Chlorine trioxide
- Formula: ClO3
- Molecular weight: 83.451
- CAS Registry Number: 13932-10-0
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess
View reactions leading to ClO3+ (ion structure unspecified)
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 4.25 ± 0.10 | LPES | Wang and Wang, 2000 | Vertical Detachment Energy: 4.65±0.10 eV.; B |
| >3.19997 | EIAE | Alekseev, Fedorova, et al., 1983 | From ClO3F; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.4 ± 0.10 | EI | Alekseev, Zyubina, et al., 1989 | LL |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wang and Wang, 2000
Wang, X.B.; Wang, L.S.,
The electronic structure and electron affinities of higher chlorine oxide radicals ClOx (x=2-4) from photoelectron spectroscopy of ClOx- anions,
J. Chem. Phys., 2000, 113, 24, 10928-10933, https://doi.org/10.1063/1.1326067
. [all data]
Alekseev, Fedorova, et al., 1983
Alekseev, V.I.; Fedorova, L.I.; Baluev, A.V.,
Mass Spectrometric Study of Thermochemical Characteristics of Perchloryl Fluoride and its Decomposition Product Chlorosyl Fluoride, Izv. Akad. Nauk SSR Ser. Khim. 1084, 1983. [all data]
Alekseev, Zyubina, et al., 1989
Alekseev, V.I.; Zyubina, T.S.; Zyubin, A.S.; Baluev, A.V.,
Mass-spectrometric and quantum-chemical investigation of thermochemical characteristics of chlorine oxides,
J. Am. Chem. Soc., 1989, 2092. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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