AlCN
- Formula: CAlN
- Molecular weight: 52.9989
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: A
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| To = 28755.3 ± 0.3 | gas | A-X | 325 | 405 | Fukushima, 1998 | ||
| Gerasimov, Yang, et al., 1999 | |||||||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| Σ+ | 1 | CN stretch | 1974.5 ± 1.5 | gas | LF | Fukushima, 1998 Gerasimov, Yang, et al., 1999 | |
| CN stretch | 2143.7 | Ar | IR | Lanzisera and Andrews, 1997 | |||
| Π | 2 | Bend | 131.9 ± 1.3 | gas | LF | Fukushima, 1998 Gerasimov, Yang, et al., 1999 | |
| Σ+ | 3 | AlC stretch | 523.5 ± 0.7 | gas | LF | Fukushima, 1998 Gerasimov, Yang, et al., 1999 | |
Additional references: Jacox, 2003, page 79; Walker and Gerry, 1999
Notes
| o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Fukushima, 1998
Fukushima, M.,
Laser induced fluorescence spectroscopy of AlNC/AlCN in supersonic free expansions,
Chem. Phys. Lett., 1998, 283, 5-6, 337, https://doi.org/10.1016/S0009-2614(97)01408-5
. [all data]
Gerasimov, Yang, et al., 1999
Gerasimov, I.; Yang, X.; Dagdigian, P.J.,
Laser fluorescence excitation spectra of the AlNC and AlCN isomers,
J. Chem. Phys., 1999, 110, 1, 220, https://doi.org/10.1063/1.478097
. [all data]
Lanzisera and Andrews, 1997
Lanzisera, D.V.; Andrews, L.,
Reactions of Laser-Ablated Al, Ga, In, and Tl Atoms with Hydrogen Cyanide in Excess Argon. Matrix Infrared Spectra and Density Functional Theory Calculations on New Cyanide and Isocyanide Products,
J. Phys. Chem. A, 1997, 101, 50, 9660, https://doi.org/10.1021/jp972333x
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Walker and Gerry, 1999
Walker, K.A.; Gerry, M.C.L.,
Laboratory microwave spectroscopy of aluminium cyanide,
Chem. Phys. Lett., 1999, 301, 1-2, 200, https://doi.org/10.1016/S0009-2614(99)00013-5
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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