H10Cl2Mo (cr) + 2CHCl3 (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -321.3 ± 4.4 | kJ/mol | RSC | Calado, Dias, et al., 1979 | MS |
C10H12W (cr) + 2 (l) = C10H10Cl2W (cr) + 2
(l)
By formula: C10H12W (cr) + 2CCl4 (l) = C10H10Cl2W (cr) + 2CHCl3 (l)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -301.1 ± 3.4 | kJ/mol | RSC | Calado, Dias, et al., 1979 | MS |
By formula: 2CCl2O = CO2 + CCl4
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | -70. ± 2. | kJ/mol | Eqk | Lord and Pritchard, 1969 | gas phase; ALS |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 11.47 ± 0.01 | eV | N/A | N/A | L |
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.80 ± 0.34 | IMRB | Staneke, Groothuis, et al., 1995 | EA > EA(CH2S-.), and Cl-A(CCl3.) < Cl-A(CCl4); B |
2.00 ± 0.20 | NBIE | Lacmann, Maneira, et al., 1983 | B |
2.00 ± 0.20 | NBIE | Dispert and Lacmann, 1978 | B |
2.12 ± 0.10 | SI | Gaines, Kay, et al., 1966 | The Magnetron method, lacking mass analysis, is not considered reliable.; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
11.5 ± 0.1 | EI | Kime, Driscoll, et al., 1987 | LBLHLM |
11.3 | PE | Von Niessen, Asbrink, et al., 1982 | LBLHLM |
11.47 ± 0.08 | PE | Bassett and Lloyd, 1971 | LLK |
11.47 | PE | Dewar and Worley, 1969 | RDSH |
11.47 ± 0.01 | PI | Watanabe, 1957 | RDSH |
11.0 ± 1.0 | EI | Baker and Tate, 1938 | RDSH |
11.69 | PE | Kimura, Katsumata, et al., 1981 | Vertical value; LLK |
11.69 | PE | Dixon, Murrell, et al., 1971 | Vertical value; LLK |
Appearance energy determinations
Ion clustering data
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: CCl5- + 2CCl4 = C2Cl9-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 38.9 | kJ/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 12.7 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
By formula: Cl- + CCl4 = (Cl- • CCl4)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 56.1 ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
ΔrH° | 59.4 ± 2.9 | kJ/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrS° | 116. | J/mol*K | HPMS | Dougherty, Dalton, et al., 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 21.1 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
ΔrG° | 24.7 ± 3.8 | kJ/mol | TDAs | Dougherty, Dalton, et al., 1974 | gas phase; B |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Manion, 2002
Manion, J.A.,
Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons,
J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703
. [all data]
Hu and Sinke, 1969
Hu, A.T.; Sinke, G.C.,
Combustion calorimetry of some chlorinated organic compounds,
J. Chem. Thermodyn., 1969, 1, 6, 507, https://doi.org/10.1016/0021-9614(69)90010-X
. [all data]
Hu and Sinke, 1969, 2
Hu, A.T.; Sinke, G.C.,
Combustion calorimetry of some chlorinated organic compounds,
J. Chem. Thermodyn., 1969, 1, 507-513. [all data]
Smith, Bjellerup, et al., 1953
Smith, L.; Bjellerup, L.; Krook, S.; Westermark, H.,
Heats of combustion of organic chloro compounds determined by the "quartz wool" method,
Acta Chem. Scand., 1953, 7, 65. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]
Hicks, Hooley, et al., 1944
Hicks, J.F.G.; Hooley, J.G.; Stephenson, C.C.,
The heat capacity of carbon tetrachloride from 15 to 300K. The heats of transition and of fusion. The entropy from thermal measurments compared with the entropy from molecular data,
J. Am. Chem. Soc., 1944, 66, 1064-1067. [all data]
Latimer, 1922
Latimer, W.M.,
