Nitrogen

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Reaction thermochemistry data

Go To: Top, Henry's Law data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
MS - José A. Martinho Simões
B - John E. Bartmess
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Reactions 1 to 50

Nitric oxide anion + Nitrogen = (Nitric oxide anion • Nitrogen)

By formula: NO- + N2 = (NO- • N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrH°20.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
ΔrH°18.kJ/molHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
ΔrH°22.kJ/molHPMSTurner and Conway, 1976gas phase; M
ΔrH°19.kJ/molDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrS°57.7J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
ΔrS°55.6J/mol*KHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
ΔrS°79.1J/mol*KHPMSTurner and Conway, 1976gas phase; M
ΔrS°65.7J/mol*KDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.200.FADunkin, Fehsenfeld, et al., 1971gas phase; M

Nitrogen cation + Nitrogen = (Nitrogen cation • Nitrogen)

By formula: N2+ + N2 = (N2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°102. to 102.kJ/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°87.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°67.8J/mol*KPHPMSTeng and Conway, 1973gas phase; M
ΔrS°81.6J/mol*KPHPMSPayzant and Kebarle, 1970gas phase; M
ΔrS°46.J/mol*KDTVarney, 1968gas phase; Entropy change is questionable; M
ΔrS°-4.J/mol*KDTVarney, 1959gas phase; Entropy change is questionable; M

Oxygen cation + Nitrogen = (Oxygen cation • Nitrogen)

By formula: O2+ + N2 = (O2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°21. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°22.kJ/molHPMSSpeller and Fitaire, 1983gas phase; M
ΔrH°24.kJ/molPHPMSJanik and Conway, 1967gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°72.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°66.1J/mol*KHPMSSpeller and Fitaire, 1983gas phase; M
ΔrS°79.1J/mol*KPHPMSJanik and Conway, 1967gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0296.FAHoward, Bierbaum, et al., 1972gas phase; M

(HN2+ • 4Nitrogen) + Nitrogen = (HN2+ • 5Nitrogen)

By formula: (HN2+ • 4N2) + N2 = (HN2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°13.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°95.8J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°84.J/mol*KN/AHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
5.992.PHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

(Oxygen anion • 7Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 8Nitrogen • Oxygen)

By formula: (O2- • 7N2 • O2) + N2 = (O2- • 8N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
ΔrH°6.40kJ/molPHPMSHiraoka, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka, 1988gas phase; M
ΔrS°75.3J/mol*KN/AHiraoka, 1988gas phase; Entropy change calculated or estimated; M

(Oxygen cation • 2Nitrogen) + Nitrogen = (Oxygen cation • 3Nitrogen)

By formula: (O2+ • 2N2) + N2 = (O2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°18. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°15.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°82.0J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°50.6J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation • Nitrogen) + Nitrogen = (Oxygen cation • 2Nitrogen)

By formula: (O2+ • N2) + N2 = (O2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°18.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°79.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°57.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Nitric oxide anion • Nitrogen) + Nitrogen = (Nitric oxide anion • 2Nitrogen)

By formula: (NO- • N2) + N2 = (NO- • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrH°16.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°72.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrS°52.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

C3N2NiO3 (solution) = C3NiO3 (solution) + Nitrogen (solution)

By formula: C3N2NiO3 (solution) = C3NiO3 (solution) + N2 (solution)

Quantity Value Units Method Reference Comment
ΔrH°42. ± 4.kJ/molKinSTurner, Simpson, et al., 1983solvent: Liquid krypton; The reaction enthalpy relies on the experimental value for the activation enthalpy, 42. ± 4. kJ/mol, and on the assumption that the activation enthalpy for product recombination is negligible Turner, Simpson, et al., 1983.; MS

N+ + Nitrogen = (N+ • Nitrogen)

By formula: N+ + N2 = (N+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°249.kJ/molN/ANational Bureau of Standards, 1968gas phase; from ΔrH(f); M
ΔrH°250.kJ/molEISaporoschenko, 1965gas phase; M
ΔrH°250.kJ/molEIFranklin, Dibeler, et al., 1958gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
361. (+7.5,-0.) CIDHaynes, Freysinger, et al., 1995gas phase; guided ion beam CID; M

Copper ion (1+) + Nitrogen = (Copper ion (1+) • Nitrogen)

By formula: Cu+ + N2 = (Cu+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°26.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
ΔrS°67.J/mol*KHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
ΔrG°5.9kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M

(HN2+ • 2Nitrogen) + Nitrogen = (HN2+ • 3Nitrogen)

By formula: (HN2+ • 2N2) + N2 = (HN2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°16.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 3Nitrogen) + Nitrogen = (HN2+ • 4Nitrogen)

By formula: (HN2+ • 3N2) + N2 = (HN2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°15.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°88.7J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • Nitrogen) + Nitrogen = (HN2+ • 2Nitrogen)

By formula: (HN2+ • N2) + N2 = (HN2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°17.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°80.3J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°75.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°33.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°77.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
9.2310.FAPerry, Rowe, et al., 1980gas phase; M
8.4310.DTBeyer and Keller, 1971gas phase; low E/N; M

HN2+ + Nitrogen = (HN2+ • Nitrogen)

By formula: HN2+ + N2 = (HN2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°66.9kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
ΔrH°60.7kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M
ΔrS°85.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M

C39H66N2O3P2W (solution) + Hydrogen (g) = C39H68O3P2W (solution) + Nitrogen (g)

By formula: C39H66N2O3P2W (solution) + H2 (g) = C39H68O3P2W (solution) + N2 (g)

Quantity Value Units Method Reference Comment
ΔrH°18.4 ± 1.7kJ/molEqSGonzalez and Hoff, 1989solvent: Tetrahydrofuran; Temperature range: 288-308 K; MS

