Chloromethane

• Formula: CH₃Cl
• Molecular weight: 50.488
• IUPAC Standard InChI: InChI=1S/CH3Cl/c1-2/h1H3 Copy

  
• IUPAC Standard InChIKey: NEHMKBQYUWJMIP-UHFFFAOYSA-N Copy
• CAS Registry Number: 74-87-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Methane, chloro-; Methyl chloride; Artic; Freon 40; Monochloromethane; CH3Cl; Chloor-methaan; Chlor-methan; Chlorure de methyle; Clorometano; Cloruro di metile; Methylchlorid; Metylu chlorek; R 40; Rcra waste number U045; UN 1063; Refrigerant R40
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Condensed phase thermochemistry data
  • Phase change data
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Henry's Law data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • Vibrational and/or electronic energy levels
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
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• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

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Condensed phase thermochemistry data

Go To: Top, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Phase change data

Go To: Top, Condensed phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Enthalpy of vaporization

Entropy of vaporization

Antoine Equation Parameters

log₁₀(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

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Enthalpy of sublimation

Enthalpy of fusion

Entropy of fusion

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 +  = ( • )

By formula: Cl^- + CH₃Cl = (Cl^- • CH₃Cl)

CH₂Cl^- +  =

By formula: CH₂Cl^- + H⁺ = CH₃Cl

(CH₂Cl⁺ • ) +  = (CH₂Cl⁺ • 2)

By formula: (CH₂Cl⁺ • CH₃Cl) + CH₃Cl = (CH₂Cl⁺ • 2CH₃Cl)

Free energy of reaction

(CH₄Cl⁺ • ) +  = (CH₄Cl⁺ • 2)

By formula: (CH₄Cl⁺ • CH₃Cl) + CH₃Cl = (CH₄Cl⁺ • 2CH₃Cl)

Free energy of reaction

CH₂Cl⁺ +  = (CH₂Cl⁺ • )

By formula: CH₂Cl⁺ + CH₃Cl = (CH₂Cl⁺ • CH₃Cl)

Free energy of reaction

C₃H₇⁺ +  = (C₃H₇⁺ • )

By formula: C₃H₇⁺ + CH₃Cl = (C₃H₇⁺ • CH₃Cl)

 +  = ( • )

By formula: CH₃⁺ + CH₃Cl = (CH₃⁺ • CH₃Cl)

 +  = ( • )

By formula: Br^- + CH₃Cl = (Br^- • CH₃Cl)

CN^- +  = (CN^- • )

By formula: CN^- + CH₃Cl = (CN^- • CH₃Cl)

CH₃Cl₂^- + 2 = C₂H₆Cl₃^-

By formula: CH₃Cl₂^- + 2CH₃Cl = C₂H₆Cl₃^-

C₂H₆Cl₃^- + 3 = C₃H₉Cl₄^-

By formula: C₂H₆Cl₃^- + 3CH₃Cl = C₃H₉Cl₄^-

C₃H₉Cl₄^- + 4 = C₄H₁₂Cl₅^-

By formula: C₃H₉Cl₄^- + 4CH₃Cl = C₄H₁₂Cl₅^-

C₄H₁₂Cl₅^- + 5 = C₅H₁₅Cl₆^-

By formula: C₄H₁₂Cl₅^- + 5CH₃Cl = C₅H₁₅Cl₆^-

C₅H₁₅Cl₆^- + 6 = C₆H₁₈Cl₇^-

By formula: C₅H₁₅Cl₆^- + 6CH₃Cl = C₆H₁₈Cl₇^-

C₆H₁₈Cl₇^- + 7 = C₇H₂₁Cl₈^-

By formula: C₆H₁₈Cl₇^- + 7CH₃Cl = C₇H₂₁Cl₈^-

C₇H₂₁Cl₈^- + 8 = C₈H₂₄Cl₉^-

By formula: C₇H₂₁Cl₈^- + 8CH₃Cl = C₈H₂₄Cl₉^-

C₂H₅⁺ +  = (C₂H₅⁺ • )

By formula: C₂H₅⁺ + CH₃Cl = (C₂H₅⁺ • CH₃Cl)

 +  = ( • )

By formula: Li⁺ + CH₃Cl = (Li⁺ • CH₃Cl)

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CH₃Cl = (C₄H₉⁺ • CH₃Cl)

CH₆N⁺ +  = (CH₆N⁺ • )

By formula: CH₆N⁺ + CH₃Cl = (CH₆N⁺ • CH₃Cl)

 +  =  + 

By formula: H₂ + CH₃Cl = CH₄ + HCl

Gas phase ion energetics data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to CH₃Cl⁺ (ion structure unspecified)

Ionization energy determinations

Appearance energy determinations

De-protonation reactions

CH₂Cl^- +  =

By formula: CH₂Cl^- + H⁺ = CH₃Cl

Ion clustering data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 +  = ( • )

By formula: Br^- + CH₃Cl = (Br^- • CH₃Cl)

CH₂Cl⁺ +  = (CH₂Cl⁺ • )

By formula: CH₂Cl⁺ + CH₃Cl = (CH₂Cl⁺ • CH₃Cl)

Free energy of reaction

(CH₂Cl⁺ • ) +  = (CH₂Cl⁺ • 2)

By formula: (CH₂Cl⁺ • CH₃Cl) + CH₃Cl = (CH₂Cl⁺ • 2CH₃Cl)

Free energy of reaction

 +  = ( • )

By formula: CH₃⁺ + CH₃Cl = (CH₃⁺ • CH₃Cl)