The distribution of thermal energy in the tetrachlorides of carbon, silicon, titantium and tin,
J. Am. Chem. Soc., 1922, 44, 90-97. [all data]
Stull, 1937
Stull, D.R.,
A semi-micro calorimeter for measuring heat capacities at low temperatures,
J. Am. Chem. Soc., 1937, 59, 2726-2733. [all data]
Shehatta, 1993
Shehatta, I.,
Heat capacity at constant pressure of some halogen compounds,
Thermochim. Acta, 1993, 213, 1-10. [all data]
Lainez, Rodrigo, et al., 1989
Lainez, A.; Rodrigo, M.M.; Wilhelm, E.; Grolier, J.-P.E.,
Excess volumes and excess heaat capacitiies of some mixtures with trans,trans,cis-1,5,9-cyclododecatriene at 298.15K,
J. Chem. Eng. Data, 1989, 34, 332-335. [all data]
Petrov, Peshekhodov, et al., 1989
Petrov, A.N.; Peshekhodov, P.B.; Al'per, G.A.,
Heat capacity of non-aqueous solutions of non-electrolyts with N,N-dimethylformamide as a base, Sbornik Nauch. Trud., Termodin. Rast. neelect., Ivanovo,
Inst. nevod. rast., 1989, Akad. [all data]
Nkinamubanzi, Charlet, et al., 1985
Nkinamubanzi, P.; Charlet, G.; Delmas, G.,
Excess enthalpies, excess heat capacities and excess volumes of tetraalkoxysilanes with cyclohexane and carbon tetrachloride,
Fluid Phase Equilibria, 1985, 20, 57-73. [all data]
Tanaka, 1982
Tanaka, R.,
Determination of excess heat capacities of (benzene + tetrachloromethane and + cyclohexane) between 293.15 and 303.15 K by use of a Picker flow calorimeter,
J. Chem. Thermodynam., 1982, 14, 259-268. [all data]
Atalla, El-Sharkawy, et al., 1981
Atalla, S.R.; El-Sharkawy, A.A.; Gasser, F.A.,
Measurement of thermal properties of liquids with an AC heated-wire technique,
Inter. J. Thermophys., 1981, 2(2), 155-162. [all data]
Grolier, Hamedi, et al., 1979
Grolier, J-P.E.; Hamedi, M.H.; Wilhelm, E.; Kehiaian, H.V.,
Excess heat capacities of binary mixtures of carbon tetrachloride with n-alkanes at 298.15 K,
Thermochim. Acta, 1979, 31, 79-84. [all data]
Vesely, Zabransky, et al., 1979
Vesely, F.; Zabransky, M.; Svoboda, V.; Pick, J.,
The use of mixing calorimeter for measuring heat capacities of liquids,
Coll. Czech. Chem. Commun., 1979, 44, 3529-3532. [all data]
Wilhelm, Faradjzadeh, et al., 1979
Wilhelm, E.; Faradjzadeh, A.; Grolier, J.-P.E.,
Molar excess heat capacities and excess volumes of 1,2-dichloroethane + cyclooctane, + mesitylene, and + tetrachloromethane,
J. Chem. Thermodynam., 1979, 11, 979-984. [all data]
Grolier, Wilhelm, et al., 1978
Grolier, J.-P.E.; Wilhelm, E.; Hamedi, M.H.,
Molar heat capacities and isothermal compressibility of binary liquid mixtures: carbon tetrachloride + benzene, carbon tetrachloride + cyclohexane and benzene + cyclohexane,
Ber. Bunsenges. Phys. Chem., 1978, 82, 1282-1290. [all data]
Vesely, Svoboda, et al., 1977
Vesely, F.; Svoboda, V.; Pick, J.,
Heat capacities of some organic liquids determined with the mixing calorimeter,
1st Czech. Conf. Calorimetry (Lect. Short Commun.), 1977, C9-1-C9-4. [all data]
Fortier, Benson, et al., 1976
Fortier, J.-L.; Benson, G.C.; Picker, P.,
Heat capacities of some organic liquids determined with the Picker flow calorimeter,
J. Chem. Thermodynam., 1976, 8, 289-299. [all data]
Fortier and Benson, 1976
Fortier, J.-L.; Benson, G.C.,
Excess heat capacities of binary liquid mixtures determined with a Picker flow calorimeter,
J. Chem. Thermodynam., 1976, 8, 411-423. [all data]
Grolier, Benson, et al., 1975
Grolier, J-P.E.; Benson, G.C.; Picker, P.,
Simultaneous measurements of heat capacities and densities of organic liquid mixtures-systems containing ketones,