C39H66MoO3P3 (solution) + Nitrogen (g) = C39H66MoN2O3P2 (solution)

By formula: C39H66MoO3P3 (solution) + N2 (g) = C39H66MoN2O3P2 (solution)

Quantity Value Units Method Reference Comment
ΔrH°-37.7 ± 2.5kJ/molEqSGonzalez and Hoff, 1989solvent: Tetrahydrofuran; Temperature range: 294-308 K; MS

(Hydronium cation • 2Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 3Water)

By formula: (H3O+ • 2N2 • 3H2O) + N2 = (H3O+ • 3N2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°5.0kJ/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
ΔrS°27.J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

(Oxygen cation • 4Nitrogen) + Nitrogen = (Oxygen cation • 5Nitrogen)

By formula: (O2+ • 4N2) + N2 = (O2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°67.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.184.HPMSSpeller and Fitaire, 1983gas phase; M

(Nitric oxide anion • 2Nitrogen) + Nitrogen = (Nitric oxide anion • 3Nitrogen)

By formula: (NO- • 2N2) + N2 = (NO- • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°70.3J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
4.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 3Nitrogen) + Nitrogen = (Nitric oxide anion • 4Nitrogen)

By formula: (NO- • 3N2) + N2 = (NO- • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Oxygen cation • 3Nitrogen) + Nitrogen = (Oxygen cation • 4Nitrogen)

By formula: (O2+ • 3N2) + N2 = (O2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°17. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°94.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.204.HPMSSpeller and Fitaire, 1983gas phase; M

(Hydronium cation • 3Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 4Nitrogen • 2Water)

By formula: (H3O+ • 3N2 • 2H2O) + N2 = (H3O+ • 4N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°10.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
ΔrS°50.J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

(Nitric oxide anion • 9Nitrogen) + Nitrogen = (Nitric oxide anion • 10Nitrogen)

By formula: (NO- • 9N2) + N2 = (NO- • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°7.03kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°79.J/mol*KN/AHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M

(HN2+ • 10Nitrogen) + Nitrogen = (HN2+ • 11Nitrogen)

By formula: (HN2+ • 10N2) + N2 = (HN2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°7.20kJ/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
ΔrH°11.3 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°77.0J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-11.7 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

(C2H5+ • Nitrogen) + Nitrogen = (C2H5+ • 2Nitrogen)

By formula: (C2H5+ • N2) + N2 = (C2H5+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°19.kJ/molHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°45.6J/mol*KHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M

(Nitrogen cation • Nitrogen) + Nitrogen = (Nitrogen cation • 2Nitrogen)

By formula: (N2+ • N2) + N2 = (N2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°11.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°5.9kJ/molPILinn, Ono, et al., 1981gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°62.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • Oxygen) + Nitrogen = (Oxygen cation • Nitrogen • Oxygen)

By formula: (O2+ • O2) + N2 = (O2+ • N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°12.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°42.3J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°70.3J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-1.310.FAPerry, Rowe, et al., 1980gas phase; M

(CH2N+ • 2Nitrogen) + Nitrogen = (CH2N+ • 3Nitrogen)

By formula: (CH2N+ • 2N2) + N2 = (CH2N+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°54.8J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 3Nitrogen) + Nitrogen = (CH2N+ • 4Nitrogen)

By formula: (CH2N+ • 3N2) + N2 = (CH2N+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°57.7J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 4Nitrogen) + Nitrogen = (CH2N+ • 5Nitrogen)

By formula: (CH2N+ • 4N2) + N2 = (CH2N+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°63.6J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

2,5-Pyrrolidinedione, 1-bromo- + 0.5Hydrazine = Hydrogen bromide + Succinimide + 0.5Nitrogen

By formula: C4H4BrNO2 + 0.5H4N2 = HBr + C4H5NO2 + 0.5N2

Quantity Value Units Method Reference Comment
ΔrH°-260.3 ± 0.46kJ/molCmHoward and Skinner, 1966solid phase; solvent: Aqueous solution; Reanalyzed by Pedley, Naylor, et al., 1986, Original value = -261.7 ± 0.46 kJ/mol; ALS

Oxygen anion + Nitrogen = (Oxygen anion • Nitrogen)

By formula: O2- + N2 = (O2- • N2)

Quantity Value Units Method Reference Comment
ΔrH°25. ± 4.2kJ/molN/APosey and Johnson, 1988gas phase; B
ΔrH°<56.90kJ/molIMRBAdams and Bohme, 1970gas phase; N2..O2- + O2 -> O4-; B

C12H34P4Ru (solution) + Nitrogen (solution) = C12H32N2P4Ru (solution) + Hydrogen (solution)

By formula: C12H34P4Ru (solution) + N2 (solution) = C12H32N2P4Ru (solution) + H2 (solution)

Quantity Value Units Method Reference Comment
ΔrH°16.3kJ/molPACBelt, Scaiano, et al., 1993solvent: Cyclohexane; The reaction enthalpy relies on 0.85 for the quantum yield of H2 dissociation.; MS

(Hydronium cation • 2Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 2Water)

By formula: (H3O+ • 2N2 • 2H2O) + N2 = (H3O+ • 3N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°38. ± 11.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°119.J/mol*KDTGheno and Fitaire, 1987gas phase; M

Vanadium, tetracarbonyl(η5-2,4-cyclopentadien-1-yl)- (solution) + Nitrogen (solution) = C8H5N2O3V (solution) + Carbon monoxide (solution)

By formula: C9H5O4V (solution) + N2 (solution) = C8H5N2O3V (solution) + CO (solution)

Quantity Value Units Method Reference Comment
ΔrH°27. ± 4.kJ/molPACJohnson, Popov, et al., 1991solvent: Heptane; The reaction enthalpy relies on 0.80 for the quantum yield of CO dissociation.; MS