CH₃Cl₂^- + 2 = C₂H₆Cl₃^-

By formula: CH₃Cl₂^- + 2CH₃Cl = C₂H₆Cl₃^-

(CH₄Cl⁺ • ) +  = (CH₄Cl⁺ • 2)

By formula: (CH₄Cl⁺ • CH₃Cl) + CH₃Cl = (CH₄Cl⁺ • 2CH₃Cl)

Free energy of reaction

CH₆N⁺ +  = (CH₆N⁺ • )

By formula: CH₆N⁺ + CH₃Cl = (CH₆N⁺ • CH₃Cl)

CN^- +  = (CN^- • )

By formula: CN^- + CH₃Cl = (CN^- • CH₃Cl)

C₂H₅⁺ +  = (C₂H₅⁺ • )

By formula: C₂H₅⁺ + CH₃Cl = (C₂H₅⁺ • CH₃Cl)

C₂H₆Cl₃^- + 3 = C₃H₉Cl₄^-

By formula: C₂H₆Cl₃^- + 3CH₃Cl = C₃H₉Cl₄^-

C₃H₇⁺ +  = (C₃H₇⁺ • )

By formula: C₃H₇⁺ + CH₃Cl = (C₃H₇⁺ • CH₃Cl)

C₃H₉Cl₄^- + 4 = C₄H₁₂Cl₅^-

By formula: C₃H₉Cl₄^- + 4CH₃Cl = C₄H₁₂Cl₅^-

C₄H₉⁺ +  = (C₄H₉⁺ • )

By formula: C₄H₉⁺ + CH₃Cl = (C₄H₉⁺ • CH₃Cl)

C₄H₁₂Cl₅^- + 5 = C₅H₁₅Cl₆^-

By formula: C₄H₁₂Cl₅^- + 5CH₃Cl = C₅H₁₅Cl₆^-

C₅H₁₅Cl₆^- + 6 = C₆H₁₈Cl₇^-

By formula: C₅H₁₅Cl₆^- + 6CH₃Cl = C₆H₁₈Cl₇^-

C₆H₁₈Cl₇^- + 7 = C₇H₂₁Cl₈^-

By formula: C₆H₁₈Cl₇^- + 7CH₃Cl = C₇H₂₁Cl₈^-

C₇H₂₁Cl₈^- + 8 = C₈H₂₄Cl₉^-

By formula: C₇H₂₁Cl₈^- + 8CH₃Cl = C₈H₂₄Cl₉^-

 +  = ( • )

By formula: Cl^- + CH₃Cl = (Cl^- • CH₃Cl)

 +  = ( • )

By formula: Li⁺ + CH₃Cl = (Li⁺ • CH₃Cl)

References

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Manion, 2002
Manion, J.A., Evaluated Enthalpies of Formation of the Stable Closed Shell C1 and C2 Chlorinated Hydrocarbons, J. Phys. Chem. Ref. Data, 2002, 31, 1, 123-172, https://doi.org/10.1063/1.1420703 . [all data]

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Larson and McMahon, 1984, 2
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Utsunomiya, C.; Kobayashi, T.; Nagakura, S., Photoelectron angular distribution measurements for some aliphatic alcohols, amines, halides, Bull. Chem. Soc. Jpn., 1980, 53, 1216. [all data]

Uehara, Saito, et al., 1973
Uehara, Y.; Saito, N.; Yonezawa, T., Ionization potentials of trifluoromethyl and methyl halides by photoelectron spectroscopy and calculations by extended Hucket and CNDO/2 methods, Chem. Lett., 1973, 495. [all data]

Dixon, Murrell, et al., 1971
Dixon, R.N.; Murrell, J.N.; Narayan, B., The photoelectron spectra of the halomethanes, Mol. Phys., 1971, 20, 611. [all data]

Reed and Snedden, 1956
Reed, R.I.; Snedden, W., Studies in electron impact methods. Part 6.-The formation of the methine and carbon ions, J. Chem. Soc. Faraday Trans., 1956, 55, 876. [all data]

Tsuda and Hamill, 1964
Tsuda, S.; Hamill, W.H., Structure in ionization efficiency curves near threshold from alkanes and alkyl halides, J. Chem. Phys., 1964, 41, 2713. [all data]

Martin, Lampe, et al., 1966
Martin, R.H.; Lampe, F.W.; Taft, R.W., An electron-impact study of ionization and dissociation in methoxy- and halogen- substituted methanes, J. Am. Chem. Soc., 1966, 88, 1353. [all data]

Krauss, Walker, et al., 1968
Krauss, M.; Walker, J.A.; Dibeler, V.H., Mass spectrometric study of photoionization. X. Hydrogen chloride and methyl halides, J. Res. NBS, 1968, 72A, 281. [all data]

Tsuda, Melton, et al., 1964
Tsuda, S.; Melton, C.E.; Hamill, W.H., Ionization- efficiency curves for molecular and fragment ions from methane and the methyl halides, J. Chem. Phys., 1964, 41, 689. [all data]

Notes

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  AE	Appearance energy
  Cp,liquid	Constant pressure heat capacity of liquid
  IE (evaluated)	Recommended ionization energy
  Pc	Critical pressure
  Ptriple	Triple point pressure
  S°liquid	Entropy of liquid at standard conditions
  T	Temperature
  Tboil	Boiling point
  Tc	Critical temperature
  Tfus	Fusion (melting) point
  Ttriple	Triple point temperature
  ΔfH°liquid	Enthalpy of formation of liquid at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions
  ΔsubH	Enthalpy of sublimation
  ΔvapH	Enthalpy of vaporization
  ΔvapH°	Enthalpy of vaporization at standard conditions
  ΔvapS	Entropy of vaporization
  ρc	Critical density

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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