J. Chem. Eng. Data, 1975, 20, 243-246. [all data]
Wilhelm, Zettler, et al., 1974
Wilhelm, E.; Zettler, M.; Sackmann, H.,
Molar heat capacities for the binary systems cyclohexane, carbon tetrachloride,
silicon tetrachloride and tin tetrachloride Ber. Bunsenges. Phys. Chem., 1974, 78, 795-804. [all data]
Subrahmanyam and Rajagopal, 1973
Subrahmanyam, S.V.; Rajagopal, E.,
Excess thermodynamic functions of the systems isooctane + carbon tetrachloride and isooctane + cyclohexane,
Z. Phys. Chem. [NF], 1973, 85, 256-268. [all data]
Arentsen and Van Miltenburg, 1972
Arentsen, J.G.; Van Miltenburg, J.C.,
Carbon tetrachloride. Determination of the enthalpy of transition from metastable face-centered cubic carbon tetrachloride to the stable rhombohedral modification,
J. Chem. Thermodynam., 1972, 4, 789-791. [all data]
Deshpande and Bhatagadde, 1971
Deshpande, D.D.; Bhatagadde, L.G.,
Heat capacities at constant volume, free volumes, and rotational freedom in some liquids,
Aust. J. Chem., 1971, 24, 1817-1822. [all data]
Rastorguev and Ganiev, 1967
Rastorguev, Yu.L.; Ganiev, Yu.A.,
Study of the heat capacity of selected solvents,
Izv. Vyssh. Uchebn. Zaved. Neft Gaz. 10, 1967, No.1, 79-82. [all data]
Harrison and Moelwyn-Hughes, 1957
Harrison, D.; Moelwyn-Hughes, E.A.,
The heat capacities of certain liquids,
Proc. Roy. Soc. (London), 1957, A239, 230-246. [all data]
Staveley, Tupman, et al., 1955
Staveley, L.A.K.; Tupman, W.I.; Hart, K.R.,
Some thermodynamice properties of the systems benzene + ethylene dichloride, benzene + carbon tetrachloride, acetone + chloroform, and acetone + carbon disulphide,
Trans. Faraday Soc., 1955, 51, 323-342. [all data]
Kurbatov, 1948
Kurbatov, V.Ya.,
Heat capacity of liquids. 2. Heat capacity and the temperature dependence of heat capacity from halogen derivatives of acylic hydrocarbons,
Zh. Obshch. Kim., 1948, 18, 372-389. [all data]
Zhdanov, 1941
Zhdanov, A.K.,
Specific heats of some liquids and azeotropic mixtures,
Zhur. Obshch. Khim., 1941, 11, 471-482. [all data]
Phillip, 1939
Phillip, N.M.,
Adiabatic and isothermal compressibilities of liquids,
Proc. Indian Acad. Sci., 1939, A9, 109-120. [all data]
Vold, 1937
Vold, R.D.,
A calorimetric test of the solubility equation for regular solutions,
J. Am. Chem. Soc., 1937, 59, 1515-1521. [all data]
Kolosovskii and Udovenko, 1934
Kolosovskii, N.A.; Udovenko, W.W.,
Specific heat of liquids. II.,
Zhur. Obshchei Khim., 1934, 4, 1027-1033. [all data]
de Kolossowsky and Udowenko, 1933
de Kolossowsky, N.A.; Udowenko, W.W.,
Mesure des chaleurs specifique moleculaires de quelques liquides,
Compt. rend., 1933, 197, 519-520. [all data]
Richards and Wallace, 1932
Richards, W.T.; Wallace, J.H., Jr.,
The specific heats of five organic liquids from their adiabatic temperature-pressure coefficients,
J. Am. Chem. Soc., 1932, 54, 2705-2713. [all data]
Williams and Daniels, 1925
Williams, J.W.; Daniels, F.,
The specific heats of binary mixtures,
J. Am. Chem. Soc., 1925, 47, 1490-1503. [all data]
Willams and Daniels, 1924
Willams, J.W.; Daniels, F.,
The specific heats of certain organic liquids at elevated temperatures,
J. Am. Chem. Soc., 1924, 46, 903-917. [all data]
Atake and Chihara, 1971
Atake, T.; Chihara, H.,
Heat capacity of solid carbon tetrachloride from 3 to 50 K,
J. Chem. Thermodynam., 1971, 3, 51-60. [all data]
Altunin, Geller, et al., 1987
Altunin, V.V.; Geller, V.Z.; Kremenvskaya, E.A.; Perel'shtein, I.I.; Petrov, E.K.,