(Oxygen anion • 2Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 3Nitrogen • Oxygen)

By formula: (O2- • 2N2 • O2) + N2 = (O2- • 3N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°10.3 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°76.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 3Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 4Nitrogen • Oxygen)

By formula: (O2- • 3N2 • O2) + N2 = (O2- • 4N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°9.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 4Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 5Nitrogen • Oxygen)

By formula: (O2- • 4N2 • O2) + N2 = (O2- • 5N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°8.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 5Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 6Nitrogen • Oxygen)

By formula: (O2- • 5N2 • O2) + N2 = (O2- • 6N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 6Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 7Nitrogen • Oxygen)

By formula: (O2- • 6N2 • O2) + N2 = (O2- • 7N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°7.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°78.7J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 2Nitrogen • Oxygen)

By formula: (O2- • N2 • O2) + N2 = (O2- • 2N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°11.7 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka, 1988gas phase; M

(Hydronium cation • 2Nitrogen • Water) + Nitrogen = (Hydronium cation • 3Nitrogen • Water)

By formula: (H3O+ • 2N2 • H2O) + N2 = (H3O+ • 3N2 • H2O)

Quantity Value Units Method Reference Comment
ΔrH°33. ± 8.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 2Water)

By formula: (H3O+ • N2 • 2H2O) + N2 = (H3O+ • 2N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°69.5J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 3Water)

By formula: (H3O+ • N2 • 3H2O) + N2 = (H3O+ • 2N2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°18.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°65.7J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Oxygen cation • 10Nitrogen) + Nitrogen = (Oxygen cation • 11Nitrogen)

By formula: (O2+ • 10N2) + N2 = (O2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 10Nitrogen) + Nitrogen = (Nitrogen cation • 11Nitrogen)

By formula: (N2+ • 10N2) + N2 = (N2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°6.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Henry's Law data

Go To: Top, Reaction thermochemistry data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

k°H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference
0.000601300.XN/A
0.000651300.LN/A

Ion clustering data

Go To: Top, Reaction thermochemistry data, Henry's Law data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar
B - John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Ar+ + Nitrogen = (Ar+ • Nitrogen)

By formula: Ar+ + N2 = (Ar+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°164.kJ/molFAShul, Passarella, et al., 1987gas phase; switching reaction(Ar+)Ar, ΔrH>; Dehmer and Pratt, 1982; M

Trifluoromethyl cation + Nitrogen = (Trifluoromethyl cation • Nitrogen)

By formula: CF3+ + N2 = (CF3+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°29.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • Nitrogen) + Nitrogen = (Trifluoromethyl cation • 2Nitrogen)

By formula: (CF3+ • N2) + N2 = (CF3+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 2Nitrogen) + Nitrogen = (Trifluoromethyl cation • 3Nitrogen)

By formula: (CF3+ • 2N2) + N2 = (CF3+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°8.4kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°54.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 3Nitrogen) + Nitrogen = (Trifluoromethyl cation • 4Nitrogen)

By formula: (CF3+ • 3N2) + N2 = (CF3+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°7.5kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

(Trifluoromethyl cation • 4Nitrogen) + Nitrogen = (Trifluoromethyl cation • 5Nitrogen)

By formula: (CF3+ • 4N2) + N2 = (CF3+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°6.3kJ/molPHPMSHiraoka, Nasu, et al., 1996gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°50.J/mol*KPHPMSHiraoka, Nasu, et al., 1996gas phase; M

CH2N+ + Nitrogen = (CH2N+ • Nitrogen)

By formula: CH2N+ + N2 = (CH2N+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°32.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°92.9J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; M

(CH2N+ • Nitrogen) + Nitrogen = (CH2N+ • 2Nitrogen)

By formula: (CH2N+ • N2) + N2 = (CH2N+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°83.3J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; M

(CH2N+ • 2Nitrogen) + Nitrogen = (CH2N+ • 3Nitrogen)

By formula: (CH2N+ • 2N2) + N2 = (CH2N+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°54.8J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 3Nitrogen) + Nitrogen = (CH2N+ • 4Nitrogen)

By formula: (CH2N+ • 3N2) + N2 = (CH2N+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°57.7J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

(CH2N+ • 4Nitrogen) + Nitrogen = (CH2N+ • 5Nitrogen)

By formula: (CH2N+ • 4N2) + N2 = (CH2N+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°13.kJ/molHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°63.6J/mol*KHPMSSpeller, Fitaire, et al., 1982gas phase; Entropy change is questionable; M

Methyl cation + Nitrogen = (Methyl cation • Nitrogen)

By formula: CH3+ + N2 = (CH3+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°203.kJ/molPDissFoster, Williamson, et al., 1974gas phase; M

CH5+ + Nitrogen = (CH5+ • Nitrogen)

By formula: CH5+ + N2 = (CH5+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°28.kJ/molHPMSSpeller, 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°82.4J/mol*KHPMSSpeller, 1983gas phase; M

C2H5+ + Nitrogen = (C2H5+ • Nitrogen)

By formula: C2H5+ + N2 = (C2H5+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°29.kJ/molHPMSSpeller, 1983gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°76.1J/mol*KHPMSSpeller, 1983gas phase; M

(C2H5+ • Nitrogen) + Nitrogen = (C2H5+ • 2Nitrogen)

By formula: (C2H5+ • N2) + N2 = (C2H5+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°19.kJ/molHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°45.6J/mol*KHPMSSpeller, 1983gas phase; deuterated, Entropy change is questionable; M

Calcium ion (1+) + Nitrogen = (Calcium ion (1+) • Nitrogen)

By formula: Ca+ + N2 = (Ca+ • N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.296.FASpears and Fehsenfeld, 1972gas phase; M