Thermophysical Properties of Freons, Methane Ser. Part 2, Vol. 9, NSRDS-USSR, Selover, T. B., Ed., Hemisphere, New York, 1987. [all data]
Majer and Svoboda, 1985
Majer, V.; Svoboda, V.,
Enthalpies of Vaporization of Organic Compounds: A Critical Review and Data Compilation, Blackwell Scientific Publications, Oxford, 1985, 300. [all data]
Campbell and Chatterjee, 1969
Campbell, A.N.; Chatterjee, R.M.,
The critical constants and orthobaric densities of acetone, chloroform benzene, and carbon tetrachloride,
Can. J. Chem., 1969, 47, 3893-8. [all data]
Livingston, Morgan, et al., 1908
Livingston, J.; Morgan, R.; Higgins, E.,
The Weight of Falling Drops and Tate's Laws. Determination of Molecular Weights and Critical Temp. of Liquids Using Drop Weights: II.,
Z. Phys. Chem., Stoechiom. Verwandtschaftsl., 1908, 64, 170. [all data]
Kordes, 1954
Kordes, E.,
The heterogeneous vapor-liquid equilibrium. II. Calculation of the density of liquids and vapors as well as the necessary degrees of filling of the autoclave in the work with liquids at high temp,
Z. Elektrochem., 1954, 58, 76-80. [all data]
Lewis, 1953
Lewis, D.T.,
The Determination of the Critical Constants of Liquid Explosives,
J. Appl. Chem., 1953, 3, 154. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Boublík and Aim, 1972
Boublík, T.; Aim, K.,
Heats of vaporization of simple non-spherical molecule compounds,
Collect. Czech. Chem. Commun., 1972, 37, 11, 3513-3521, https://doi.org/10.1135/cccc19723513
. [all data]
Hildenbrand and McDonald, 1959
Hildenbrand, D.L.; McDonald, R.A.,
The Heat of Vaporization and Vapor Pressure of Carbon Tetrachloride; The Entropy from Calorimetric Data.,
J. Phys. Chem., 1959, 63, 9, 1521-1522, https://doi.org/10.1021/j150579a053
. [all data]
Barker, Brown, et al., 1953
Barker, J.A.; Brown, I.; Smith, F.,
Thermodynamic properties of alcohol solutions. The system ethanol + carbon tetrachloride,
Discuss. Faraday Soc., 1953, 15, 142, https://doi.org/10.1039/df9531500142
. [all data]
Hildenbrand and McDonald, 1959, 2
Hildenbrand, D.L.; McDonald, R.A.,
The Heat of Vaporization and Vapor Pressure of Carbon Tetrachloride; the Entropy from Calorimetric Data,
J. Phys. Chem., 1959, 63, 9, 1521-1523, https://doi.org/10.1021/j150579a053
. [all data]
Goto, Fujinawa, et al., 1996
Goto, Hirotoshi; Fujinawa, Tasuku; Asahi, Hidemasa; Inabe, Tamotsu; Ogata, Hironori; Miyajima, Seiichi; Maruyama, Yusei,
Crystal Structures and Physical Properties of 1,6-Diaminopyrene-p-chloranil (DAP-CHL) Charge-Transfer Complex. Two Polymorphs and Their Unusual Electrical Properties.,
Bull. Chem. Soc. Jpn., 1996, 69, 1, 85-93, https://doi.org/10.1246/bcsj.69.85
. [all data]
Bondi, 1963
Bondi, A.,
Heat of Siblimation of Molecular Crystals: A Catalog of Molecular Structure Increments.,
J. Chem. Eng. Data, 1963, 8, 3, 371-381, https://doi.org/10.1021/je60018a027
. [all data]
Jones, 1960
Jones, A.H.,
Sublimation Pressure Data for Organic Compounds.,
J. Chem. Eng. Data, 1960, 5, 2, 196-200, https://doi.org/10.1021/je60006a019
. [all data]
Domalski and Hearing, 1996
Domalski, Eugene S.; Hearing, Elizabeth D.,
Heat Capacities and Entropies of Organic Compounds in the Condensed Phase. Volume III,
J. Phys. Chem. Ref. Data, 1996, 25, 1, 1, https://doi.org/10.1063/1.555985
. [all data]
Morrison and Richards, 1976
Morrison, J.A.; Richards, E.J.,
Thermodynamic study of phase transitions in carbon tetrachloride,
J. Chem. Thermodynam., 1976, 8, 1033-1038. [all data]