Copper ion (1+) + Nitrogen = (Copper ion (1+) • Nitrogen)

By formula: Cu+ + N2 = (Cu+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°26.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
ΔrS°67.J/mol*KHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M
Quantity Value Units Method Reference Comment
ΔrG°5.9kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desrption; M

(Copper ion (1+) • Nitrogen) + Nitrogen = (Copper ion (1+) • 2Nitrogen)

By formula: (Cu+ • N2) + N2 = (Cu+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrG°12.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desorption, equilibrium?; M

(Copper ion (1+) • 2Nitrogen) + Nitrogen = (Copper ion (1+) • 3Nitrogen)

By formula: (Cu+ • 2N2) + N2 = (Cu+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrG°10.kJ/molHPMSEl-Shall, Schriver, et al., 1989gas phase; Cu+ from laser desorption; M

Iron ion (1+) + Nitrogen = (Iron ion (1+) • Nitrogen)

By formula: Fe+ + N2 = (Fe+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°54.0 ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • Nitrogen) + Nitrogen = (Iron ion (1+) • 2Nitrogen)

By formula: (Fe+ • N2) + N2 = (Fe+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°82.8 ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 2Nitrogen) + Nitrogen = (Iron ion (1+) • 3Nitrogen)

By formula: (Fe+ • 2N2) + N2 = (Fe+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°45. ± 3.kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 3Nitrogen) + Nitrogen = (Iron ion (1+) • 4Nitrogen)

By formula: (Fe+ • 3N2) + N2 = (Fe+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°54.0 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Iron ion (1+) • 4Nitrogen) + Nitrogen = (Iron ion (1+) • 5Nitrogen)

By formula: (Fe+ • 4N2) + N2 = (Fe+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°61.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

HN2+ + Nitrogen = (HN2+ • Nitrogen)

By formula: HN2+ + N2 = (HN2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°66.9kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
ΔrH°60.7kJ/molPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°100.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M
ΔrS°85.4J/mol*KPHPMSMeot-Ner (Mautner) and Field, 1974gas phase; M

(HN2+ • Nitrogen) + Nitrogen = (HN2+ • 2Nitrogen)

By formula: (HN2+ • N2) + N2 = (HN2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°17.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°80.3J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°75.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 2Nitrogen) + Nitrogen = (HN2+ • 3Nitrogen)

By formula: (HN2+ • 2N2) + N2 = (HN2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°16.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.1J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 3Nitrogen) + Nitrogen = (HN2+ • 4Nitrogen)

By formula: (HN2+ • 3N2) + N2 = (HN2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°15.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°88.7J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°84.J/mol*KPHPMSHiraoka, Saluja, et al., 1979gas phase; M

(HN2+ • 4Nitrogen) + Nitrogen = (HN2+ • 5Nitrogen)

By formula: (HN2+ • 4N2) + N2 = (HN2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
ΔrH°13.kJ/molPHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°95.8J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M
ΔrS°84.J/mol*KN/AHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
5.992.PHPMSHiraoka, Saluja, et al., 1979gas phase; Entropy change calculated or estimated; M

(HN2+ • 5Nitrogen) + Nitrogen = (HN2+ • 6Nitrogen)

By formula: (HN2+ • 5N2) + N2 = (HN2+ • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°9. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 6Nitrogen) + Nitrogen = (HN2+ • 7Nitrogen)

By formula: (HN2+ • 6N2) + N2 = (HN2+ • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°89.5J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 7Nitrogen) + Nitrogen = (HN2+ • 8Nitrogen)

By formula: (HN2+ • 7N2) + N2 = (HN2+ • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.0J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 8Nitrogen) + Nitrogen = (HN2+ • 9Nitrogen)

By formula: (HN2+ • 8N2) + N2 = (HN2+ • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°91.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 9Nitrogen) + Nitrogen = (HN2+ • 10Nitrogen)

By formula: (HN2+ • 9N2) + N2 = (HN2+ • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka and Mori, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°91.2J/mol*KPHPMSHiraoka and Mori, 1989gas phase; M

(HN2+ • 10Nitrogen) + Nitrogen = (HN2+ • 11Nitrogen)

By formula: (HN2+ • 10N2) + N2 = (HN2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°7.20kJ/molPHPMSHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KN/AHiraoka and Mori, 1989gas phase; Entropy change calculated or estimated; M

(Hydronium cation • Water) + Nitrogen = (Hydronium cation • Nitrogen • Water)

By formula: (H3O+ • H2O) + N2 = (H3O+ • N2 • H2O)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°58.2J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • 2Water) + Nitrogen = (Hydronium cation • Nitrogen • 2Water)

By formula: (H3O+ • 2H2O) + N2 = (H3O+ • N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°59.8J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • Water) + Nitrogen = (Hydronium cation • 2Nitrogen • Water)

By formula: (H3O+ • N2 • H2O) + N2 = (H3O+ • 2N2 • H2O)

Quantity Value Units Method Reference Comment
ΔrH°21.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°54.8J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 2Water)

By formula: (H3O+ • N2 • 2H2O) + N2 = (H3O+ • 2N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°69.5J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 2Nitrogen • 3Water)

By formula: (H3O+ • N2 • 3H2O) + N2 = (H3O+ • 2N2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°18.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°65.7J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • 2Nitrogen • Water) + Nitrogen = (Hydronium cation • 3Nitrogen • Water)

By formula: (H3O+ • 2N2 • H2O) + N2 = (H3O+ • 3N2 • H2O)

Quantity Value Units Method Reference Comment
ΔrH°33. ± 8.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°92.J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • 2Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 2Water)

By formula: (H3O+ • 2N2 • 2H2O) + N2 = (H3O+ • 3N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°38. ± 11.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°119.J/mol*KDTGheno and Fitaire, 1987gas phase; M

(Hydronium cation • 2Nitrogen • 3Water) + Nitrogen = (Hydronium cation • 3Nitrogen • 3Water)

By formula: (H3O+ • 2N2 • 3H2O) + N2 = (H3O+ • 3N2 • 3H2O)

Quantity Value Units Method Reference Comment
ΔrH°5.0kJ/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
ΔrS°27.J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

(Hydronium cation • 3Nitrogen • 2Water) + Nitrogen = (Hydronium cation • 4Nitrogen • 2Water)

By formula: (H3O+ • 3N2 • 2H2O) + N2 = (H3O+ • 4N2 • 2H2O)

Quantity Value Units Method Reference Comment
ΔrH°10.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M
Quantity Value Units Method Reference Comment
ΔrS°50.J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrH, ΔrS approximate; M

NH4+ + Nitrogen = (NH4+ • Nitrogen)

By formula: H4N+ + N2 = (H4N+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°50. ± 20.kJ/molDTGheno and Fitaire, 1987gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°130.J/mol*KDTGheno and Fitaire, 1987gas phase; M

Potassium ion (1+) + Nitrogen = (Potassium ion (1+) • Nitrogen)

By formula: K+ + N2 = (K+ • N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
4.2310.DTBeyer and Keller, 1971gas phase; low E/N; M

Lithium ion (1+) + Nitrogen = (Lithium ion (1+) • Nitrogen)

By formula: Li+ + N2 = (Li+ • N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

(Lithium ion (1+) • Nitrogen) + Nitrogen = (Lithium ion (1+) • 2Nitrogen)

By formula: (Li+ • N2) + N2 = (Li+ • 2N2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

N+ + Nitrogen = (N+ • Nitrogen)

By formula: N+ + N2 = (N+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°249.kJ/molN/ANational Bureau of Standards, 1968gas phase; from ΔrH(f); M
ΔrH°250.kJ/molEISaporoschenko, 1965gas phase; M
ΔrH°250.kJ/molEIFranklin, Dibeler, et al., 1958gas phase; M

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
361. (+7.5,-0.) CIDHaynes, Freysinger, et al., 1995gas phase; guided ion beam CID; M

Nitric oxide anion + Nitrogen = (Nitric oxide anion • Nitrogen)

By formula: NO- + N2 = (NO- • N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrH°20.kJ/molDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
ΔrH°18.kJ/molHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
ΔrH°22.kJ/molHPMSTurner and Conway, 1976gas phase; M
ΔrH°19.kJ/molDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrS°57.7J/mol*KDTGheno and Fitaire, 1987gas phase; ΔrS+-12. J/mol*K; M
ΔrS°55.6J/mol*KHPMSSpeller, Fitaire, et al., 1983gas phase; Entropy change is questionable; M
ΔrS°79.1J/mol*KHPMSTurner and Conway, 1976gas phase; M
ΔrS°65.7J/mol*KDTJohnsen, Huang, et al., 1975gas phase; corrected for ln T by Keesee and Castleman, 1986; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.200.FADunkin, Fehsenfeld, et al., 1971gas phase; M

(Nitric oxide anion • Nitrogen) + Nitrogen = (Nitric oxide anion • 2Nitrogen)

By formula: (NO- • N2) + N2 = (NO- • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrH°16.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°72.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M
ΔrS°52.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Nitric oxide anion • 2Nitrogen) + Nitrogen = (Nitric oxide anion • 3Nitrogen)

By formula: (NO- • 2N2) + N2 = (NO- • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°70.3J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
4.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 3Nitrogen) + Nitrogen = (Nitric oxide anion • 4Nitrogen)

By formula: (NO- • 3N2) + N2 = (NO- • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.204.HPMSSpeller, Fitaire, et al., 1983gas phase; M

(Nitric oxide anion • 4Nitrogen) + Nitrogen = (Nitric oxide anion • 5Nitrogen)

By formula: (NO- • 4N2) + N2 = (NO- • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°13. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°89.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 5Nitrogen) + Nitrogen = (Nitric oxide anion • 6Nitrogen)

By formula: (NO- • 5N2) + N2 = (NO- • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°13. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°95.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 6Nitrogen) + Nitrogen = (Nitric oxide anion • 7Nitrogen)

By formula: (NO- • 6N2) + N2 = (NO- • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°12. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°95.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 7Nitrogen) + Nitrogen = (Nitric oxide anion • 8Nitrogen)

By formula: (NO- • 7N2) + N2 = (NO- • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°11. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°97.5J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 8Nitrogen) + Nitrogen = (Nitric oxide anion • 9Nitrogen)

By formula: (NO- • 8N2) + N2 = (NO- • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°81.6J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(Nitric oxide anion • 9Nitrogen) + Nitrogen = (Nitric oxide anion • 10Nitrogen)

By formula: (NO- • 9N2) + N2 = (NO- • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°7.03kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°79.J/mol*KN/AHiraoka and Yamabe, 1989gas phase; Entropy change calculated or estimated; M

NO2+ + Nitrogen = (NO2+ • Nitrogen)

By formula: NO2+ + N2 = (NO2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°76.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • Nitrogen) + Nitrogen = (NO2+ • 2Nitrogen)

By formula: (NO2+ • N2) + N2 = (NO2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°82.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 2Nitrogen) + Nitrogen = (NO2+ • 3Nitrogen)

By formula: (NO2+ • 2N2) + N2 = (NO2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°18. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°87.4J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 3Nitrogen) + Nitrogen = (NO2+ • 4Nitrogen)

By formula: (NO2+ • 3N2) + N2 = (NO2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°16. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 4Nitrogen) + Nitrogen = (NO2+ • 5Nitrogen)