Chang and Westrum, 1970
Chang, E.T.; Westrum,
E.F., Heat capacities and thermodynamic properties of globular molecules. XV. The binary system tetramethylmethane-tetrachloromethane,
J. Phys. Chem., 1970, 74, 2528-2538. [all data]
Hiraoka, Mizuno, et al., 2001
Hiraoka, K.; Mizuno, T.; Iino, T.; Eguchi, D.; Yamabe, S.,
Characteristic changes of bond energies for gas-phase cluster ions of halide ions with methane and chloromethanes,
J. Phys. Chem. A, 2001, 105, 20, 4887-4893, https://doi.org/10.1021/jp010143n
. [all data]
Dougherty, Dalton, et al., 1974
Dougherty, R.C.; Dalton, J.; Roberts, J.D.,
SN2 reactions in the gas phase: Structure of the transition state,
Org. Mass Spectrom., 1974, 8, 77. [all data]
Nolan, López de la Vega, et al., 1986
Nolan, S.P.; López de la Vega, R.; Hoff, C.D.,
J. Organometal. Chem., 1986, 315, 187. [all data]
Nolan, López de la Vega, et al., 1986, 2
Nolan, S.P.; López de la Vega, R.; Hoff, C.D.,
Organometallics, 1986, 5, 2529. [all data]
Lord and Pritchard, 1969
Lord, A.; Pritchard, H.O.,
Thermodynamics of the reaction between carbon dioxide and carbon tetrachloride,
J. Chem. Thermodyn., 1969, 1, 495-498. [all data]
Kirkbride, 1956
Kirkbride, F.W.,
The heats of chlorination of some hydrocarbons and their chloro-derivatives,
J. Appl. Chem., 1956, 6, 11-21. [all data]
Mendenhall, Golden, et al., 1973
Mendenhall, G.D.; Golden, D.M.; Benson, S.W.,
Thermochemistry of the bromination of carbon tetrachloride and the heat of formation of carbon tetrachloride,
J. Phys. Chem., 1973, 77, 2707-2709. [all data]
Calado, Dias, et al., 1979
Calado, J.C.G.; Dias, A.R.; Martinho Simões, J.A.; Ribeiro da Silva, M.A.V.,
J. Organometal. Chem., 1979, 174, 77. [all data]
Staneke, Groothuis, et al., 1995
Staneke, P.O.; Groothuis, G.; Ingemann, S.; Nibbering, N.M.M.,
Formation, stability and structure of radical anions of chloroform, tetrachloromethane and fluorotrichloromethane in the gas phase,
Int. J. Mass Spectrom. Ion Proc., 1995, 142, 1-2, 83, https://doi.org/10.1016/0168-1176(94)04127-S
. [all data]
Lacmann, Maneira, et al., 1983
Lacmann, K.; Maneira, M.J.P.; Moutinho, A.M.C.; Weigman, U.,
Total and Double Differential Cross Sections of Ion- Pair Formations in Collisions of K Atoms with SnCl4 and CCl4,
J. Chem. Phys., 1983, 78, 1767. [all data]
Dispert and Lacmann, 1978
Dispert, H.; Lacmann, K.,
Negative ion formation in collisions between potassium and fluoro- and chloromethanes: Electron affinities and bond dissociation energies,
Int. J. Mass Spectrom. Ion Phys., 1978, 28, 49. [all data]
Gaines, Kay, et al., 1966
Gaines, A.F.; Kay, J.; Page, F.M.,
Determination of Electron Affinities. Part 8. - CCl4, CHCl3, and CH2Cl2,
Trans. Farad. Soc., 1966, 62, 874, https://doi.org/10.1039/tf9666200874
. [all data]
Kime, Driscoll, et al., 1987
Kime, Y.J.; Driscoll, D.C.; Dowben, P.A.,
The stability of the carbon tetrahalide ions,
J. Chem. Soc. Faraday Trans. 2, 1987, 83, 403. [all data]
Von Niessen, Asbrink, et al., 1982
Von Niessen, W.; Asbrink, L.; Bieri, G.,
30.4 nm He(II) Photoelectron spectra of organic molecules. Part VI. Halogeno-compounds (C,H,X: X = Cl, Br, I),
J. Electron Spectrosc. Relat. Phenom., 1982, 26, 173. [all data]
Bassett and Lloyd, 1971
Bassett, P.J.; Lloyd, D.R.,
Photoelectron spectra of halides. Part I. Tetrafluorides and tetrachlorides of group IVB,
J. Chem. Soc., 1971, (A), 641. [all data]
Dewar and Worley, 1969
Dewar, M.J.S.; Worley, S.D.,