By formula: (NO2+ • 4N2) + N2 = (NO2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°108.J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 5Nitrogen) + Nitrogen = (NO2+ • 6Nitrogen)

By formula: (NO2+ • 5N2) + N2 = (NO2+ • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 6Nitrogen) + Nitrogen = (NO2+ • 7Nitrogen)

By formula: (NO2+ • 6N2) + N2 = (NO2+ • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°71.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 7Nitrogen) + Nitrogen = (NO2+ • 8Nitrogen)

By formula: (NO2+ • 7N2) + N2 = (NO2+ • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 8Nitrogen) + Nitrogen = (NO2+ • 9Nitrogen)

By formula: (NO2+ • 8N2) + N2 = (NO2+ • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°79.1J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 9Nitrogen) + Nitrogen = (NO2+ • 10Nitrogen)

By formula: (NO2+ • 9N2) + N2 = (NO2+ • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°86.2J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 10Nitrogen) + Nitrogen = (NO2+ • 11Nitrogen)

By formula: (NO2+ • 10N2) + N2 = (NO2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°77.8J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

(NO2+ • 11Nitrogen) + Nitrogen = (NO2+ • 12Nitrogen)

By formula: (NO2+ • 11N2) + N2 = (NO2+ • 12N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°82.0J/mol*KPHPMSHiraoka and Yamabe, 1989gas phase; M

Nitrogen cation + Nitrogen = (Nitrogen cation • Nitrogen)

By formula: N2+ + N2 = (N2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°102. to 102.kJ/molRNGN/ARange of 6 values; Individual data points
Quantity Value Units Method Reference Comment
ΔrS°87.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°67.8J/mol*KPHPMSTeng and Conway, 1973gas phase; M
ΔrS°81.6J/mol*KPHPMSPayzant and Kebarle, 1970gas phase; M
ΔrS°46.J/mol*KDTVarney, 1968gas phase; Entropy change is questionable; M
ΔrS°-4.J/mol*KDTVarney, 1959gas phase; Entropy change is questionable; M

(Nitrogen cation • Nitrogen) + Nitrogen = (Nitrogen cation • 2Nitrogen)

By formula: (N2+ • N2) + N2 = (N2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°11.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°5.9kJ/molPILinn, Ono, et al., 1981gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°62.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 2Nitrogen) + Nitrogen = (Nitrogen cation • 3Nitrogen)

By formula: (N2+ • 2N2) + N2 = (N2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°66.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 3Nitrogen) + Nitrogen = (Nitrogen cation • 4Nitrogen)

By formula: (N2+ • 3N2) + N2 = (N2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°10.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°69.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 4Nitrogen) + Nitrogen = (Nitrogen cation • 5Nitrogen)

By formula: (N2+ • 4N2) + N2 = (N2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°10.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°85.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 5Nitrogen) + Nitrogen = (Nitrogen cation • 6Nitrogen)

By formula: (N2+ • 5N2) + N2 = (N2+ • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°9.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°90.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 6Nitrogen) + Nitrogen = (Nitrogen cation • 7Nitrogen)

By formula: (N2+ • 6N2) + N2 = (N2+ • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°8.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°85.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 7Nitrogen) + Nitrogen = (Nitrogen cation • 8Nitrogen)

By formula: (N2+ • 7N2) + N2 = (N2+ • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°7.8 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°80.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 8Nitrogen) + Nitrogen = (Nitrogen cation • 9Nitrogen)

By formula: (N2+ • 8N2) + N2 = (N2+ • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°81.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 9Nitrogen) + Nitrogen = (Nitrogen cation • 10Nitrogen)

By formula: (N2+ • 9N2) + N2 = (N2+ • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°7.4 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°86.6J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Nitrogen cation • 10Nitrogen) + Nitrogen = (Nitrogen cation • 11Nitrogen)

By formula: (N2+ • 10N2) + N2 = (N2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°6.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

N3+ + Nitrogen = (N3+ • Nitrogen)

By formula: N3+ + N2 = (N3+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°83.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • Nitrogen) + Nitrogen = (N3+ • 2Nitrogen)

By formula: (N3+ • N2) + N2 = (N3+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.5J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 2Nitrogen) + Nitrogen = (N3+ • 3Nitrogen)

By formula: (N3+ • 2N2) + N2 = (N3+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°17. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°89.5J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 3Nitrogen) + Nitrogen = (N3+ • 4Nitrogen)

By formula: (N3+ • 3N2) + N2 = (N3+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°15. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°97.1J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 4Nitrogen) + Nitrogen = (N3+ • 5Nitrogen)

By formula: (N3+ • 4N2) + N2 = (N3+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°14. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°106.J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 5Nitrogen) + Nitrogen = (N3+ • 6Nitrogen)

By formula: (N3+ • 5N2) + N2 = (N3+ • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°10. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°88.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 6Nitrogen) + Nitrogen = (N3+ • 7Nitrogen)

By formula: (N3+ • 6N2) + N2 = (N3+ • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°9. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°80.8J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 7Nitrogen) + Nitrogen = (N3+ • 8Nitrogen)

By formula: (N3+ • 7N2) + N2 = (N3+ • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°8. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°69.9J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 8Nitrogen) + Nitrogen = (N3+ • 9Nitrogen)

By formula: (N3+ • 8N2) + N2 = (N3+ • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°68.2J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 9Nitrogen) + Nitrogen = (N3+ • 10Nitrogen)

By formula: (N3+ • 9N2) + N2 = (N3+ • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°69.0J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

(N3+ • 10Nitrogen) + Nitrogen = (N3+ • 11Nitrogen)

By formula: (N3+ • 10N2) + N2 = (N3+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Yamabe, 1989, 2gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°70.7J/mol*KPHPMSHiraoka and Yamabe, 1989, 2gas phase; M

Sodium ion (1+) + Nitrogen = (Sodium ion (1+) • Nitrogen)

By formula: Na+ + N2 = (Na+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°33.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°77.8J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
9.2310.FAPerry, Rowe, et al., 1980gas phase; M
8.4310.DTBeyer and Keller, 1971gas phase; low E/N; M

(Sodium ion (1+) • Nitrogen) + Nitrogen = (Sodium ion (1+) • 2Nitrogen)

By formula: (Na+ • N2) + N2 = (Na+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°22.kJ/molFAPerry, Rowe, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°70.3J/mol*KFAPerry, Rowe, et al., 1980gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
-1.310.FAPerry, Rowe, et al., 1980gas phase; M

Nickel ion (1+) + Nitrogen = (Nickel ion (1+) • Nitrogen)

By formula: Ni+ + N2 = (Ni+ • N2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
111. (+10.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) • Nitrogen) + Nitrogen = (Nickel ion (1+) • 2Nitrogen)

By formula: (Ni+ • N2) + N2 = (Ni+ • 2N2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
111. (+10.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) • 2Nitrogen) + Nitrogen = (Nickel ion (1+) • 3Nitrogen)

By formula: (Ni+ • 2N2) + N2 = (Ni+ • 3N2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
56. (+4.,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

(Nickel ion (1+) • 3Nitrogen) + Nitrogen = (Nickel ion (1+) • 4Nitrogen)

By formula: (Ni+ • 3N2) + N2 = (Ni+ • 4N2)

Enthalpy of reaction

ΔrH° (kJ/mol) T (K) Method Reference Comment
42.3 (+9.6,-0.) CIDKhan, Steele, et al., 1995gas phase; guided ion beam CID; M

Oxygen cation + Nitrogen = (Oxygen cation • Nitrogen)

By formula: O2+ + N2 = (O2+ • N2)

Quantity Value Units Method Reference Comment
ΔrH°21. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°22.kJ/molHPMSSpeller and Fitaire, 1983gas phase; M
ΔrH°24.kJ/molPHPMSJanik and Conway, 1967gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°72.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°66.1J/mol*KHPMSSpeller and Fitaire, 1983gas phase; M
ΔrS°79.1J/mol*KPHPMSJanik and Conway, 1967gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
0.0296.FAHoward, Bierbaum, et al., 1972gas phase; M

(Oxygen cation • Nitrogen) + Nitrogen = (Oxygen cation • 2Nitrogen)

By formula: (O2+ • N2) + N2 = (O2+ • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°19. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°18.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°79.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°57.7J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation • 2Nitrogen) + Nitrogen = (Oxygen cation • 3Nitrogen)

By formula: (O2+ • 2N2) + N2 = (O2+ • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°18. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrH°15.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°82.0J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M
ΔrS°50.6J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

(Oxygen cation • 3Nitrogen) + Nitrogen = (Oxygen cation • 4Nitrogen)

By formula: (O2+ • 3N2) + N2 = (O2+ • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°17. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°94.1J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.204.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation • 4Nitrogen) + Nitrogen = (Oxygen cation • 5Nitrogen)

By formula: (O2+ • 4N2) + N2 = (O2+ • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°11.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°67.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
3.184.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation • 5Nitrogen) + Nitrogen = (Oxygen cation • 6Nitrogen)

By formula: (O2+ • 5N2) + N2 = (O2+ • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°10.3 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°67.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 6Nitrogen) + Nitrogen = (Oxygen cation • 7Nitrogen)

By formula: (O2+ • 6N2) + N2 = (O2+ • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°9.5 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°77.4J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 7Nitrogen) + Nitrogen = (Oxygen cation • 8Nitrogen)

By formula: (O2+ • 7N2) + N2 = (O2+ • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°8.8 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°80.8J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 8Nitrogen) + Nitrogen = (Oxygen cation • 9Nitrogen)

By formula: (O2+ • 8N2) + N2 = (O2+ • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°7.9 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°79.9J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 9Nitrogen) + Nitrogen = (Oxygen cation • 10Nitrogen)

By formula: (O2+ • 9N2) + N2 = (O2+ • 10N2)

Quantity Value Units Method Reference Comment
ΔrH°7.0 ± 0.8kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°87.0J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • 10Nitrogen) + Nitrogen = (Oxygen cation • 11Nitrogen)

By formula: (O2+ • 10N2) + N2 = (O2+ • 11N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 1.kJ/molPHPMSHiraoka and Nakajima, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.5J/mol*KPHPMSHiraoka and Nakajima, 1988gas phase; M

(Oxygen cation • Nitrogen • Oxygen) + Nitrogen = (Oxygen cation • 2Nitrogen • Oxygen)

By formula: (O2+ • N2 • O2) + N2 = (O2+ • 2N2 • O2)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
2.230.HPMSSpeller and Fitaire, 1983gas phase; M

(Oxygen cation • Oxygen) + Nitrogen = (Oxygen cation • Nitrogen • Oxygen)

By formula: (O2+ • O2) + N2 = (O2+ • N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°12.kJ/molHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
ΔrS°42.3J/mol*KHPMSSpeller and Fitaire, 1983gas phase; Entropy change is questionable; M

Oxygen anion + Nitrogen = (Oxygen anion • Nitrogen)

By formula: O2- + N2 = (O2- • N2)

Quantity Value Units Method Reference Comment
ΔrH°25. ± 4.2kJ/molN/APosey and Johnson, 1988gas phase; B
ΔrH°<56.90kJ/molIMRBAdams and Bohme, 1970gas phase; N2..O2- + O2 -> O4-; B

(Oxygen anion • Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 2Nitrogen • Oxygen)