Photoelectron spectra of molecules. I. Ionization potentials of some organic molecules and their interpretation,
J. Chem. Phys., 1969, 50, 654. [all data]
Watanabe, 1957
Watanabe, K.,
Ionization potentials of some molecules,
J. Chem. Phys., 1957, 26, 542. [all data]
Baker and Tate, 1938
Baker, R.F.; Tate, J.T.,
Ionization and dissociation by electron impact in CCl2F2 and in CCl4 vapor,
Phys. Rev., 1938, 53, 683. [all data]
Kimura, Katsumata, et al., 1981
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S.,
Ionization energies, Ab initio assignments, and valence electronic structure for 200 molecules
in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Press, Tokyo, 1981. [all data]
Dixon, Murrell, et al., 1971
Dixon, R.N.; Murrell, J.N.; Narayan, B.,
The photoelectron spectra of the halomethanes,
Mol. Phys., 1971, 20, 611. [all data]
Burton, Chan, et al., 1994
Burton, G.R.; Chan, W.F.; Cooper, G.; Brion, C.E.,
Valence- and inner-shell (Cl 2p, 2s; C1s) photoabsorption and photoionization of carbon tetrachloride. Absolute oscillator strengths (5-400 eV) and dipole-induced breakdown pathways,
Chem. Phys., 1994, 181, 147. [all data]
Reed and Snedden, 1958
Reed, R.I.; Snedden, W.,
Studies in electron impact methods. Part 2. The latent heat of sublimation of carbon,
J. Chem. Soc. Faraday Trans., 1958, 54, 301. [all data]
Blanchard and LeGoff, 1957
Blanchard, L.P.; LeGoff, P.,
Mass spectrometric study of the species CS, SO, and CCl2 produced in primary heterogeneous reactions,
Can. J. Chem., 1957, 35, 89. [all data]
Shapiro and Lossing, 1968
Shapiro, J.S.; Lossing, F.P.,
Free radicals by mass spectrometry. XXXVII. The ionization potential and heat of formation of dichlorocarbene,
J. Phys. Chem., 1968, 72, 1552. [all data]
Werner, Tsai, et al., 1974
Werner, A.S.; Tsai, B.P.; Baer, T.,
Photoionization study of the ionization potentials fragmentation paths of the chlorinated methanes carbon tetrabromide,
J. Chem. Phys., 1974, 60, 3650. [all data]
Lossing, 1972
Lossing, F.P.,
Free radicals by mass spectrometry. XLIV. Ionization potentials bond dissociation energies for chloro-and fluoromethyl radicals,
Bull. Soc. Chim. Belg., 1972, 81, 125. [all data]
Fox and Curran, 1961
Fox, R.E.; Curran, R.K.,
Ionization processes in CCl4 and SF6 by electron beams,
J. Chem. Phys., 1961, 34, 1595. [all data]
Farmer, Henderson, et al., 1956
Farmer, J.B.; Henderson, I.H.S.; Lossing, F.P.; Marsden, D.G.H.,
Free radicals by mass spectrometry. IX. Ionization potentials of CF3 and CCl3 radicals and bond dissociation energies in some derivatives,
J. Chem. Phys., 1956, 24, 348. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References
- Symbols used in this document:
AE Appearance energy Cp,liquid Constant pressure heat capacity of liquid Cp,solid Constant pressure heat capacity of solid EA Electron affinity IE (evaluated) Recommended ionization energy Pc Critical pressure S°gas,1 bar Entropy of gas at standard conditions (1 bar) S°liquid Entropy of liquid at standard conditions Tboil Boiling point Tc Critical temperature Tfus Fusion (melting) point Ttriple Triple point temperature ΔHtrs Enthalpy of phase transition ΔStrs Entropy of phase transition ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔfusS Entropy of fusion ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions ΔrS° Entropy of reaction at standard conditions ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions ρc Critical density - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.