By formula: (O2- • N2 • O2) + N2 = (O2- • 2N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°11.7 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 2Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 3Nitrogen • Oxygen)

By formula: (O2- • 2N2 • O2) + N2 = (O2- • 3N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°10.3 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°76.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 3Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 4Nitrogen • Oxygen)

By formula: (O2- • 3N2 • O2) + N2 = (O2- • 4N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°9.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 4Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 5Nitrogen • Oxygen)

By formula: (O2- • 4N2 • O2) + N2 = (O2- • 5N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°8.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 5Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 6Nitrogen • Oxygen)

By formula: (O2- • 5N2 • O2) + N2 = (O2- • 6N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°81.6J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 6Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 7Nitrogen • Oxygen)

By formula: (O2- • 6N2 • O2) + N2 = (O2- • 7N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°7.1 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°78.7J/mol*KPHPMSHiraoka, 1988gas phase; M

(Oxygen anion • 7Nitrogen • Oxygen) + Nitrogen = (Oxygen anion • 8Nitrogen • Oxygen)

By formula: (O2- • 7N2 • O2) + N2 = (O2- • 8N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
ΔrH°6.40kJ/molPHPMSHiraoka, 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
ΔrS°74.9J/mol*KPHPMSHiraoka, 1988gas phase; M
ΔrS°75.3J/mol*KN/AHiraoka, 1988gas phase; Entropy change calculated or estimated; M

(Oxygen anion • Oxygen) + Nitrogen = (Oxygen anion • Nitrogen • Oxygen)

By formula: (O2- • O2) + N2 = (O2- • N2 • O2)

Quantity Value Units Method Reference Comment
ΔrH°12.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°69.0J/mol*KPHPMSHiraoka, 1988gas phase; M

O3- + Nitrogen = (O3- • Nitrogen)

By formula: O3- + N2 = (O3- • N2)

Quantity Value Units Method Reference Comment
ΔrH°11.3 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
ΔrS°77.0J/mol*KPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrG°-11.7 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

(O3- • Nitrogen) + Nitrogen = (O3- • 2Nitrogen)

By formula: (O3- • N2) + N2 = (O3- • 2N2)

Quantity Value Units Method Reference Comment
ΔrH°11.0 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°82.0J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 2Nitrogen) + Nitrogen = (O3- • 3Nitrogen)

By formula: (O3- • 2N2) + N2 = (O3- • 3N2)

Quantity Value Units Method Reference Comment
ΔrH°10.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°82.4J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 3Nitrogen) + Nitrogen = (O3- • 4Nitrogen)

By formula: (O3- • 3N2) + N2 = (O3- • 4N2)

Quantity Value Units Method Reference Comment
ΔrH°9.5 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°84.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 4Nitrogen) + Nitrogen = (O3- • 5Nitrogen)

By formula: (O3- • 4N2) + N2 = (O3- • 5N2)

Quantity Value Units Method Reference Comment
ΔrH°8.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°78.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 5Nitrogen) + Nitrogen = (O3- • 6Nitrogen)

By formula: (O3- • 5N2) + N2 = (O3- • 6N2)

Quantity Value Units Method Reference Comment
ΔrH°8.2 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°79.5J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 6Nitrogen) + Nitrogen = (O3- • 7Nitrogen)

By formula: (O3- • 6N2) + N2 = (O3- • 7N2)

Quantity Value Units Method Reference Comment
ΔrH°7.6 ± 0.8kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°76.1J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 7Nitrogen) + Nitrogen = (O3- • 8Nitrogen)

By formula: (O3- • 7N2) + N2 = (O3- • 8N2)

Quantity Value Units Method Reference Comment
ΔrH°7. ± 1.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°73.2J/mol*KPHPMSHiraoka, 1988gas phase; M

(O3- • 8Nitrogen) + Nitrogen = (O3- • 9Nitrogen)

By formula: (O3- • 8N2) + N2 = (O3- • 9N2)

Quantity Value Units Method Reference Comment
ΔrH°6. ± 2.kJ/molPHPMSHiraoka, 1988gas phase; M
Quantity Value Units Method Reference Comment
ΔrS°70.7J/mol*KPHPMSHiraoka, 1988gas phase; M

O4- + Nitrogen + Oxygen = N2O4-

By formula: O4- + N2 + O2 = N2O4-

Quantity Value Units Method Reference Comment
ΔrH°12.1 ± 0.84kJ/molTDAsHiraoka, 1988gas phase; B
Quantity Value Units Method Reference Comment
ΔrG°-8.8 ± 2.1kJ/molTDAsHiraoka, 1988gas phase; B

References

Go To: Top, Reaction thermochemistry data, Henry's Law data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Yamabe, 1989
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Gatland, I.R.; Colonna-Romano, L.M.; Keller, G.E., Single and Double Clustering of Nitrogen to Li+, Phys. Rev. A, 1975, 12, 5, 1885, https://doi.org/10.1103/PhysRevA.12.1885 . [all data]

Hiraoka and Yamabe, 1989, 2
Hiraoka, K.; Yamabe, S., Stabilities of the N3+(N2)n Cluster Ions with n = 1 - 11, Chem. Phys. Lett., 1989, 154, 2, 139, https://doi.org/10.1016/S0009-2614(89)87275-6 . [all data]

Khan, Steele, et al., 1995
Khan, F.A.; Steele, D.L.; Armentrout, P.B., Ligand effects in organometallic thermochemistry: The sequential bond energies of Ni(CO)x+ and Ni(N2)x+ (x = 1-4) and Ni(NO)x+ (x = 1-3) [Data derived from reported bond energies taking value of 8.273±0.046 eV for IE[Ni(CO)4]], J. Phys. Chem., 1995, 99, 7819. [all data]

Notes

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